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    Method for producing palladium complex compound
    1.
    发明授权
    Method for producing palladium complex compound 失效
    钯配合物的制造方法

    公开(公告)号：US06706905B1

    公开(公告)日：2004-03-16

    申请号：US09458080

    申请日：1999-12-10

    申请人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada ,  Michio Ishida ,  Yuzuru Morino

    发明人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada ,  Michio Ishida ,  Yuzuru Morino

    IPC分类号： C07F1702

    CPC分类号： C07F15/006 ,  C07F15/0066

    摘要： An aromatic compound represented by the general formula Ar1X is reacted with a palladium compound and a phosphine derivative, in the presence of a first basic substance, thereby producing a palladium-complex compound represented by the general formula Ar1—PdL2X. This palladium-complex compound is reacted with a benzoic acid represented by the general formula Ar2—COOH, in the presence of a second basic substance, thereby producing another palladium-complex compound represented by the following general formula. The above palladium-complex compounds are useful as catalysts and can be produced easily by the above reactions. In the above general formulas, Ar1 is an aryl group; and X is a halogen that is fluorine, chlorine, bromine or iodine, trifluoromethanesulfonate group, an alkylsulfonate group having a carbon atom number of 1-4, or a substituted or unsubstituted arylsulfonate group; each L is independently a phosphine ligand; and Ar2 is an aryl group.

    摘要翻译： 在通式Ar 1 X表示的芳香族化合物与钯化合物和膦衍生物在第一碱性物质的存在下反应，由此制备由通式Ar 1〜 PdL2X。 在第二碱性物质的存在下，使该钯络合物与通式为Ar 2 -COOH表示的苯甲酸反应，由此生成由以下通式表示的另一种钯络合物。 复合化合物可用作催化剂，并且可以通过上述反应容易地制备。 在上述通式中，Ar 1是芳基; X是氟，氯，溴或碘的卤素，三氟甲磺酸酯基，碳原子数为1-4的烷基磺酸酯基或取代或未取代的芳基磺酸酯基; 每个L独立地是膦配体; Ar 2为芳基。

    Method for producing palladium complex compound
    2.
    发明授权
    Method for producing palladium complex compound 失效
    钯配合物的制造方法

    公开(公告)号：US06878663B2

    公开(公告)日：2005-04-12

    申请号：US10116057

    申请日：2002-04-05

    申请人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada

    发明人： Takashi Kume ,  Satoru Narizuka ,  Makoto Koide ,  Koichi Mikami ,  Manabu Hatano ,  Masahiro Terada

    IPC分类号： C07F15/00 ,  C07F17/02

    CPC分类号： C07F15/006 ,  C07F15/0066

    摘要： An aromatic compound represented by the general formula Ar1X is reacted with a palladium compound and a phosphine derivative, in the presence of a first basic substance, thereby producing a palladium-complex compound represented by the general formula Ar1—PdL2X. This palladium-complex compound is reacted with a benzoic acid represented by the general formula Ar2—COOH, in the presence of a second basic substance, thereby producing another palladium-complex compound represented by the following general formula. The above palladium-complex compounds are useful as catalysts and can be produced easily by the above reactions. In the above general formulas, Ar1 is an aryl group; and X is a halogen that is fluorine, chlorine, bromine or iodine, trifluoromethanesulfonate group, an alkylsulfonate group having a carbon atom number of 1-4, or a substituted or unsubstituted arylsulfonate group; each L is independently a phosphine ligand; and Ar2 is an aryl group.

    摘要翻译： 在通式Ar 1 X表示的芳香族化合物与钯化合物和膦衍生物在第一碱性物质的存在下反应，由此制备由通式Ar 1〜 PdL2X。 在第二碱性物质的存在下，使该钯络合物与通式为Ar 2 -COOH表示的苯甲酸反应，由此生成由以下通式表示的另一种钯络合物。 复合化合物可用作催化剂，并且可以通过上述反应容易地制备。 在上述通式中，Ar 1是芳基; X是氟，氯，溴或碘的卤素，三氟甲磺酸酯基，碳原子数为1-4的烷基磺酸酯基或取代或未取代的芳基磺酸酯基; 每个L独立地是膦配体; Ar 2为芳基。

