公开(公告)号：US5155240A

公开(公告)日：1992-10-13

申请号：US668656

申请日：1991-03-13

申请人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo

发明人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo

IPC分类号： C07D309/28

CPC分类号： C07D309/28

摘要： A process for producing an optically active dihydropyran derivative represented by formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom, a lower alkyl group, a tri-lower alkylsilylmethyl group, a lower alkoxycarbonylamino group, or an --OR.sup.5 group, wherein R.sup.5 represents a lower alkyl group, a lower acyl group, a lower alkoxycarbonyl group, a di-lower alkylcarbamoyl group, or a tri-lower alkylsilyl group, or R.sup.1 and R.sup.2 are taken together to form a 5- to 7-membered cyclic hydrocarbon group or to form a condensed heterocyclic group with an oxygen atom, or R.sup.2 and R.sup.3 are taken together to form a 5- to 7-membered cyclic hydrocarbon group or to form a condensed heterocyclic group with an oxygen atom, provided that all of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 do not represent hydrogen atoms at the same time; and R.sup.6 represents a lower alkyl group, which comprises reacting a diene compound represented by formula (2): ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 have the same meanings as defined above, with a glyoxylic acid ester represented by formula (3): ##STR3## wherein R.sup.6 has the same meaning as defined above, in the presence of a binaphthol-titanium complex represented by formula (4): ##STR4## wherein X represents a chlorine atom or a bromine atom, is disclosed.

摘要翻译： 一种制备式（1）表示的光学活性二氢吡喃衍生物的方法：其中R1，R2，R3和R4各自表示氢原子，低级烷基，三低级烷基甲硅烷基甲基， 低级烷氧基羰基氨基或-OR5基团，其中R5表示低级烷基，低级酰基，低级烷氧基羰基，二低级烷基氨基甲酰基或三低级烷基甲硅烷基，或者R1和R2组合在一起 形成5至7元环状烃基或与氧原子形成稠合杂环基，或将R 2和R 3一起形成5-至7-元环状烃基或形成稠合杂环基 具有氧原子，条件是所有R1，R2，R3和R4不同时表示氢原子; 并且R 6表示低级烷基，其包括使式（2）表示的二烯化合物：其中R 1，R 2，R 3和R 4具有与上述相同的含义，与表示的二羟乙酸酯反应 在式（4）表示的联萘酚钛化合物存在下，式（3）表示：其中R 6具有与上述相同的含义，其中X表示氯原子 或溴原子。

公开(公告)号：US4965398A

公开(公告)日：1990-10-23

申请号：US386480

申请日：1989-07-28

申请人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo ,  Hidenori Kumobayashi

发明人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo ,  Hidenori Kumobayashi

IPC分类号： B01J31/22 ,  C07B61/00 ,  C07C67/347 ,  C07C69/732

CPC分类号： C07C69/732

摘要： A process for preparing an .alpha.-hydroxycarboxylate represented by formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; R.sup.2 represents a lower alkyl group, a phenyl group or a cycloalkyl group, or R.sup.1 and R.sup.2 are bonded to each other to form a five- to seven-membered cycloalkenyl or bicycloalkenyl ring which may be substituted with a lower alkyl group; and R.sup.3 represents a lower alkyl group,which comprises reacting an olefin compound represented by formula (II): ##STR2## wherein R.sup.1 ' represents a hydrogen atom or a lower alkyl group; and R.sup.2 ' represents a lower alkyl group, a phenyl group or a cycloalkyl group, or R.sup.1 ' and R.sup.2 ' are bonded to each other to form a five- to seven-membered cycloalkyl or bicycloalkyl ring which may be substituted with a lower alkyl group,with a glyoxylate represented by formula (III): ##STR3## wherein R.sup.3 is as defined above, in the presence of a binaphthol-titanium complex represented by formula (IV): ##STR4## wherein X represents a chlorine atom or bromine atom.

