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1.发明授权Method and apparatus for converting hydrocarbon fuel into hydrogen gas and carbon dioxide 失效将烃燃料转化为氢气和二氧化碳的方法和装置
公开(公告)号：US6126908A
公开(公告)日：2000-10-03
申请号：US703398
申请日：1996-08-26
CPC分类号： H01M8/0631 , B01J8/0278 , B01J8/0285 , B01J8/0465 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , C01B3/382 , C01B3/384 , C01B3/48 , H01M8/0612 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0455 , C01B2203/0465 , C01B2203/0485 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1205 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/80 , C01B2203/82 , H01M2250/20 , Y02T90/32
摘要： An apparatus and a method are disclosed for converting hydrocarbon fuel or an alcohol into hydrogen gas and carbon dioxide. The apparatus includes a first vessel having a partial oxidation reaction zone and a separate steam reforming reaction zone that is distinct from the partial oxidation reaction zone. The first vessel has a first vessel inlet at the partial oxidation reaction zone and a first vessel outlet at the steam reforming zone. The reformer also includes a helical tube extending about the first vessel. The helical tube has a first end connected to an oxygen-containing source and a second end connected to the first vessel at the partial oxidation reaction zone. Oxygen gas from an oxygen-containing source can be directed through the helical tube to the first vessel. A second vessel having a second vessel inlet and second vessel outlet is annularly disposed about the first vessel. The helical tube is disposed between the first vessel and the second vessel and gases from the first vessel can be directed through second vessel.
摘要翻译： 公开了用于将烃燃料或醇转化为氢气和二氧化碳的装置和方法。 该装置包括具有部分氧化反应区和与该部分氧化反应区不同的单独蒸汽重整反应区的第一容器。 第一容器在部分氧化反应区具有第一容器入口，在蒸汽重整区具有第一容器出口。 重整器还包括围绕第一容器延伸的螺旋管。 螺旋管具有连接到含氧源的第一端和在部分氧化反应区连接到第一容器的第二端。 来自含氧源的氧气可以通过螺旋管引导到第一容器。 具有第二容器入口和第二容器出口的第二容器围绕第一容器环形地设置。 螺旋管设置在第一容器和第二容器之间，并且来自第一容器的气体可以被引导通过第二容器。
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公开(公告)号：US06245303B1
公开(公告)日：2001-06-12
申请号：US09006727
申请日：1998-01-14
IPC分类号： B01J802
CPC分类号： H01M8/0631 , B01J8/0411 , B01J8/0496 , B01J2208/00026 , B01J2208/00203 , B01J2208/00309 , B01J2208/00495 , C01B3/323 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0288 , C01B2203/066 , C01B2203/0844 , C01B2203/0883 , C01B2203/1011 , C01B2203/1035 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1217 , C01B2203/1235 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/82 , Y02P20/52
摘要： A reformer reactor 10 for producing a hydrogen-rich gas includes a first zone 18, a second zone 20, a third zone 22, a fourth zone 24 and a product gas collection space 40. The zones are sequentially adjacent. A flow path P1 is provided for directing flow of a reaction stream in diverging directions from the first zone 18 into the second zone 20, the flow of the reaction stream continuing in the same general diverging directions through the second zone 20 and into and through the third and fourth zones 22,24. Directing the flow in diverging directions permits flow into and through a zone over more than just a single cross-sectional geometry of the zone or a single cross-section of the flow path transverse to the direction of flows. This configuration can be used to require a lower pressure for flowing the reaction stream so as to reduce the parasitic requirements of the reactor. This configuration can also be used to increase throughput of the reactor.