    Process for producing optically active dihydropyran derivative
    3.
    发明授权
    Process for producing optically active dihydropyran derivative 失效
    光学活性二氢吡喃衍生物的制备方法

    公开(公告)号：US5155240A

    公开(公告)日：1992-10-13

    申请号：US668656

    申请日：1991-03-13

    申请人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo

    发明人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo

    IPC分类号： C07D309/28

    CPC分类号： C07D309/28

    摘要： A process for producing an optically active dihydropyran derivative represented by formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom, a lower alkyl group, a tri-lower alkylsilylmethyl group, a lower alkoxycarbonylamino group, or an --OR.sup.5 group, wherein R.sup.5 represents a lower alkyl group, a lower acyl group, a lower alkoxycarbonyl group, a di-lower alkylcarbamoyl group, or a tri-lower alkylsilyl group, or R.sup.1 and R.sup.2 are taken together to form a 5- to 7-membered cyclic hydrocarbon group or to form a condensed heterocyclic group with an oxygen atom, or R.sup.2 and R.sup.3 are taken together to form a 5- to 7-membered cyclic hydrocarbon group or to form a condensed heterocyclic group with an oxygen atom, provided that all of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 do not represent hydrogen atoms at the same time; and R.sup.6 represents a lower alkyl group, which comprises reacting a diene compound represented by formula (2): ##STR2## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 have the same meanings as defined above, with a glyoxylic acid ester represented by formula (3): ##STR3## wherein R.sup.6 has the same meaning as defined above, in the presence of a binaphthol-titanium complex represented by formula (4): ##STR4## wherein X represents a chlorine atom or a bromine atom, is disclosed.

    摘要翻译： 一种制备式（1）表示的光学活性二氢吡喃衍生物的方法：其中R1，R2，R3和R4各自表示氢原子，低级烷基，三低级烷基甲硅烷基甲基， 低级烷氧基羰基氨基或-OR5基团，其中R5表示低级烷基，低级酰基，低级烷氧基羰基，二低级烷基氨基甲酰基或三低级烷基甲硅烷基，或者R1和R2组合在一起 形成5至7元环状烃基或与氧原子形成稠合杂环基，或将R 2和R 3一起形成5-至7-元环状烃基或形成稠合杂环基 具有氧原子，条件是所有R1，R2，R3和R4不同时表示氢原子; 并且R 6表示低级烷基，其包括使式（2）表示的二烯化合物：其中R 1，R 2，R 3和R 4具有与上述相同的含义，与表示的二羟乙酸酯反应 在式（4）表示的联萘酚钛化合物存在下，式（3）表示：其中R 6具有与上述相同的含义，其中X表示氯原子 或溴原子。

    Process for producing optically active alpha-hydroxycarboxylates
    5.
    发明授权
    Process for producing optically active alpha-hydroxycarboxylates 失效
    光学活性α-羟基羧酸盐的制备方法

    公开(公告)号：US4965398A

    公开(公告)日：1990-10-23

    申请号：US386480

    申请日：1989-07-28

    申请人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo ,  Hidenori Kumobayashi

    发明人： Koichi Mikami ,  Masahiro Terada ,  Takeshi Nakai ,  Noboru Sayo ,  Hidenori Kumobayashi

    IPC分类号： B01J31/22 ,  C07B61/00 ,  C07C67/347 ,  C07C69/732

    CPC分类号： C07C69/732

    摘要： A process for preparing an .alpha.-hydroxycarboxylate represented by formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; R.sup.2 represents a lower alkyl group, a phenyl group or a cycloalkyl group, or R.sup.1 and R.sup.2 are bonded to each other to form a five- to seven-membered cycloalkenyl or bicycloalkenyl ring which may be substituted with a lower alkyl group; and R.sup.3 represents a lower alkyl group,which comprises reacting an olefin compound represented by formula (II): ##STR2## wherein R.sup.1 ' represents a hydrogen atom or a lower alkyl group; and R.sup.2 ' represents a lower alkyl group, a phenyl group or a cycloalkyl group, or R.sup.1 ' and R.sup.2 ' are bonded to each other to form a five- to seven-membered cycloalkyl or bicycloalkyl ring which may be substituted with a lower alkyl group,with a glyoxylate represented by formula (III): ##STR3## wherein R.sup.3 is as defined above, in the presence of a binaphthol-titanium complex represented by formula (IV): ##STR4## wherein X represents a chlorine atom or bromine atom.

