摘要:
A fuel processing system is operable to remove substantially all of the sulfur present in an undiluted hydrocarbon fuel stock supply used to power a fuel cell power plant in a mobile environment, such as an automobile, bus, truck, boat, or the like, or in a stationary environment. The power plant hydrogen fuel source can be gasoline, diesel fuel, naphtha, light hydrocarbon fuels such as butane, propane, natural gas, or other like fuels which contain relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, and the like. The undiluted hydrocarbon fuel supply is passed through a nickel desulfurizer bed wherein essentially all of the sulfur in the organic sulfur compounds react with the nickel reactant, and are converted to nickel sulfide while the desulfurized organic remnants continue through the remainder of the fuel processing system. The system does not require the addition of steam or a hydrogen source to the fuel stream prior to the desulfurizing step. The system operates at relatively low temperatures and can be used to desulfurize either a liquid or a gaseous fuel stream.
摘要:
A fuel processing system is operable to remove substantially all of the sulfur present in an undiluted hydrocarbon fuel stock supply used to power a fuel cell power plant in a mobile environment, such as an automobile, bus, truck, boat, or the like, or in a stationary environment. The power plant hydrogen fuel source can be gasoline, diesel fuel, naphtha, light hydrocarbon fuels such as butane, propane, natural gas, or other like fuels which contain relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, and the like. The undiluted hydrocarbon fuel supply is passed through a nickel desulfurizer bed wherein essentially all of the sulfur in the organic sulfur compounds react with the nickel reactant, and are converted to nickel sulfide while the desulfurized organic remnants continue through the remainder of the fuel processing system. The system does not require the addition of steam or a hydrogen source to the fuel stream prior to the desulfurizing step. The system operates at relatively low temperatures and can be used to desulfurize either a liquid or a gaseous fuel stream.
摘要:
A fuel gas processing system is operable to remove substantially all of the sulfur present in a hydrocarbon fuel supply used to power a fuel cell power plant in a mobile vehicular environment. The power plant fuel can be gasoline, diesel fuel, kerosene, fuel oil, natural gas, or another fuel which contains relatively high levels of organic sulfur compounds such as mercaptans, sulfides, disulfides, and the like. The hydrocarbon fuel supply is passed through a nickel reactant desulfurizer bed wherein essentially all of the sulfur in the organic sulfur compounds react with the nickel reactant, and are converted to nickel sulfide while the desulfurized fuel continues through the remainder of the fuel processing system. The fuel cell power plant and the processing system can be used to power a mobile vehicle, such an automobile, truck, bus, or the like. An auxiliary supply of hydrogen is provided in order to power the fuel cell power plant during start up of the fuel processing system. A second auxiliary supply of desulfurized fuel is also provided to operate the fuel cell power plant during an interim period until the highest temperature component of the fuel processing system is brought up to operational temperatures during the start up protocol.
摘要:
The invention is a reformate fuel treatment system for a fuel cell power plant that includes at least one fuel cell for generating electricity from process oxidant and reducing fluid reactant streams; fuel processing components including a steam supply and a reformer for producing a hydrogen enriched reformate fuel for the fuel cell from a hydrocarbon fuel; and, an ammonia removal apparatus that treats the reformate fuel to make it appropriate for supplying hydrogen to an anode electrode of the fuel cell. The ammonia removal apparatus may be a disposable ammonia scrubber, an ammonia scrubbing cool water bed and an ammonia stripping warm water bed, a pair of first and second regenerable scrubbers, or a single regenerable ammonia scrubber.
摘要:
A fuel gas catalyst bed for use in a fuel cell power plant is formed from a monolithic open cell foam component, the open cell lattice of which forms gas passages through the catalyst bed. The monolithic component has a lattice of internal open cells which are both laterally and longitudinally interconnected so as to produce a diffuse gas flow pattern through the catalyst bed. All areas of the monolithic component which form the gas flow pattern are provided with an underlying high porosity wash coat layer. The porous surface of the wash coat layer is provided with a nickel catalyst layer, or a noble metal catalyst layer, such as platinum, rhodium, palladium, or the like, over which the gas stream being treated flows. The base foam lattice can be a metal such as aluminum, stainless steel, a steel-aluminum alloy, a nickel alloy, a ceramic, or the like material which can be wash coated. The use of an open cell lattice as the basis of a catalyst bed enables the formation of very compact, light weight and high surface area catalyst bed with excellent gas flow-through characteristics.
摘要:
A fuel processing system is operable to remove substantially all of the sulfur present in gasoline or diesel fuel used for operating an internal combustion engine. The fuel supply is passed through a nickel reactant desulfurizer bed wherein essentially all of the sulfur in organic sulfur compounds in the fuel combine with the nickel reactant in the desulfurizer bed, and are converted to nickel sulfide. The desulfurizing system can operate at ambient or elevated pressures. The fuel can be treated either in a liquid phase or in a vapor phase. The sulfur scrubbing operation can be performed either in a vehicle while the latter is being operated, or at the fueling station (gas station) prior to sale to the end user. The amount of sulfur in the fuel can be lowered to less than about 0.05 ppm. This extends the life of the catalytic converters in vehicles, reduces corrosion of parts of the internal combustion engine, and provides an environmentally compatible system.
摘要:
A method of forming thin, uniform braze joints is effected through the use of curtain coating. Braze powder is admixed with a liquid polymeric binder to form a slurry. The slurry is forced through the slots in a curtain coating head and deposited on at least one of the metal surfaces to be bonded together. The method has particular utility for bonding fin/plate sections of a heat exchanger where the fins have a U-shaped cross section. The slurry is deposited on the top portion of the fin and the side portion of the fin and wiped from the top portion leaving braze material primarily on the side wall portion. When the plates are contacted to the fins and heating performed, a bond is effected with maximum plate-to-fin contact for high heat transfer and a strong braze joint.
摘要:
A PEM fuel cell system includes a PEM fuel cell that has an input and output port each for fuel or reformate, process air and coolant. A predetermined fraction of volume of moistened exhaust air leaving the air output port of the fuel cell is diverted back and combined with fresh, air at ambient temperature entering the air input port of the PEM fuel cell to maintain water balance in the fuel cell at high ambient operating temperatures. The recycle-to-air vent ratio is controlled by a processor which adjusts the recycle flow based on the ambient temperature and the power level of the fuel cell.