利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

19 条记录 (耗时 0.041 秒)

    Process for the production of N-substituted .alpha.,.beta.-unsaturated carboxylic acid amides
    1.
    发明授权
    Process for the production of N-substituted .alpha.,.beta.-unsaturated carboxylic acid amides 失效
    制备N-取代的α，β-不饱和羧酸酰胺的方法

    公开(公告)号：US4644083A

    公开(公告)日：1987-02-17

    申请号：US695125

    申请日：1985-01-25

    申请人： Kurt Dahmen ,  Erich Kuster ,  Richard Mertens ,  Helmut Brehm

    发明人： Kurt Dahmen ,  Erich Kuster ,  Richard Mertens ,  Helmut Brehm

    IPC分类号： C07C231/00 ,  C07C67/00 ,  C07C231/02 ,  C07C231/12 ,  C07C233/01 ,  C07C233/09 ,  C07C233/38 ,  C07C103/133 ,  C07D241/04 ,  C07D265/30 ,  C07D295/00

    CPC分类号： C07C233/01

    摘要： The present invention relates to a process for the production of N-substituted .alpha.,.beta.-unsaturated carboxylic acid amides, which proceeds from the .alpha.,.beta.-unsaturated carboxylic acid amide that is unsubstituted at the amido nitrogen, which forms the Michael adduct initially by conversion with a polyvalent alcohol having a boiling point of >/=150.degree. C., converts this with a primary or secondary amine with elimination of ammonia to form N-substituted carboxylic acid amide with a protected double bond, the polyvalent alcohol being subsequently eliminated from this product at high temperatures, with formation of the N-substituted .alpha.,.beta.-unsaturated carboxylic acid amide.

    摘要翻译： 本发明涉及一种生产N-取代的α，β-不饱和羧酸酰胺的方法，其由在酰氨基氮未被取代的α，β-不饱和羧酸酰胺进行，其最初由 用沸点> 150℃的多元醇进行转化，将其与伯胺或仲胺反应，同时除去氨以形成具有受保护双键的N-取代羧酸酰胺，随后将多元醇除去 从该产品在高温下，形成N-取代的α，β-不饱和羧酸酰胺。

    Copolymers of allyliminodiacetic acid with unsaturated carboxylic acids and their use as complexing agents, peroxide stabilizers, builders in washing and cleaning products and dispersing agents
    2.
    发明授权
    Copolymers of allyliminodiacetic acid with unsaturated carboxylic acids and their use as complexing agents, peroxide stabilizers, builders in washing and cleaning products and dispersing agents 失效
    烯丙基二乙酸与不饱和羧酸的共聚物及其作为络合剂的用途，过氧化物稳定剂，洗涤和清洁产品中的助洗剂和分散剂

    公开(公告)号：US5548049A

    公开(公告)日：1996-08-20

    申请号：US362435

    申请日：1994-12-29

    申请人： Helmut Brehm ,  Kurt Dahmen ,  Richard Mertens

    发明人： Helmut Brehm ,  Kurt Dahmen ,  Richard Mertens

    IPC分类号： C08F220/06 ,  B01F17/52 ,  C08F20/02 ,  C08F26/00 ,  C08F220/04 ,  C08F222/02 ,  C08F222/06 ,  C08F226/02 ,  C11D3/37 ,  C11D3/39

    CPC分类号： C11D3/394 ,  C08F220/04 ,  C08F222/02 ,  C08F226/02 ,  C11D3/3769 ,  C11D3/3773

    摘要： Polymers consisting of (a) 1-50% weight of N-allyliminodiacetic acid and its salts; (b) 50-99% weight of one or several unsaturated, polymerisable carboxylic acids having the formula (I), in which R.sup.1 stands for hydrogen, C.sub.1-C.sub.4 alkyl or COOM, R.sup.2 stands for hydrogen or C.sub.1-C.sub.4 alkyl, R.sup.3 stands for hydrogen, C.sub.1-C.sub.4 alkyl or CH.sub.2 COOM and M stands for hydrogen, ammonium, an alkali metal or an alkaline earth metal; and (c) 0-40% by weight water soluble monomers copolymerisable with (a) and (b). These polymers preferably contain acrylic acid, methacrylic acid and maleic acid as unsaturated polymerisable carboxylic acids. Also disclosed are the use of these polymers as complexing agents, as peroxide stabilizers and builders in washing products, as dispersing agents and hardness stabilizers.

