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    REACTIVE MIXTURE FOR COATING MOLDED OBJECTS BY MEANS OF REACTION INJECTION MOLDING AND COATED MOLDED OBJECT
    2.
    发明申请
    REACTIVE MIXTURE FOR COATING MOLDED OBJECTS BY MEANS OF REACTION INJECTION MOLDING AND COATED MOLDED OBJECT 审中-公开
    通过反应注射成型和涂覆成型对象涂覆模制对象的反应混合物

    公开(公告)号：US20100167045A1

    公开(公告)日：2010-07-01

    申请号：US12601852

    申请日：2008-04-17

    申请人： Klaus Schultes ,  Thorsten Goldacker ,  Klaus Koralewski ,  Werner Hoess ,  Ghirmay Seyoum ,  Elevtherios Gross ,  Erwin Felger

    发明人： Klaus Schultes ,  Thorsten Goldacker ,  Klaus Koralewski ,  Werner Hoess ,  Ghirmay Seyoum ,  Elevtherios Gross ,  Erwin Felger

    IPC分类号： B32B27/08 ,  B29C59/16 ,  B32B5/00 ,  C08J3/28

    CPC分类号： C09D4/00 ,  B29C45/0001 ,  B29C45/1679 ,  C08F2/46 ,  C08F4/32 ,  Y10T428/263 ,  Y10T428/264 ,  Y10T428/31721 ,  Y10T428/31913 ,  Y10T428/31924 ,  Y10T428/31928

    摘要： The present invention relates to a reactive mixture for coating mouldings by means of reaction injection moulding, comprising at least 40% by weight of (meth)acrylates having at least two double bonds, the reactive mixture comprising at least one photoinitiator and at least one thermal initiator.The present invention furthermore describes a coated moulding comprising a moulding which is obtainable by injection moulding processes and comprises at least one polymer selected from the group consisting of polymethyl methacrylate, polymethylmethacrylimide, styrene-acrylonitrile copolymer, styrene-maleic acid copolymer and polymethyl methacrylate copolymers, and a coating which is obtainable by polymerization of (meth)acrylates having at least two double bonds, the coating having an adhesive strength rating of not more than 1 according to the cross hatch test and a decrease in gloss at 20° after a scratch resistance test according to ASTM 1044 (12/05) (applied weight 500 g, number of cycles=100) of not more than 10%.

    摘要翻译： 本发明涉及一种用于通过反应注射成型涂覆模制品的反应混合物，其包含至少40重量％的具有至少两个双键的（甲基）丙烯酸酯，所述反应性混合物包含至少一种光引发剂和至少一种热 发起人 本发明还描述了一种涂覆的模制品，其包括可通过注射成型方法获得的模制品，并且包括至少一种选自聚甲基丙烯酸甲酯，聚甲基丙烯酰胺，苯乙烯 - 丙烯腈共聚物，苯乙烯 - 马来酸共聚物和聚甲基丙烯酸甲酯共​​聚物的聚合物， 以及可通过聚合具有至少两个双键的（甲基）丙烯酸酯获得的涂层，该涂层根据交叉影线试验具有不大于1的粘合强度等级，并且在耐划伤性之后在20°下降低光泽度 根据ASTM 1044（12/05）（施加重量500g，循环数= 100）测试不大于10％。

    Use of polyalkyl(meth)acrylate bead polymers and moulding material for producing extruded moulded parts with a matt surface
    6.
    发明授权
    Use of polyalkyl(meth)acrylate bead polymers and moulding material for producing extruded moulded parts with a matt surface 有权
    使用聚（甲基）丙烯酸烷基酯珠粒聚合物和用于生产具有无光泽表面的挤出成型部件的成型材料

    公开(公告)号：US08399560B2

    公开(公告)日：2013-03-19

    申请号：US11661651

    申请日：2005-08-30

    申请人： Klaus Schultes ,  Peter Battenhausen ,  Ursula Golchert ,  Stefan Nau ,  Werner Hoess

    发明人： Klaus Schultes ,  Peter Battenhausen ,  Ursula Golchert ,  Stefan Nau ,  Werner Hoess

    IPC分类号： C08F2/38 ,  C08F20/10 ,  C08J5/10 ,  C08L33/12 ,  C08L51/06

    CPC分类号： C08L33/12 ,  C08L2205/02 ,  C08L2205/18 ,  C08L2666/04

    摘要： The invention relates to the use of polyalkyl(meth)acrylate bead polymers with an average particle size V50 that ranges between 30 and 70 μm for improving the stress cracking resistance of moulding materials containing polyalkyl(meth)acrylate. The invention also relates to moulding materials comprising: a) at least 50 wt. % of an impact resistance modifying agent, which contains at least one polyalkyl(meth)acrylate phase; b) at least 8 wt. % of a polyalkyl(meth)acrylate bead polymer with an average particle size V50 that ranges between 30 and 70 μm; and c) between 0 and 42 wt. % of a polyalkyl(meth)acrylate with a molecular weight ranging between 20,000 and 350,000 g/mol, whereby the wt. % of the components a) to c) amounts to 100 wt. %, and to moulded bodies that can be obtained from said materials.