摘要翻译： 用于生产富氢气体的重整器反应器10包括第一区域18，第二区域20，第三区域22，第四区域24和产物气体收集空间40.区域依次相邻。 提供流路P1，用于引导反应流从第一区18向第二区20发散的方向的流动，反应流的流动以相同的一般发散方向连续通过第二区20并进入并通过 第三和第四区域22,24。 沿着发散方向引导流动允许流过并穿过区域超过该区域的单个横截面几何形状或横向于流动方向的流动路径的单个横截面。 这种配置可以用于要求较低的压力以使反应流流动，以便减少反应器的寄生要求。 该配置也可用于增加反应器的生产量。
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3.发明授权
公开(公告)号：US6083425A
公开(公告)日：2000-07-04
申请号：US184387
申请日：1998-11-02
IPC分类号： B01J8/02 , B01J8/04 , C01B3/38 , C01B3/48 , H01M8/06 , C07C1/02 , C01B3/00 , C01B3/22 , C01B3/24 , C01B3/26 , C01B31/20
CPC分类号： H01M8/0631 , B01J8/0278 , B01J8/0285 , B01J8/0465 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , C01B3/382 , C01B3/384 , C01B3/48 , H01M8/0612 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0455 , C01B2203/0465 , C01B2203/0485 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1205 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/80 , C01B2203/82 , H01M2250/20 , Y02T90/32
摘要： A method for converting hydrocarbon fuel into hydrogen gas and carbon dioxide within a reformer 10 is disclosed. According to the method, a stream including an oxygen-containing gas is directed adjacent to a first vessel 18 and the oxygen-containing gas is heated. A stream including unburned fuel is introduced into the oxygen-containing gas stream to form a mixture including oxygen-containing gas and fuel. The mixture of oxygen-containing gas and unburned fuel is directed tangentially into a partial oxidation reaction zone 24 within the first vessel 18. The mixture of oxygen-containing gas and fuel is further directed through the partial oxidation reaction zone 24 to produce a heated reformate stream including hydrogen gas and carbon monoxide. Steam may also be mixed with the oxygen-containing gas and fuel, and the reformate stream from the partial oxidation reaction zone 24 directed into a steam reforming zone 26. High- and low-temperature shift reaction zones 64,76 may be employed for further fuel processing.
摘要翻译： 公开了一种在重整器10内将烃类燃料转化为氢气和二氧化碳的方法。 根据该方法，将包含含氧气体的物流定向在第一容器18附近，并加热含氧气体。 将含有未燃燃料的物流引入含氧气体流中以形成包含含氧气体和燃料的混合物。 含氧气体和未燃燃料的混合物切向地引导到第一容器18内的部分氧化反应区24中。含氧气体和燃料的混合物进一步通过部分氧化反应区24引导，以产生加热的重整产物 流包括氢气和一氧化碳。 蒸汽也可以与含氧气体和燃料混合，并且来自部分氧化反应区24的重整产物流导入蒸汽重整区26.高温和低温转化反应区64,76可用于进一步 燃料加工。
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公开(公告)号：US06783742B2
公开(公告)日：2004-08-31
申请号：US09872166
申请日：2001-06-01
IPC分类号： B01J802
CPC分类号： H01M8/0631 , B01J8/0411 , B01J8/0496 , B01J2208/00026 , B01J2208/00203 , B01J2208/00309 , B01J2208/00495 , C01B3/323 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0288 , C01B2203/066 , C01B2203/0844 , C01B2203/0883 , C01B2203/1011 , C01B2203/1035 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1082 , C01B2203/1094 , C01B2203/1217 , C01B2203/1235 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/82 , Y02P20/52
摘要： A reformer for producing a hydrogen-rich gas includes a first zone, a second zone, a third zone, a fourth zone and a product gas collection space. The zones are sequentially adjacent. A flow path is provided for directing flow of a reaction stream in diverging directions from the first zone into the second zone, and continuing in the same general diverging directions through the second zone, third zone, and fourth zone. Directing the flow in diverging directions permits flow into and through a zone over more that just a single cross-sectional geometry of the zone or a single cross-section of the flow path transverse to the direction of flows. This configuration can be used to require a lower pressure for flowing the reaction stream so as to reduce the parasitic requirements of the reactor, and can also be used to increase throughput of the reactor.