    摘要翻译： PCT No.PCT / EP93 / 01694 Sec。 371日期1994年12月29日第 102（e）日期1994年12月29日PCT提交1993年7月1日PCT公布。 第WO94 / 01477号公报 日期1994年1月20日<图像（I）由（a）1-50％重量的N-烯丙基二亚氨基二乙酸及其盐组成的聚合物; （b）50-99重量％的具有式（I）的一种或多种不饱和的可聚合羧酸，其中R1代表氢，C1-C4烷基或COOM，R2代表氢或C1-C4烷基，R3代表 对于氢，C 1 -C 4烷基或CH 2 COOM，M代表氢，铵，碱金属或碱土金属; 和（c）0-40重量％可与（a）和（b）共聚的水溶性单体。 这些聚合物优选含有丙烯酸，甲基丙烯酸和马来酸作为不可聚合的羧酸。 还公开了这些聚合物作为络合剂，作为洗涤剂中的过氧化物稳定剂和助洗剂，作为分散剂和硬度稳定剂的用途。

    Cross-linked, water-absorbing polymer and its use in the production of hygiene items
    4.
    发明授权
    Cross-linked, water-absorbing polymer and its use in the production of hygiene items 失效
    交联，吸水聚合物及其在卫生用品生产中的应用

    公开(公告)号：US5408019A

    公开(公告)日：1995-04-18

    申请号：US191742

    申请日：1994-02-01

    申请人： Richard Mertens ,  Kurt Dahmen ,  Helmut Brehm

    发明人： Richard Mertens ,  Kurt Dahmen ,  Helmut Brehm

    IPC分类号： A61L15/60 ,  C08F220/04 ,  C08F236/22 ,  C08F236/70

    CPC分类号： C08F220/04 ,  A61L15/60

    摘要： The invention relates to a cross-linked, water-absorbent polymer obtainable by the polymerization of a mixture consisting of a) 60-99%-wt. unsaturated, polymerizable monomers with acid groups which are neutralized to the extent of at least 30 mol-%, b) 0-37%-wt. monomers copolymerizable with a), c) 0.1-3.0%-wt. of a cross-linking agent and d) 0-10%-wt. of a water-soluble polymer, in which polymerization is conducted with a redox catalyst system containing formamidine sulfinic acid as reducing agent. The polymer is distinguished by a retention of greater than or equal to 28 g 0.9% aqueous NaCl-solution per 1 g of polymer, an absorption of greater than or equal to 26 g 0.9% aqueous NaCl-solution per 1 g of polymer at a load of 20 g/cm.sup.2 and a residual monomer content of less than 700 ppm, and preferably less than 500 ppm. The invention also relates to the use of this polymer in the production of hygiene articles.

    摘要翻译： 本发明涉及一种交联的吸水聚合物，其通过以下混合物的聚合获得：a）60-99重量％ 具有酸性基团的不饱和的可聚合单体，其被中和到至少30mol％的程度，b）0-37wt％ 可与a）共聚的单体，c）0.1-3.0％重量 的交联剂和d）0-10％-wt。 的水溶性聚合物，其中使用含有甲脒亚磺酸作为还原剂的氧化还原催化剂体系进行聚合。 该聚合物的特征在于每1g聚合物保留大于或等于28g 0.9％的NaCl水溶液，在1g聚合物中每1g聚合物吸收大于或等于26g 0.9％的NaCl水溶液 负载为20g / cm 2，残留单体含量小于700ppm，优选小于500ppm。 本发明还涉及这种聚合物在卫生制品生产中的应用。

    Alkoxy group containing copolymers and their use in retanning leather
    5.
    发明授权
    Alkoxy group containing copolymers and their use in retanning leather 失效
    含烷氧基的共聚物及其在复鞣皮革中的应用

    公开(公告)号：US5873908A

    公开(公告)日：1999-02-23

    申请号：US735987

    申请日：1996-10-25

    申请人： Kurt Dahmen ,  Richard Mertens ,  Helmut Brehm ,  Horst Kilian ,  Jochen Houben ,  Thomas Muller

    发明人： Kurt Dahmen ,  Richard Mertens ,  Helmut Brehm ,  Horst Kilian ,  Jochen Houben ,  Thomas Muller

    IPC分类号： C08F220/04 ,  C08F222/02 ,  C08F222/04 ,  C08F246/00 ,  C14C3/22 ,  C14C3/28

    CPC分类号： C08F222/04 ,  C08F220/04 ,  C14C3/22 ,  C14C3/28

    摘要： The present invention relates to alkoxy-groups-containing copolymers of a) 1 to 99%-wt. water soluble ethylenically unsaturated, acid-groups-containing monomers, b) 1 to 50%-wt. monomers having a polyalkoxy sequence and c) 0 to 60%-wt. water soluble monomers which are copolymerizable with a) and b); and to the use of said copolymers for retanning leathers previously tanned by a mineral or combined method. The leathers treated with the retanning agents according to the invention in particular stand out for an improved fullness and good grain tightness.The acid groups of monomers a) preferably are carboxyl groups.