    摘要翻译： 本发明涉及平均粒度V50为30〜70μm的聚（甲基）丙烯酸烷基酯聚合物（聚甲基丙烯酸烷基酯）聚合物用于提高含（甲基）丙烯酸聚烷基酯的成型材料的抗应力开裂性。 本发明还涉及成型材料，其包含：a）至少50wt。 ％的耐冲击改性剂，其含有至少一种（甲基）丙烯酸烷基酯相; b）至少8wt。 ％的平均粒度V50为（30〜70μm）的（甲基）丙烯酸烷基酯聚合的（甲基）丙烯酸烷基酯聚合物; 和c）0至42wt。 ％的分子量在20,000和350,000g / mol之间的聚（甲基）丙烯酸烷基酯，其中wt。 组分a）至c）的％相当于100wt。 ％，以及可以从所述材料获得的成型体。

    Composition with increased stress cracking resistance
    7.
    发明授权
    Composition with increased stress cracking resistance 失效
    具有增加的抗开裂性的组合物

    公开(公告)号：US08227549B2

    公开(公告)日：2012-07-24

    申请号：US12600840

    申请日：2008-04-09

    申请人： Klaus Schultes ,  Werner Hoess ,  Nils Mehler

    发明人： Klaus Schultes ,  Werner Hoess ,  Nils Mehler

    IPC分类号： C08L25/02 ,  C08L33/02 ,  C08L33/04 ,  C08L33/14 ,  C08L33/18 ,  C08L33/20 ,  C08L35/02

    CPC分类号： C08L33/08 ,  C08L25/12 ,  C08L33/10 ,  C08L2666/04

    摘要： Composition containing, based in each case on its total weight, A) 50.0% by weight to 99.5% by weight of at least one (meth)acrylate (co)polymer and B) 0.5% by weight to 50.0% by weight of at least one copolymer obtainable by polymerization of a monomer mixture comprising i. 70% by weight to 92% by weight of a vinylaromatic monomer and ii. 8% by weight to 30% by weight of acrylonitrile or methacrylonitrile or mixtures thereof and iii. 0% by weight to 22% by weight of at least one further monomer, the composition having a haze according to ASTM D1003 of less than 2.0% at 23° C. and a haze according to ASTM D1003 of less than 4.0% at 40° C. and the composition containing at least one (meth)acrylate (co)polymer a) having a solution viscosity in chloroform at 25° C. (ISO 1628—part 6) of greater than 55 ml/g. The moldings obtainable from the composition are distinguished in particular by improved stress cracking resistance and are suitable in particular for coverings, finishes or films.

    摘要翻译： 包含基于每种情况的总重量的组合物A）50.0重量％至99.5重量％的至少一种（甲基）丙烯酸酯（共）聚合物，和B）至少0.5重量％至50.0重量％ 一种共聚物，其通过单体混合物的聚合获得，所述单体混合物包含i。 70重量％至92重量％的乙烯基芳族单体，和ii。 8重量％至30重量％的丙烯腈或甲基丙烯腈或其混合物，iii。 0重量％至22重量％的至少一种其它单体，该组合物在-23℃下具有根据ASTM D1003的雾度小于2.0％，并且根据ASTM D1003的雾度小于4.0％ 40℃，组合物含有至少一种在-25℃（ISO 1628-第6部分）中溶液粘度在55ml / g以上的（甲基）丙烯酸酯（共）聚合物）a）。 可从组合物获得的模制品特别是通过改进的耐应力开裂性来区分，特别适用于覆盖物，表面处理剂或膜。

    COMPOSITION WITH INCREASED STRESS CRACKING RESISTANCE
    8.
    发明申请
    COMPOSITION WITH INCREASED STRESS CRACKING RESISTANCE 失效
    具有增加的应力抗裂性的组合物

    公开(公告)号：US20100174022A1

    公开(公告)日：2010-07-08

    申请号：US12600840

    申请日：2008-04-09

    申请人： Klaus Schultes ,  Werner Hoess ,  Nils Mehler

    发明人： Klaus Schultes ,  Werner Hoess ,  Nils Mehler

    IPC分类号： C08L33/20 ,  C08K5/05 ,  B29C45/00

    CPC分类号： C08L33/08 ,  C08L25/12 ,  C08L33/10 ,  C08L2666/04

    摘要： Composition containing, based in each case on its total weight, A) 50.0% by weight to 99.5% by weight of at least one (meth)acrylate (co)polymer and B) 0.5% by weight to 50.0% by weight of at least one copolymer obtainable by polymerisation of a monomer mixture comprising i. 70% by weight to 92% by weight of a vinylaromatic monomer and ii. 8% by weight to 30% by weight of acrylonitrile or methacrylonitrile or mixtures thereof and iii. 0% by weight to 22% by weight of at least one further monomer, the composition having a haze according to ASTM D1003 of less than 2.0% at 23° C. and a haze according to ASTM D1003 of less than 4.0% at 40° C. and the composition containing at least one (meth)acrylate (co)polymer a) having a solution viscosity in chloroform at 25° C. (ISO 1628—part 6) of greater than 55 ml/g. The mouldings obtainable from the composition are distinguished in particular by improved stress cracking resistance and are suitable in particular for coverings, finishes or films.

    摘要翻译： 包含基于每种情况的总重量的组合物A）50.0重量％至99.5重量％的至少一种（甲基）丙烯酸酯（共）聚合物，和B）至少0.5重量％至50.0重量％ 一种可通过单体混合物的聚合获得的共聚物，其包含i。 70重量％至92重量％的乙烯基芳族单体，和ii。 8重量％至30重量％的丙烯腈或甲基丙烯腈或其混合物，iii。 0重量％至22重量％的至少一种其它单体，该组合物在-23℃下具有根据ASTM D1003的雾度小于2.0％，并且根据ASTM D1003的雾度小于4.0％ 40℃，组合物含有至少一种在-25℃（ISO 1628-第6部分）中溶液粘度在55ml / g以上的（甲基）丙烯酸酯（共）聚合物）a）。 可从组合物获得的模制品特别是通过改进的耐应力开裂性来区分，特别适用于覆盖物，表面处理剂或膜。