摘要翻译： 用于生产富氢气体的重整器包括第一区域，第二区域，第三区域，第四区域和产物气体收集空间。 这些区域依次相邻。 提供流动路径用于引导反射流的流动从发散方向从第一区进入第二区，并且沿相同的一般发散方向通过第二区，第三区和第四区。 沿着发散方向引导流动允许流入和穿过区域，只有该区域的单个横截面几何形状或横向于流动方向的流动路径的单个横截面。 该配置可用于要求较低的压力以使反应流流动，以便减少反应器的寄生要求，并且还可用于增加反应器的生产量。
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5.发明授权公开(公告)号：US06207122B1
公开(公告)日：2001-03-27
申请号：US09184615
申请日：1998-11-02
IPC分类号： C01B3118
CPC分类号： H01M8/0631 , B01J8/0278 , B01J8/0285 , B01J8/0465 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B3/382 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0455 , C01B2203/0465 , C01B2203/0485 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1205 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/80 , C01B2203/82 , H01M8/0612 , H01M2250/20 , Y02T90/32
摘要： A hydrocarbon fuel reforming method is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first mixture of an oxygen-containing gas and a first fuel is directed into a first tube 108 to produce a first reaction reformate. A second mixture of steam and a second fuel is directed into a second tube 116 annularly disposed about the first tube 108 to produce a second reaction reformate. The first and second reaction reformates are then directed into a reforming zone 144 and subject to a catalytic reforming reaction. In another aspect of the method, a first fuel is combusted with an oxygen-containing gas in a first zone 108 to produce a reformate stream, while a second fuel under steam reforming in a second zone 116. Heat energy from the first zone 108 is transferred to the second zone 116.
摘要翻译： 公开了一种烃燃料重整方法，适用于通过与烃燃料，氧气和蒸汽的反应来生产合成氢气。 将含氧气体和第一燃料的第一混合物引入第一管108以产生第一反应重整产物。 蒸汽和第二燃料的第二混合物被引导到围绕第一管108环形设置的第二管116中以产生第二反应重整产物。 然后将第一和第二反应重整产物导入重整区144并进行催化重整反应。 在该方法的另一方面，第一燃料在第一区域108中与含氧气体一起燃烧以产生重整产物流，而第二燃料在第二区域116内在蒸汽重整下形成。来自第一区域108的热能为 转移到第二区116。
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公开(公告)号：US07066973B1
公开(公告)日：2006-06-27
申请号：US09562787
申请日：2000-05-02
CPC分类号： B01J8/0469 , B01J8/0465 , B01J8/048 , B01J8/0488 , B01J8/0496 , B01J19/0046 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0288 , C01B2203/044 , C01B2203/045 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/0894 , C01B2203/1058 , C01B2203/1229 , C01B2203/1235 , C01B2203/127 , C01B2203/1276 , C01B2203/146 , C01B2203/1604 , C01B2203/1614 , C01B2203/1685 , C01B2203/169 , C01B2203/82
摘要： A hydrocarbon fuel reformer for producing diatomic hydrogen gas is disclosed. The reformer includes a first reaction vessel, a shift reactor vessel annularly disposed about the first reaction vessel, including a first shift reactor zone, and a first helical tube disposed within the first shift reactor zone having an inlet end communicating with a water supply source. The water supply source is preferably adapted to supply liquid-phase water to the first helical tube at flow conditions sufficient to ensure discharge of liquid-phase and steam-phase water from an outlet end of the first helical tube. The reformer may further include a first catalyst bed disposed in the first shift reactor zone, having a low-temperature shift catalyst in contact with the first helical tube. The catalyst bed includes a plurality of coil sections disposed in coaxial relation to other coil sections and to the central longitudinal axis of the reformer, each coil section extending between the first and second ends, and each coil section being in direct fluid communication with at least one other coil section.