    摘要翻译： 本发明涉及a）1至99重量％的含烷氧基基团的共聚物。 水溶性烯属不饱和的含酸基团的单体，b）1〜50重量％ 具有聚烷氧基序列的单体和c）0至60重量％ 可与a）和b）共聚的水溶性单体; 以及所述共聚物用于复鞣以前由矿物或组合方法鞣制的皮革的用途。 用根据本发明的复鞣剂处理的皮革特别突出，以改善丰满度和良好的颗粒紧密度。 单体的酸基a）优选为羧基。

    Powdery absorbing material for aqueous liquids based on water-swellable carboxylate polymers
    7.
    发明授权
    Powdery absorbing material for aqueous liquids based on water-swellable carboxylate polymers 失效
    基于水溶胀性羧酸盐聚合物的含水液体的粉状吸收材料

    公开(公告)号：US5229466A

    公开(公告)日：1993-07-20

    申请号：US884344

    申请日：1992-05-18

    申请人： Helmut Brehm ,  Richard Mertens

    发明人： Helmut Brehm ,  Richard Mertens

    IPC分类号： A61L15/00 ,  A61L15/60 ,  B01J20/26 ,  C08F8/30 ,  C08K5/17 ,  C08L101/00

    CPC分类号： A61L15/60 ,  B01J20/26 ,  C08F8/32 ,  C08F2800/10

    摘要： The present invention relates to a powdery absorbing material for aqueous liquids based on a water-swellable powdery polymer having at least 0.2 equivalents carboxyl groups per 100 parts by weight which are neutralized by 50 to 99, advantageously by at least 80 mole %. The powdery absorbing material is obtained by treating the water-swellable carboxyl-groups-containing polymer with a solution of an N-(hydroxyalkyl).beta.-(meth)-alanine ester or with the polycondensation products thereof. As a solvent for the powdery absorbing material, water is used which either contains water-miscible organic diluents which evaporate on heating, or non-evaporative water-miscible organic diluents, i.e., diluents remaining in the polymer.

    摘要翻译： 本发明涉及一种基于每100重量份具有至少0.2当量羧基的水溶胀性粉末状聚合物的水性液体粉末状吸收材料，其被50-99中和，有利地至少为80摩尔％。 通过用N-（羟基烷基）β-（甲基） - 丙氨酸酯或其缩聚产物的溶液处理含水溶胀性的含羧基聚合物而得到粉状吸收材料。 作为粉末吸收材料的溶剂，使用水，其包含在加热时蒸发的水混溶性有机稀释剂，或非蒸发性水混溶性有机稀释剂，即残留在聚合物中的稀释剂。

    Polymer composition and a method for producing the same
    8.
    发明授权
    Polymer composition and a method for producing the same 失效
    聚合物组合物及其制备方法

    公开(公告)号：US06911499B1

    公开(公告)日：2005-06-28

    申请号：US10069278

    申请日：2000-08-02

    申请人： Helmut Brehm ,  Hans-Georg Hartan

    发明人： Helmut Brehm ,  Hans-Georg Hartan

    IPC分类号： A61F13/53 ,  A61F5/44 ,  A61F13/49 ,  A61L15/60 ,  B01J20/26 ,  B01J20/30 ,  C08F2/00 ,  C08F220/04 ,  C08F251/00 ,  C08F261/04 ,  C08F290/06 ,  C08F291/00 ,  C08L51/00 ,  C08F20/02 ,  C08J9/28

    CPC分类号： A61L15/60 ,  B01J20/26 ,  C08F220/04 ,  C08F251/00 ,  C08F261/04 ,  C08L51/003

    摘要： The present invention relates to powdered, crosslinked polymer compositions, containing a) 55-99.9 wt.-% of at least one polymerized, ethylenically unsaturated, polymerizable monomer which contains acid groups neutralized to at least 25 mole-%, b) 0-40 wt.-% of polymerized, unsaturated monomers copolymerizable with a), c) 0.01-5.0 wt.-%, preferably 0.1-2.0 wt.-% of one or more crosslinking agents, d) 0-30 wt.-% of a water-soluble polymer, the weight amounts a) through d) being based on anhydrous polymer composition, and the sum of these components always being 100 wt.-%, which compositions can be obtained by continuous polymerization wherein at least one parameter biasing the polymerization is varied according to a recurring pattern. The present invention also relates to a process for their production and to their use.