公开(公告)号：US5434289A

公开(公告)日：1995-07-18

申请号：US208379

申请日：1994-03-10

申请人： Koichi Mikami ,  Satoru Matsukawa ,  Masaki Shimizu ,  Masahiro Terada ,  Noboru Sayo

发明人： Koichi Mikami ,  Satoru Matsukawa ,  Masaki Shimizu ,  Masahiro Terada ,  Noboru Sayo

IPC分类号： B01J31/22 ,  C07B53/00 ,  C07B61/00 ,  C07C45/51 ,  C07C45/67 ,  C07C67/333 ,  C07C67/343 ,  C07C67/38 ,  C07C69/675 ,  C07C69/708 ,  C07C69/712 ,  C07C69/732 ,  C07C69/734 ,  C07C319/20 ,  C07C323/22 ,  C07C327/28 ,  C07C327/32 ,  C07C327/00 ,  C07C45/00 ,  C07C69/76

CPC分类号： C07C327/32 ,  C07C327/28 ,  C07C45/511 ,  C07C67/343

摘要： A process for producing an optically active .beta.-hydroxyketone represented by formula (I): ##STR1## by catalytic asymmetrical aldol reaction is disclosed, comprising reacting a silyl-enol ether represented by formula (II): ##STR2## with a substituted aldehyde represented by formula (III):R.sup.5 CHO (III)in the presence of a binaphthol-titanium complex represented by formula (IV): ##STR3## An optically active .beta.-hydroxyketone is efficiently produced with diastereo-specificity and enantio-specificity.

摘要翻译： 公开了由式（I）表示的光学活性β-羟基酮：通过催化不对称醛醇缩合反应制备的光学活性β-羟基酮的方法，包括使由式（II）表示的甲硅烷基烯醇醚： ）与由式（III）表示的取代的醛：R5CHO（III）在由式（IV）表示的联萘酚 - 钛络合物的存在下：以非对映特异性和对映体特异性有效地产生。

公开(公告)号：US06878663B2

公开(公告)日：2005-04-12

申请号：US10116057

申请日：2002-04-05

申请人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada

发明人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada

IPC分类号： C07F15/00 ,  C07F17/02

CPC分类号： C07F15/006 ,  C07F15/0066

摘要： An aromatic compound represented by the general formula Ar1X is reacted with a palladium compound and a phosphine derivative, in the presence of a first basic substance, thereby producing a palladium-complex compound represented by the general formula Ar1—PdL2X. This palladium-complex compound is reacted with a benzoic acid represented by the general formula Ar2—COOH, in the presence of a second basic substance, thereby producing another palladium-complex compound represented by the following general formula. The above palladium-complex compounds are useful as catalysts and can be produced easily by the above reactions. In the above general formulas, Ar1 is an aryl group; and X is a halogen that is fluorine, chlorine, bromine or iodine, trifluoromethanesulfonate group, an alkylsulfonate group having a carbon atom number of 1-4, or a substituted or unsubstituted arylsulfonate group; each L is independently a phosphine ligand; and Ar2 is an aryl group.

摘要翻译： 在通式Ar 1 X表示的芳香族化合物与钯化合物和膦衍生物在第一碱性物质的存在下反应，由此制备由通式Ar 1〜 PdL2X。 在第二碱性物质的存在下，使该钯络合物与通式为Ar 2 -COOH表示的苯甲酸反应，由此生成由以下通式表示的另一种钯络合物。 复合化合物可用作催化剂，并且可以通过上述反应容易地制备。 在上述通式中，Ar 1是芳基; X是氟，氯，溴或碘的卤素，三氟甲磺酸酯基，碳原子数为1-4的烷基磺酸酯基或取代或未取代的芳基磺酸酯基; 每个L独立地是膦配体; Ar 2为芳基。

公开(公告)号：US06706905B1

公开(公告)日：2004-03-16

申请号：US09458080

申请日：1999-12-10

申请人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada ,  Michio Ishida ,  Yuzuru Morino

发明人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada ,  Michio Ishida ,  Yuzuru Morino

IPC分类号： C07F1702

CPC分类号： C07F15/006 ,  C07F15/0066

摘要： An aromatic compound represented by the general formula Ar1X is reacted with a palladium compound and a phosphine derivative, in the presence of a first basic substance, thereby producing a palladium-complex compound represented by the general formula Ar1—PdL2X. This palladium-complex compound is reacted with a benzoic acid represented by the general formula Ar2—COOH, in the presence of a second basic substance, thereby producing another palladium-complex compound represented by the following general formula. The above palladium-complex compounds are useful as catalysts and can be produced easily by the above reactions. In the above general formulas, Ar1 is an aryl group; and X is a halogen that is fluorine, chlorine, bromine or iodine, trifluoromethanesulfonate group, an alkylsulfonate group having a carbon atom number of 1-4, or a substituted or unsubstituted arylsulfonate group; each L is independently a phosphine ligand; and Ar2 is an aryl group.

