摘要:
Structured automotive catalysts which comprise a plurality of different catalytically active coatings arranged above one another on a support body and whose coatings contain transition metals and porous support materials are well known. Structured automotive catalysts of this type which do not belong to the group of three-way catalysts, in particular, frequently display large selectivity losses after thermal aging processes which can be attributed to the thermally induced migration of transition metal atoms from one layer into the neighboring coating. The introduction of a diffusion barrier which slows or prevents the thermally induced migration of transition metal atoms from one catalytically active layer into the other increases the thermal aging stability of such catalysts significantly.
摘要:
The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditions takes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion engines extending from 200° C. to 600° C., it has therefore mostly been necessary to use complicated exhaust gas systems containing a plurality of catalysts having different working temperature ranges. Disclosed is a structured SCR catalyst whose working range extends over a significantly broader temperature window and by means of which complicated exhaust gas units can be considerably simplified, with a saving of components.
摘要:
The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditionstakes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion enginesextending from 200° C. to 600° C., it has therefore mostly been necessary to use complicated exhaust gas systemscontaining a plurality of catalysts having different working temperature ranges. Disclosed is a structured SCR catalyst whose working range extends over a significantly broader temperature window and by means of which complicated exhaust gas units can be considerably simplified, with a saving of components.
摘要:
Structured automotive catalysts which comprise a plurality of different catalytically active coatings arranged above one another on a support body and whose coatings contain transition metals and porous support materials are well known. Structured automotive catalysts of this type which do not belong to the group of three-way catalysts, in particular, frequently display large selectivity losses after thermal aging processes which can be attributed to the thermally induced migration of transition metal atoms from one layer into the neighbouring coating. The introduction of a diffusion barrier which slows or prevents the thermally induced migration of transition metal atoms from one catalytically active layer into the other increases the thermal aging stability of such catalysts significantly
摘要:
A catalytically active diesel particulate filter with ammonia trap action is presented, which, in addition to an oxidation-active coating (2), comprises a coating (1) which is catalytically active in the SCR reaction. By means of this inventive diesel particulate filter, it is possible to make exhaust gas aftertreatment systems for removing nitrogen oxides and particulates from the exhaust gas of lean engines considerably simpler and less expensive.
摘要:
An exhaust gas purification system (method and device) for the treatment of diesel exhaust gases containing nitrogen oxides and hydrocarbons is disclosed, which comprises the addition of ammonia or of a compound decomposable to ammonia into the exhaust gas stream and the subsequent leading of the exhaust gas stream over two successively arranged SCR catalysts with different properties and compositions. Both SCR catalysts are free of vanadium compounds and only the downstream SCR catalyst contains zeolite compounds. The exhaust gas purification system according to the invention is characterized by good “kick-off” behavior at low temperatures and a simultaneously high conversion performance over a wide temperature range.
摘要:
An exhaust gas purification system (method and device) for the treatment of diesel exhaust gases containing nitrogen oxides and hydrocarbons is disclosed, which comprises the addition of ammonia or of a compound decomposable to ammonia into the exhaust gas stream and the subsequent leading of the exhaust gas stream over two successively arranged SCR catalysts with different properties and compositions. Both SCR catalysts are free of vanadium compounds and only the downstream SCR catalyst contains zeolite compounds. The exhaust gas purification system according to the invention is characterized by good “kick-off” behavior at low temperatures and a simultaneously high conversion performance over a wide temperature range.
摘要:
A catalytically active diesel particulate filter with ammonia trap action is presented, which, in addition to an oxidation-active coating (2), comprises a coating (1) which is catalytically active in the SCR reaction. By means of this inventive diesel particulate filter, it is possible to make exhaust gas aftertreatment systems for removing nitrogen oxides and particulates from the exhaust gas of lean engines considerably simpler and less expensive.
摘要:
In exhaust gas purification units for decreasing nitrogen oxides in lean-burn exhaust gas of internal combustion engines by selective catalytic reduction by means of ammonia, introduction of excess ammonia leads to undesirable emissions of unused ammonia. These emissions can be decreased by means of ammonia barrier catalysts. In the ideal case, ammonia is oxidized to nitrogen and water by these catalysts. These require additional space in the exhaust gas purification unit which may have to be taken away from the space provided for the SCR main catalyst. In addition, the use of such ammonia barrier catalysts can result in overoxidation of the ammonia to nitrogen oxides.To overcome these disadvantages, a catalyst containing two superposed layers is proposed for the removal of nitrogen-containing pollutant gases from diesel exhaust gas. The lower layer contains an oxidation catalyst and the upper layer can store at least 20 milliliters of ammonia per gram of catalyst material. This catalyst displays reduced ammonia breakthrough at good SCR conversions in the low-temperature range. It can be used as SCR catalyst having reduced ammonia breakthrough or as ammonia barrier catalyst.
摘要:
In order to ensure a simple, reliable and recuperative operation in a hydraulic drive (10) for accelerating and braking a gas exchange valve (20) of internal combustion engines or other reciprocating engines, it is proposed that a first pressure reservoir (41) for providing a first pressure p1 comprises a restoring energy accumulator, preferably configured as a spring (25), and at least one hydraulic base pressure reservoir (40), which has a lower pressure p0 than the first pressure reservoir (41). In a connecting line (48) between the first hydraulic pressure reservoir (41) and the working cylinder (22), a controllable opening (49) of a first valve (46) comprising at least one check valve (47) is arranged upstream or downstream in the flow path, which allows the pressure medium (30) to flow in the direction of working cylinder (22), but prevents a backflow towards the pressure reservoir (41). In order to also initiate the closing movement or to enable the breaking of the gas exchange valve in a hydraulically simple and reliable manner, in a second connecting line (58) between the first pressure reservoir (41) and the working cylinder (22) there is arranged a controllable opening (59) of a second valve (56) comprising a check valve (57), which prevents a flow in the direction of the working cylinder (22), but allows a return flow in the direction of the pressure reservoir (41).