摘要翻译： 公开了一种用于生产双原子氢气的碳氢化合物燃料重整器。 重整器包括第一反应容器，围绕第一反应容器环状设置的换档反应器容器，包括第一变换反应器区，以及布置在第一变换反应器区内的第一螺旋管，其具有与供水源连通的入口端。 供水源优选地适于在足以确保从第一螺旋管的出口端排出液相和蒸汽相水的流动条件下向第一螺旋管供应液相水。 重整器还可以包括设置在第一变换反应器区中的第一催化剂床，其具有与第一螺旋管接触的低温变换催化剂。 催化剂床包括多个线圈段，其设置成与其它线圈段和重整器的中心纵向轴线同轴，每个线圈段在第一和第二端之间延伸，并且每个线圈段至少直接流体连通 另一个线圈部分。
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公开(公告)号：US06986797B1
公开(公告)日：2006-01-17
申请号：US09565288
申请日：2000-05-02
申请人： Lawrence G. Clawson , Matthew H. Dorson , William L. Mitchell , Brian J. Nowicki , Jeffrey M. Bentley , Robert Davis , Jennifer W. Rumsey
发明人： Lawrence G. Clawson , Matthew H. Dorson , William L. Mitchell , Brian J. Nowicki , Jeffrey M. Bentley , Robert Davis , Jennifer W. Rumsey
IPC分类号： C10J3/00
CPC分类号： C01B3/48 , B01J19/0013 , B01J2219/00006 , B01J2219/00157 , B01J2219/00159 , C01B2203/0244 , C01B2203/0288 , C01B2203/044 , C01B2203/047 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0844 , C01B2203/142 , C01B2203/146 , C01B2203/82 , Y02P20/128
摘要： An auxiliary reactor for use with a reformer reactor having at least one reaction zone, and including a burner for burning fuel and creating a heated auxiliary reactor gas stream, and heat exchanger for transferring heat from auxiliary reactor gas stream and heat transfer medium, preferably two-phase water, to reformer reaction zone. Auxiliary reactor may include first cylindrical wall defining a chamber for burning fuel and creating a heated auxiliary reactor gas stream, the chamber having an inlet end, an outlet end, a second cylindrical wall surrounding first wall and a second annular chamber there between. The reactor being configured so heated auxiliary reactor gas flows out the outlet end and into and through second annular chamber and conduit which is disposed in second annular chamber, the conduit adapted to carry heat transfer medium and being connectable to reformer reaction zone for additional heat exchange.
摘要翻译： 一种用于具有至少一个反应区的重整器反应器的辅助反应器，并且包括用于燃烧燃料并产生加热的辅助反应器气流的燃烧器，以及用于从辅助反应器气流和传热介质传递热量的热交换器，优选两个 相水，重整反应区。 辅助反应器可以包括限定用于燃烧燃料并产生加热的辅助反应器气流的室的第一圆柱形壁，所述室具有入口端，出口端，围绕第一壁的第二圆柱形壁和其间的第二环形室。 反应器被配置为如此加热的辅助反应器气体流出出口端并进入并通过设置在第二环形室中的第二环形室和导管，导管适于承载传热介质并且可连接到重整器反应区以进行额外的热交换 。
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8.发明授权
公开(公告)号：US6123913A
公开(公告)日：2000-09-26
申请号：US185325
申请日：1998-11-03
CPC分类号： H01M8/0631 , B01J8/0278 , B01J8/0285 , B01J8/0465 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , C01B3/382 , C01B3/384 , C01B3/48 , H01M8/0612 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0455 , C01B2203/0465 , C01B2203/0485 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1205 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/80 , C01B2203/82 , H01M2250/20 , Y02T90/32
摘要： A method is disclosed for synthesizing hydrogen gas from hydrocarbon fuel. A first mixture of steam and a first fuel is directed into a first tube 208 to subject the first mixture to a first steam reforming reaction in the presence of a first catalyst 214. A stream of oxygen-containing gas is pre-heated by transferring heat energy from product gases. A second mixture of the pre-heated oxygen-containing gas and a second fuel is directed into a second tube 218 disposed about the first tube 208 to subject the second mixture to a partial oxidation reaction and to provide heat energy for transfer to the first tube 208. A first reaction reformate from the first tube 208 and a second reaction reformate from the second tube 218 are directed into a third tube 224 disposed about the second tube 218 to subject the first and second reaction reformates to a second steam reforming reaction, wherein heat energy is transferred to the third tube 224 from the second tube 218.