摘要翻译： 在通式Ar 1 X表示的芳香族化合物与钯化合物和膦衍生物在第一碱性物质的存在下反应，由此制备由通式Ar 1〜 PdL2X。 在第二碱性物质的存在下，使该钯络合物与通式为Ar 2 -COOH表示的苯甲酸反应，由此生成由以下通式表示的另一种钯络合物。 复合化合物可用作催化剂，并且可以通过上述反应容易地制备。 在上述通式中，Ar 1是芳基; X是氟，氯，溴或碘的卤素，三氟甲磺酸酯基，碳原子数为1-4的烷基磺酸酯基或取代或未取代的芳基磺酸酯基; 每个L独立地是膦配体; Ar 2为芳基。

公开(公告)号：US08756506B2

公开(公告)日：2014-06-17

申请号：US11582314

申请日：2006-10-18

申请人： Masahiro Terada

发明人： Masahiro Terada

IPC分类号： G11B27/00

CPC分类号： G11B27/005 ,  H04N5/44591 ,  H04N21/4143 ,  H04N21/4184 ,  H04N21/4314 ,  H04N21/4438 ,  H04N21/4858 ,  H04N21/8153

摘要： In an image reproduction window, an image reproduction area in which images are reproduced, and an operating area in which a slide bar is displayed are provided. When a slider of the slide bar is moved, the number of images to be displayed in one frame in the image reproduction area is increased or decreased in accordance with a position of the slider. The number of images in one frame increases as a displacement amount of the slider increases. When the slider is moved within a range in which the number of images to be displayed in one frame does not change, only a frame change interval is changed while the number of images in one frame is unchanged.

摘要翻译： 在图像再现窗口中，提供其中再现图像的图像再现区域和显示滑动条的操作区域。 当滑块的滑块移动时，根据滑动件的位置来增加或减少图像再现区域中一帧中要显示的图像数量。 一帧中的图像数量随着滑块的位移量的增加而增加。 当滑块在一帧中要显示的图像数量不改变的范围内移动时，仅一帧改变间隔改变，而一帧中的图像数量不变。

公开(公告)号：US07962005B2

公开(公告)日：2011-06-14

申请号：US11197426

申请日：2005-08-05

申请人： Masahiro Terada

发明人： Masahiro Terada

IPC分类号： H04N9/80

CPC分类号： G11B27/034 ,  G11B27/329 ,  G11B2220/213 ,  G11B2220/218 ,  G11B2220/2562 ,  H04N5/781 ,  H04N5/85 ,  H04N9/8047 ,  H04N9/8205

摘要： The folder name and the file name of an image file recorded on a recording medium such as a DVD medium, etc. correspond to the title number and the chapter number with which the image of the image file is played back in a slide show recorded on recording medium. Therefore, the slide show can be played back on the playback player such as a DVD player, etc., and an image of a desired image file can be easily detected and confirmed.

摘要翻译： 记录在诸如DVD介质等的记录介质上的图像文件的文件夹名称和文件名对应于在所记录的幻灯片放映中播放图像文件的图像的标题号和章节号 记录介质。 因此，可以在诸如DVD播放器等的回放播放器上播放幻灯片放映，并且可以容易地检测和确认期望的图像文件的图像。

公开(公告)号：US07858145B2

公开(公告)日：2010-12-28

申请号：US11211550

申请日：2005-08-26

申请人： Tsuyoshi Furuse ,  Shosei Mori ,  Masahiro Terada ,  Taku Shimoda ,  Michiko Kato

发明人： Tsuyoshi Furuse ,  Shosei Mori ,  Masahiro Terada ,  Taku Shimoda ,  Michiko Kato

