Dynamic vulcanizates of engineering thermoplastic and acrylate rubber
blends with dissimilar cure sites using a common curative
    1.
    发明授权
    Dynamic vulcanizates of engineering thermoplastic and acrylate rubber blends with dissimilar cure sites using a common curative 失效
    使用常见治疗剂的不同治愈部位的工程热塑性和丙烯酸酯橡胶混合物的动态硫化

    公开(公告)号:US6020431A

    公开(公告)日:2000-02-01

    申请号:US109647

    申请日:1998-07-02

    摘要: Dynamic vulcanizates of an engineering thermoplastic ("plastic"), e.g. a polyamide or polyester, with acrylate rubbers having dissimilar functional groups are prepared with a metal fatty acid salt in the absence of a conventional curative, provided the rubbers are molecularly intermixed. An acrylate rubber with halogen functionality ("AcrRubHal") is thus crosslinked in a single mixing stage with an acrylate rubber having carboxyl, hydroxyl or epoxy functionality ("AcrRubX") in a "plastic". Quaternary ammonium salts and tertiary amines do not function as curatives, as one might expect. But a metal fatty acid salt, preferably a metal stearate or oleate and concentrates thereof effectively crosslink the rubbers. TPVs produced without conventional curing agents are relatively "soft", but have highly desirable low temperature physical properties and oil resistance.

    摘要翻译: 工程热塑性塑料(“塑料”)的动态硫化橡胶。 在没有常规固化剂的情况下,用金属脂肪酸盐制备具有不同官能团的丙烯酸酯橡胶的聚酰胺或聚酯,只要橡胶是分子混合的。 因此,具有卤素官能团的丙烯酸酯橡胶(“AcrRubHal”)在单一混合阶段与具有羧基,羟基或环氧官能团的丙烯酸酯橡胶(“AcrRubX”)在“塑料”中交联。 正如人们所期望的,季铵盐和叔胺不起作用。 但是金属脂肪酸盐,优选金属硬脂酸盐或油酸盐,其浓缩物有效地交联橡胶。 没有常规固化剂生产的TPV相对“柔软”,但具有非常理想的低温物理性能和耐油性。

    BIORENEWABLE COPOLYESTER THERMOPLASTIC ELASTOMERS
    2.
    发明申请
    BIORENEWABLE COPOLYESTER THERMOPLASTIC ELASTOMERS 有权
    可生物共聚物热塑性弹性体

    公开(公告)号:US20130005901A1

    公开(公告)日:2013-01-03

    申请号:US13634268

    申请日:2011-03-16

    IPC分类号: C08G63/91 C08L67/08

    摘要: A thermoplastic elastomer compound is disclosed having copolyester elastomer, epoxidized soybean oil, and vulcanized vegetable oil. The compound has a biorenewable content of at least about 50 weight percent of the compound. The compound can be used to make a plastic article needing a Shore A hardness of from about 40 to about 70. The compound is a sustainable solution for extruded or molded articles.

    摘要翻译: 公开了一种具有共聚酯弹性体,环氧化大豆油和硫化植物油的热塑性弹性体化合物。 化合物的生物可再生含量为化合物的至少约50重量%。 该化合物可用于制造需要约40至约70的肖氏A硬度的塑料制品。该化合物是用于挤出或模制制品的可持续解决方案。

    Roofing membrane
    3.
    发明授权
    Roofing membrane 有权
    屋顶膜

    公开(公告)号:US06583202B1

    公开(公告)日:2003-06-24

    申请号:US09950976

    申请日:2001-09-13

    IPC分类号: C08L9500

    摘要: This invention relates to a roofing or siding membrane comprising a non-woven mat coated with an asphaltic composition containing, in addition to 35-75 wt. % bitumen, a mixture of isotactic and amorphous propylene polymers and between about 0.08 and about 15 wt. % of a functionalized, olefin polymer to provide a non-staining membrane of high tensile strength, low polyolefin content with respect to asphalt, improved compatibility between asphalt and non-functionalized polymers and reduced light end asphalt and polymer exudates. The invention also relates to a method for preparing the membrane.