    Glare-proofing optical laminate
    6.
    发明授权
    Glare-proofing optical laminate 有权
    防眩光学层压板

    公开(公告)号：US08999463B2

    公开(公告)日：2015-04-07

    申请号：US11817818

    申请日：2006-03-29

    申请人： Koichi Mikami ,  Yukimitsu Iwata ,  Yoshihiro Nishimura ,  Takashi Kodama

    发明人： Koichi Mikami ,  Yukimitsu Iwata ,  Yoshihiro Nishimura ,  Takashi Kodama

    IPC分类号： C09K19/00 ,  G02B5/02 ,  G02B5/30

    CPC分类号： G02B1/111 ,  G02B5/02 ,  G02B5/3033 ,  Y10T428/1036 ,  Y10T428/24372 ,  Y10T428/24537 ,  Y10T428/2457 ,  Y10T428/25 ,  Y10T428/26

    摘要： An anti-dazzling laminate made of an optical laminate including a light transparent base material and an anti-dazzling layer having a concavoconvex shape provided on the material. The laminate simultaneously satisfies formulae: 0≦G100≦15 (I), 0.1≦Hs≦5.0 (II), 0.3≦Rz≦1.8 (III) wherein G100 represents a scintillation value which is a standard deviation of a variation in brightness distribution at a resolution of 100 ppi measured on the surface of the laminate; Hs represents the surface haze value of the laminate; and Rz represents the average roughness of the concavoconvex shape of the anti-dazzling layer.

    摘要翻译： 由光学层压制品制成的防光泽层压材料，该层压材料包括透明基材和具有凹凸形状的抗眩光层。 层压板同时满足公式：0＆nlE; G100＆nlE; 15（I），0.1＆nlE; Hs＆nlE; 5.0（II），0.3＆nlE; Rz＆nlE; 1.8（III）其中G100表示​​闪烁值，其是亮度变化的标准偏差 在层压板的表面上测量的分辨率为100ppi的分布; Hs表示层压板的表面雾度值; Rz表示防炫目层的凹凸形状的平均粗糙度。

    Method for producing optically active fluorine-containing carbonyl-ene product
    10.
    发明授权
    Method for producing optically active fluorine-containing carbonyl-ene product 有权
    光学活性含氟羰基产物的制备方法

    公开(公告)号：US08278479B2

    公开(公告)日：2012-10-02

    申请号：US12519959

    申请日：2007-12-18

    申请人： Koichi Mikami ,  Kohsuke Aikawa ,  Akihiro Ishii ,  Kaori Mogi ,  Takashi Ootsuka

    发明人： Koichi Mikami ,  Kohsuke Aikawa ,  Akihiro Ishii ,  Kaori Mogi ,  Takashi Ootsuka

    IPC分类号： C07C69/732

    CPC分类号： C07C67/347 ,  C07B53/00 ,  C07B2200/07 ,  C07C67/343 ,  C07C69/732

    摘要： An optically active, fluorine-containing carbonyl-ene product is produced by reacting a fluorine-containing α-ketoester with an alkene in the presence of a transition metal complex having an optically active ligand. There are Mode 1 of conducting this reaction in the absence of reaction solvent, Mode 2 of conducting this reaction in a solvent that is low in relative dielectric constant, and Mode 3 of conducting this reaction in a halogenated hydrocarbon-series solvent. In each of these three modes, it is possible to produce the optically active, fluorine-containing carbonyl-ene product with low cost.

    摘要翻译： 通过在具有光学活性配体的过渡金属络合物的存在下使含氟α-酮酯与烯烃反应来制备光学活性的含氟羰基产物。 在没有反应溶剂的情况下进行该反应的方式1，在相对介电常数低的溶剂中进行该反应的方式2，以及在卤代烃系溶剂中进行该反应的方式3。 在这三种模式中的每一种中，可以以低成本制造光学活性的含氟羰基产物。