IPC分类号： B05D5/12

CPC分类号： C23C18/06 ,  C23C18/1216 ,  H01J9/027 ,  H01J31/127 ,  H01J2201/3165 ,  H05K3/105 ,  H05K2203/0522 ,  H05K2203/121

摘要： Provided is a method for producing a pattern of an electroconductive member, comprising: a step of forming a resin film on a substrate surface; a step of incorporating the first metal component into the resin by applying to the resin a liquid which contains a complex of a first metal component, which contains also a second metal component different from the first component, and to which a compound forming a complex with the second metal component is contacting or contacted preliminary; and a step of baking the resin film to form the electroconductive member from the first metal component incorporated into the resin film. Thus, the second metal component is prevented from adversely affecting the first metal component to be incorporated into the resin.

摘要翻译： 提供一种用于制造导电构件图案的方法，包括：在衬底表面上形成树脂膜的步骤; 将第一金属成分加入到树脂中的步骤是向树脂施加含有第一金属成分的复合物的液体，该第一金属成分也含有与第一成分不同的第二金属成分，并且与其形成复合物的化合物 第二金属组分接触或接触初步; 以及从结合到树脂膜中的第一金属成分烘烤树脂膜以形成导电构件的步骤。 因此，防止了第二金属成分对要结合到树脂中的第一金属成分的不良影响。

公开(公告)号：US07783991B2

公开(公告)日：2010-08-24

申请号：US11859511

申请日：2007-09-21

申请人： Takeshi Misawa ,  Masahiro Terada

发明人： Takeshi Misawa ,  Masahiro Terada

IPC分类号： G06F3/00

CPC分类号： G06F17/30265

摘要： Date and time information concerning image files included in the folder is obtained, a time range from the oldest image to the newest image is calculated, and the time range is displayed with folder information. For example, data on shot dates and times recorded as associated information concerning the images or time stamps of the files are used to calculate the time range, and the date range is displayed on a folder icon or on a tab portion of the folder icon. Moreover, a file list displayed last time is stored, the stored file list is compared with a current file list, and only if the both file lists are different from each other, the date and time information is obtained for a different file to recalculate the time range. Thus, the user can infer images included in the folder to some extent and easily retrieve a desired image.

摘要翻译： 获取包含在文件夹中的图像文件的日期和时间信息，计算从最旧图像到最新图像的时间范围，并显示文件夹信息的时间范围。 例如，使用记录为关于文件的图像或时间戳的关联信息的拍摄日期和时间的数据来计算时间范围，并且日期范围显示在文件夹图标或文件夹图标的标签部分上。 此外，存储上次显示的文件列表，将存储的文件列表与当前文件列表进行比较，并且只有当两个文件列表彼此不同时，才获得用于不同文件的日期和时间信息，以重新计算 时间范围。 因此，用户可以在某种程度上推断包含在文件夹中的图像，并且容易地检索所需的图像。

公开(公告)号：US07542661B2

公开(公告)日：2009-06-02

申请号：US10628470

申请日：2003-07-29

申请人： Masahiro Terada

发明人： Masahiro Terada

IPC分类号： H04N7/00

CPC分类号： G11B27/034 ,  G11B2220/218 ,  G11B2220/2545 ,  G11B2220/2562 ,  H04N5/765 ,  H04N5/772 ,  H04N5/775 ,  H04N5/85 ,  H04N5/907

摘要： Serial reproduction digital video data in the form of a slide show can be easily generated from still image data and/or digital video data. Reading means reads still image data sets and/or digital video data sets stored in folders of a memory card, and selection of one of the folders is received. The still image data sets and/or the digital video data sets in the selected folder are arranged in order of photography, and a serial reproduction digital video data set can be generated.

摘要翻译： 可以从静止图像数据和/或数字视频数据容易地生成幻灯片放映形式的串行再现数字视频数据。 读取装置读取存储在存储卡的文件夹中的静止图像数据组和/或数字视频数据组，并且接收到其中一个文件夹的选择。 所选择的文件夹中的静止图像数据集和/或数字视频数据集按摄影的顺序排列，并且可以生成串行再现数字视频数据集。