摘要翻译： 公开了一种从烃燃料合成氢气的方法。 蒸汽和第一燃料的第一混合物被引导到第一管208中，以在第一催化剂214的存在下使第一混合物进行第一蒸汽重整反应。通过传递热量来预热含氧气体流 来自产品气体的能量。 预热的含氧气体和第二燃料的第二混合物被引导到围绕第一管208设置的第二管218中，以使第二混合物进行部分氧化反应并提供用于转移到第一管的热能 208.来自第一管208的第一反应重整产物和来自第二管218的第二反应重整产物被引导到围绕第二管218设置的第三管224中，以使第一和第二反应重整产物进行第二蒸汽重整反应，其中 热能从第二管218转移到第三管224。
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9.发明授权公开(公告)号：US06468480B1
公开(公告)日：2002-10-22
申请号：US09184618
申请日：1998-11-02
IPC分类号： B01J800
CPC分类号： H01M8/0631 , B01J8/0278 , B01J8/0285 , B01J8/0465 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B3/382 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0455 , C01B2203/0465 , C01B2203/0485 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1205 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/80 , C01B2203/82 , H01M8/0612 , H01M2250/20 , Y02T90/32
摘要： Hydrocarbon fuel reformer 100 suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. A first tube 108 has a first tube inlet 110 and a first tube outlet 112. The first tube inlet 110 is adapted for receiving a first mixture including an oxygen-containing gas and a first fuel. A partially oxidized first reaction reformate is directed out of the first tube 108 into a mixing zone 114. A second tube 116 is annularly disposed about the first tube 108 and has a second tube inlet 118 and a second tube outlet 120. The second tube inlet 118 is adapted for receiving a second mixture including steam and a second fuel. A steam reformed second reaction reformate is directed out of the second tube 116 and into the mixing zone 114. From the mixing zone 114, the first and second reaction reformates may be directed into a catalytic reforming zone 144 containing a reforming catalyst 147.
摘要翻译： 烃燃料重整器100适用于从与烃燃料，氧气和蒸汽的反应产生合成氢气。 第一管108具有第一管入口110和第一管出口112.第一管入口110适于接收包括含氧气体和第一燃料的第一混合物。 将部分氧化的第一反应重整油从第一管108引出到混合区114.第二管116围绕第一管108环形设置并具有第二管入口118和第二管出口120.第二管入口 118适于接收包括蒸汽和第二燃料的第二混合物。 蒸汽重整的第二反应重整产物从第二管116引出并进入混合区114.从混合区114可以将第一和第二反应重整产物引入含有重整催化剂147的催化重整区144中。
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10.发明授权公开(公告)号：US06254839B1
公开(公告)日：2001-07-03
申请号：US09185393
申请日：1998-11-03
IPC分类号： B01J804
CPC分类号： H01M8/0631 , B01J8/0278 , B01J8/0285 , B01J8/0465 , B01J8/0469 , B01J8/048 , B01J8/0492 , B01J8/0496 , B01J2208/00203 , B01J2208/0053 , B01J2208/00849 , C01B3/382 , C01B3/384 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/0288 , C01B2203/0455 , C01B2203/0465 , C01B2203/0485 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1047 , C01B2203/1052 , C01B2203/1064 , C01B2203/1076 , C01B2203/1205 , C01B2203/1223 , C01B2203/1229 , C01B2203/1241 , C01B2203/1247 , C01B2203/1258 , C01B2203/1276 , C01B2203/141 , C01B2203/142 , C01B2203/80 , C01B2203/82 , H01M8/0612 , H01M2250/20 , Y02T90/32
摘要： A hydrocarbon fuel reformer (200) is disclosed suitable for producing synthesis hydrogen gas from reactions with hydrocarbons fuels, oxygen, and steam. The reformer (200) comprises first and second tubes (208,218). The first tube (208) includes a first catalyst (214) and receives a first mixture of steam and a first fuel. The second tube (218) is annularly disposed about the first tube (208) and receives a second mixture of an oxygen-containing gas and a second fuel. In one embodiment, a third tube (224) is annularly disposed about the second tube (218) and receives a first reaction reformate from the first tube (208) and a second reaction reformate from the second tube (218). A catalyst reforming zone (260) annularly disposed about the third tube (224) may be provided to subject reformate constituents to a shift reaction. In another embodiment, a fractionator is provided to distill first and second fuels from a fuel supply source.
摘要翻译： 公开了一种烃燃料重整器（200），其适用于通过与烃燃料，氧气和蒸汽的反应产生合成氢气。 重整器（200）包括第一和第二管（208,218）。 第一管（208）包括第一催化剂（214）并且接收蒸汽和第一燃料的第一混合物。 第二管（218）环绕第一管（208）设置并接收含氧气体和第二燃料的第二混合物。 在一个实施例中，第三管（224）围绕第二管（218）环形设置，并且从第一管（208）接收第一反应重整产物，并从第二管（218）接收第二反应重整产物。 可以提供围绕第三管（224）环形设置的催化剂重整区（260），以使重整产物成分转化为转化反应。 在另一个实施例中，提供分馏器以从燃料供应源蒸馏第一和第二燃料。
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