摘要:
An exhaust gas purification material according to the present invention is provided with a particulate filter 10 that traps particulate matter in exhaust gas and contains an SCR catalyst for adsorbing ammonia and reducing NOx in the exhaust gas. A maximum allowable adsorption amount of ammonia adsorbable by the filter 10 differs between an upstream portion 10a of the filter 10 including an exhaust gas inlet-side end 10c, and a downstream portion 10b of the filter 10 including an exhaust gas outlet-side end 10d. The SCR catalyst contained in the upstream portion 10a and the SCR catalyst contained in the downstream portion 10b are qualitatively different. A ratio (B/A) of a maximum allowable adsorption amount of ammonia A in the upstream portion 10a and a maximum allowable adsorption amount of ammonia B in the downstream portion 10b satisfies the relationship 1.1≤(B/A)≤2.
摘要:
An object is to provide technology that enables an NOx catalyst to exercise its NOx reduction capability satisfactorily at any flow speed of the exhaust gas flowing into the NOx catalyst. An exhaust gas purification apparatus for an internal combustion engine includes a selective catalytic reduction NOx catalyst including at least a first catalyst layer having capability of reducing NOx and a second catalyst layer having oxidation capability and arranged closer to a catalyst substrate than the first catalyst layer. The apparatus has a supply valve for adding a specific addition quantity of reducing agent for reducing NOx to inflowing exhaust gas flowing into the selective catalytic reduction NOx catalyst. The apparatus further has a controller that is configured to control addition of the reducing agent by the supply valve based on the flow speed of the inflowing exhaust gas in such a way that the concentration of the reducing agent in a reducing agent atmosphere formed in the inflowing exhaust gas in a reducing agent addition period becomes equal to a specific concentration that is determined based on the flow speed of the inflowing exhaust gas and at which the reducing agent is assumed not to reach the second catalyst layer, when the temperature of the selective catalytic reduction NOx catalyst exceeds a specific temperature at which reduction of NOx by the first catalyst layer is carried out.
摘要:
Catalysts having a blend of platinum on a support with low ammonia storage with a Cu-SCR catalyst or an Fe-SCR catalyst are disclosed. The catalysts can also contain one or two additional SCR catalysts. The catalysts can be present in one of various configurations. Catalytic articles containing these catalysts are disclosed. The catalytic articles are useful for selective catalytic reduction (SCR) of NOx in exhaust gases and in reducing the amount of ammonia slip. Methods for producing such articles are described. Methods of using the catalytic articles in an SCR process, where the amount of ammonia slip is reduced, are also described.
摘要:
An amount of electric power consumption by a battery is reduced, and deterioration of a coil is suppressed by efficiently heating an injector and melting urea crystals at an early stage.A control device for a reducing agent injection device fills the device with a reducing agent at a start-up of an internal combustion engine and executes control for injecting the reducing agent into an exhaust passage of the internal combustion engine by the injector. The control device includes an energization control section that executes energization control in which, after an exhaust temperature of the internal combustion engine becomes equal to or higher than a specified threshold value, a temperature of the injector is increased by energizing the coil of the injector for a specified time and melting of the crystals of the reducing agent precipitated in the injector is promoted.
摘要:
Unique SCR catalyst including multiple washcoat formulations with differing performance characteristics are disclosed. One exemplary embodiment is an apparatus including a catalyst substrate defining a plurality of flow channels leading from an inlet to an outlet, a first washcoat composition distributed over a first portion of the flow channels, and a second washcoat composition distributed over a second portion of the flow channels. The first washcoat composition has a lower ammonia storage density than the second washcoat composition.
摘要:
An exhaust aftertreatment system configured to reduce nitrous oxide (N2O) formation includes a first selective catalytic reduction (SCR) catalyst. The first SCR catalyst is configured for low N2O formation and low ammonia (NH3) storage capacity. A second SCR catalyst is positioned downstream of the first SCR catalyst. The second SCR catalyst is configured for high NH3 storage capacity.
摘要:
A method for an exhaust-gas aftertreatment system which is operated on an internal combustion engine operated with an excess of air, in which exhaust-gas aftertreatment system soot particles are separated out of exhaust gas by a particle filter and the particle filter is regenerated with the aid of NO2 formed on an NO oxidation catalytic converter mounted upstream of the particle filter. A reduction of the nitrogen oxides is realized by a reducing agent which splits to form ammonia being metered into the exhaust-gas flow upstream of the particle filter and the particle filter is laden with a catalytically active material for the selective catalytic reduction of nitrogen oxides. The NH3 to NOx ratio (feed ratio α) is varied in phases by changing the nitrogen oxide untreated emissions and/or the supplied amount of reducing agent, in such a way that the feed ratio α alternates in phases between values of greater than one and values of less than one.
摘要:
Provided is a system for treating an exhaust gas comprising a first SCR catalyst zone comprising an iron loaded medium- or large-pore molecular sieve having a first ammonia storage capacity; and a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve having a second ammonia storage capacity, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system and wherein the second ammonia storage capacity is greater than the first ammonia storage capacity. Also provided is a method for using the system to treat exhaust gas.
摘要:
A control system includes an upstream nitrogen oxide (NOx) control module that increases an upstream NOx level based on an initial upstream NOx level in an exhaust system, and an ammonia (NH3) storage condition detection module that detects a NH3 storage condition based on a difference in a downstream NOx level before and after the upstream NOx level is increased. A method includes increasing an upstream NOx level based on an initial upstream NOx level in an exhaust system, and detecting an NH3 storage condition based on a difference in a downstream NOx level before and after the upstream NOx level is increased.
摘要:
Described are SCR catalyst systems comprising a first SCR catalyst composition and a second SCR catalyst composition arranged in the system, the first SCR catalyst composition promoting higher N2 formation and lower N2O formation than the second SCR catalyst composition, and the second SCR catalyst composition having a different composition than the first SCR catalyst composition, the second SCR catalyst composition promoting lower N2 formation and higher N2O formation than the first SCR catalyst composition. The SCR catalyst systems are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.