    摘要翻译: 本发明涉及一种屋顶或侧墙膜,其包括涂覆有沥青组合物的无纺布垫,所述沥青组合物除了35-75wt。 %沥青,全同立构和无定形丙烯聚合物的混合物和约0.08至约15wt。 %的官能化烯烃聚合物,以提供相对于沥青具有高拉伸强度,低聚烯烃含量的非污染膜,改善沥青和非官能化聚合物之间的相容性,以及减少的轻质沥青和聚合物渗出物。 本发明还涉及一种制备膜的方法。

    Self-cured rubber-thermoplastic elastomer compositions
    4.
    发明授权
    Self-cured rubber-thermoplastic elastomer compositions 失效
    自固化橡胶 - 热塑性弹性体组合物

    公开(公告)号:US5783631A

    公开(公告)日:1998-07-21

    申请号:US686782

    申请日:1996-07-26

    摘要: A thermoplastic elastomer composition has a plastic phase or matrix of an engineering thermoplastic such as an ester polymer and a crosslinked phase of self-cured acrylic rubber particles. The rubber particles are the reaction product of at least one functionalized acrylic rubber self-cured by a different functionalized acrylic rubber wherein the functional groups are generally a carboxyl, an epoxy, or hydroxyl, and the like. The composition can be dynamically vulcanized in the presence of an accelerator and desirably has a single low temperature brittle point.

    摘要翻译: 热塑性弹性体组合物具有工程热塑性塑料的塑料相或基质,例如酯聚合物和自固化丙烯酸橡胶颗粒的交联相。 橡胶颗粒是由不同官能化丙烯酸橡胶自固化的至少一种官能化丙烯酸橡胶的反应产物,其中官能团通常是羧基,环氧基或羟基等。 组合物可以在促进剂的存在下动态硫化,并且期望具有单个低温脆性点。

    Biorenewable copolyester thermoplastic elastomers
    5.
    发明授权
    Biorenewable copolyester thermoplastic elastomers 有权
    可生物聚合的共聚酯热塑性弹性体

    公开(公告)号:US08981003B2

    公开(公告)日:2015-03-17

    申请号:US13634268

    申请日:2011-03-16

    摘要: A thermoplastic elastomer compound is disclosed having copolyester elastomer, epoxidized soybean oil, and vulcanized vegetable oil. The compound has a biorenewable content of at least about 50 weight percent of the compound. The compound can be used to make a plastic article needing a Shore A hardness of from about 40 to about 70. The compound is a sustainable solution for extruded or molded articles.

    摘要翻译: 公开了一种具有共聚酯弹性体,环氧化大豆油和硫化植物油的热塑性弹性体化合物。 化合物的生物可再生含量为化合物的至少约50重量%。 该化合物可用于制造需要约40至约70的肖氏A硬度的塑料制品。该化合物是用于挤出或模制制品的可持续解决方案。

    Co-cured rubber-thermoplastic elastomer compositions
    8.
    发明授权
    Co-cured rubber-thermoplastic elastomer compositions 失效
    共固化的橡胶 - 热塑性弹性体组合物

    公开(公告)号:US5777033A

    公开(公告)日:1998-07-07

    申请号:US686798

    申请日:1996-07-26

    摘要: A thermoplastic elastomer composition has a plastic phase or matrix of an engineering thermoplastic such as a polyamide and a crosslinked phase of cured acrylic rubbers. The rubbers contain at least two functionalized acrylic rubbers wherein the functional group such as a carboxyl, an epoxy, or a hydroxyl can be the same or different. The curing agents generally react via covalent bonding with the reactive functional groups of the rubbers. The composition can be dynamically vulcanized and when one of the rubbers is a terpolymer of ethylene-alkyl acrylate-unsaturated carboxylic acid, the composition has a single low temperature brittle point.

    摘要翻译: 热塑性弹性体组合物具有工程热塑性塑料的塑料相或基体,例如聚酰胺和固化的丙烯酸橡胶的交联相。 橡胶含有至少两种官能化丙烯酸橡胶,其中官能团如羧基,环氧基或羟基可以相同或不同。 固化剂通常通过共价键与橡胶的反应性官能团反应。 该组合物可以动态硫化,当橡胶之一是乙烯 - 丙烯酸烷基酯 - 不饱和羧酸的三元共聚物时,该组合物具有单一的低温脆性点。