    摘要翻译： 本发明涉及粉末状交联聚合物组合物，其含有a）55-99.9重量％的至少一种聚合的烯属不饱和可聚合单体，其含有中和至少25摩尔％的酸基团，b）0-40 可与a），c）0.01-5.0重量％，优选0.1-2.0重量％的一种或多种交联剂共聚的聚合不饱和单体的重量％，d）0-30重量％ 水溶性聚合物，其重量量a）至d）以无水聚合物组合物为基准，并且这些组分的总和总是100重量％，该组合物可通过连续聚合获得，其中至少一个偏压聚合的参数 根据重复的模式而变化。 本发明还涉及其生产和使用的方法。

    Powdery polymers capable of absorbing aqueous liquids, a process for their production and their use as absorbents
    9.
    发明授权
    Powdery polymers capable of absorbing aqueous liquids, a process for their production and their use as absorbents 失效
    能够吸收含水液体的粉状聚合物，其制备方法及其作为吸收剂的用途

    公开(公告)号：US5672633A

    公开(公告)日：1997-09-30

    申请号：US615249

    申请日：1996-03-26

    申请人： Helmut Brehm ,  Hans-Georg Hartan

    发明人： Helmut Brehm ,  Hans-Georg Hartan

    IPC分类号： G02B6/44 ,  A61F13/49 ,  A61F13/53 ,  A61L15/00 ,  A61L15/24 ,  A61L15/60 ,  B01J20/26 ,  C05G3/00 ,  C05G3/04 ,  C08F2/44 ,  C08F8/00 ,  C08F8/14 ,  C08F8/32 ,  C08F8/44 ,  C08F20/06 ,  C08F20/52 ,  C08F20/58 ,  C08F220/04 ,  C08J7/12 ,  C08L33/02 ,  C09K17/16 ,  C09K17/18 ,  C09K101/00 ,  H01B7/282 ,  C08J9/00

    CPC分类号： C09K17/16 ,  A61L15/24 ,  C05G3/0047 ,  C05G3/04 ,  C08F8/00 ,  C08F8/44 ,  C08L33/02 ,  C08F2810/20

    摘要： The present invention relates to powdery, insoluble, water-swellable, cross-linked polymers absorbing water, aqueous or serous liquids, which are formed of a) 55-99.9%-wt. polymerized unsaturated, polymerizable acid-groups--comprising monomers which are neutralized to the extent of at least 25 mol-%, b) 0-40%-wt. polymerized unsaturated monomers which are co-polymerizable with a), c) 0.1-5.0%-wt. of a cross-linking agent, and d) 0-30%-wt. of a water-soluble polymer, with the weight amounts of a) to d) being relative to anhydrous polymer, and the polymer powder is heated with an at least bifunctional compound reactive with acid groups to a temperature of 150.degree. C.-250.degree. C. under cross-linkage of the surface, and the polymer powder that is thus already surface-cross-linked is subjected to a repeated surface-cross-linking treatment using an at least bifunctional compound reactive with acid groups at a temperature of 150.degree. to 250.degree. C. The present invention further relates to a process for the production of these polymers and to their use as absorbents for water and aqueous liquids, in particular in constructions for the absorption of body fluids, and in current-conducting or light-transmitting cables, as component in packing materials, as soil improver, and as artificial soil for plant breeding.

    摘要翻译： PCT No.PCT / EP94 / 03153 Sec。 371日期：1996年3月26日 102（e）1996年3月26日PCT PCT 1994年9月21日PCT公布。 第WO95 / 09014号公报 日期1995年04月6日本发明涉及吸收水，水或液体液体的粉末状，不溶性，水溶胀性交联聚合物，其由a）55-99.9重量％ 聚合的不饱和的，可聚合的含酸基团的单体，其被中和到至少25摩尔％的程度，b）0-40重量％ 与a）共可共聚的聚合不饱和单体，c）0.1-5.0重量％ 的交联剂，和d）0-30重量％ 的水溶性聚合物，a）至d）的重量相对于无水聚合物，并且将聚合物粉末与至少具有与酸基反应的双官能化合物加热至150℃-250℃的温度 在表面的交联下，将已经表面交联的聚合物粉末在150℃的温度下使用至少具有与酸基反应的双官能化合物进行重复的表面交联处理 本发明还涉及一种生产这些聚合物的方法及其作为水和含水液体的吸收剂的用途，特别是用于吸收体液的结构，以及在导电或发光的过程中， 传输电缆作为包装材料的组分，作为土壤改良剂，以及作为植物育种的人造土壤。