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1.发明授权Polyisocyanates containing ester groups, a process for the production of these polyisocyanates and their use in polyurethane coating compositions 失效含有酯基的聚异氰酸酯，生产这些聚异氰酸酯的方法及其在聚氨酯涂料组合物中的用途
公开(公告)号：US5096994A
公开(公告)日：1992-03-17
申请号：US561770
申请日：1990-08-02
IPC分类号： C07C263/16 , C07C265/04 , C07H13/04 , C08G18/73 , C08G18/77 , C09D175/00 , C09D175/04
CPC分类号： C07H13/04 , C07C265/04 , C08G18/771
摘要： The present invention relates to polyisocyanates which contain ester groups and havea) a content of aliphatically bound isocyanate groups of 18 to 33% by weight,b) an average NCO functionality of 4.1 to 10, preferably from 4.5 to 10, andc) a viscosity of 200 to 2,5000 mPa.s at 22.degree. C.The present invention also relates to preferred polyisocyanates which contain ester groups and havea) a content of aliphatically bound isocyanate groups of 20 to 33% by weight,b) an average NCO functionality of 5 to 8 andc) a viscosity of 500 to 1,000 mPa.s at 22.degree. C.The present invention further relates to a process for the preparation of these preferred polyisocyanates by reacting isocyanatocarboxylic acid chlorides with O-silylated, polyhydric alcohols at a temperature of about 50.degree. to 150.degree. C. Finally, the present invention relates to the use of the polyisocyanates as the isocyanate component for two-component polyurethane coating compositions.
摘要翻译： 本发明涉及含有酯基并且具有以下特征的多异氰酸酯：a）脂肪族结合的异氰酸酯基团的含量为18〜33重量％，b）平均NCO官能度为4.1〜10，优选为4.5〜10，以及c） 22℃下的粘度为200〜25000mPa.s。本发明还涉及优选的含有酯基的多异氰酸酯，其具有a）含有20〜33重量％的脂肪族结合的异氰酸酯基的含量，b）平均 NCO官能度为5至8，和c）在22℃下的粘度为500至1,000mPa.s。本发明还涉及通过使异氰酸酯基羧酸与O-甲硅烷基化的多元醇反应来制备这些优选的多异氰酸酯的方法 在约50℃至150℃的温度下进行。最后，本发明涉及多异氰酸酯作为双组分聚氨酯涂料组合物的异氰酸酯组分的用途。
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2.发明授权Process for the preparation of amines, the amines thus obtained and the use thereof as hardeners for epoxide resins 失效制备氨基酸的方法，获得的氨基酸及其作为环氧化物树脂硬化剂的用途
公开(公告)号：US5219975A
公开(公告)日：1993-06-15
申请号：US696901
申请日：1991-05-07
摘要： The present invention is directed to a process for the preparation of amines containing urethane and urea groups. The amines are produced by reacting A) isocyanate prepolymers containing urethane groups and in which the isocyanate groups are reversibly blocked with secondary monoamines with B) amines having molecular weights of from 60 to 500, which are at least difunctional and which have a total of at least two primary or secondary amino groups, with splitting off of the secondary monoamine. The invention is also directed to the amines so produced and to the use as a hardener for an epoxide resin.
摘要翻译： 本发明涉及一种制备含氨基甲酸酯和脲基的胺的方法。 胺是通过使A）含有氨基甲酸酯基团的异氰酸酯预聚物与其中异氰酸酯基团与二级单胺可逆地封端的B）制备的，B）分子量为60至500的胺，其至少是双官能的，并且总共在 至少两个伯或仲氨基，分离出次级单胺。 本发明还涉及如此制备的胺和用作环氧树脂的硬化剂的用途。
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3.发明授权Process for the preparation of O-silylated hydroxyl compounds and their use for the preparation of isocyanates containing ester groups 失效制备O-硅氧烷化合物的方法及其用于制备含有酯基团的异氰酸酯的方法
公开(公告)号：US5142081A
公开(公告)日：1992-08-25
申请号：US596173
申请日：1990-10-10
申请人： Lutz Schmalstieg , Josef Pedain , Klaus Nachtkamp
发明人： Lutz Schmalstieg , Josef Pedain , Klaus Nachtkamp
IPC分类号： C07F7/18
CPC分类号： C07F7/188
摘要： This present invention relates to a process for the preparation of O-silylated aliphatic hydroxyl, compounds by the reaction of aliphatic hydroxyl compounds with triorganochlorosilanes and removal of the resulting gaseous hydrogen chloride from the reaction mixture, characterized in that the reaction is carried out in the presence of phase transfer catalysts in the absence of solvent.The invention also relates to the use of the O-silylated hydroxyl compounds obtained by this process as starting materials for the preparation of isocyanates containing ester groups by a reaction with isocyanato carboxylic acid chlorides.
摘要翻译： 本发明涉及通过脂族羟基化合物与三有机氯硅烷的反应和从反应混合物中除去所得到的气态氯化氢来制备O-甲硅烷基化的脂族羟基化合物的方法，其特征在于反应在 在不存在溶剂的情况下存在相转移催化剂。 本发明还涉及通过该方法获得的O-甲硅烷基化羟基化合物作为通过与异氰酸根合羧酸氯化物反应制备含酯基的异氰酸酯的起始原料的用途。
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公开(公告)号：US5236741A
公开(公告)日：1993-08-17
申请号：US877682
申请日：1992-05-01
申请人： Christian Zwiener , Josef Pedain , Lothar Kahl , Klaus Nachtkamp
发明人： Christian Zwiener , Josef Pedain , Lothar Kahl , Klaus Nachtkamp
CPC分类号： C08G18/3821 , C08G18/6229 , C08G18/7831 , C08G18/792
摘要： The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2, and curing the coating composition at a temperature of 100.degree. C. or less.
摘要翻译： 本发明涉及通过用包含a）多异氰酸酯组分的涂料组合物涂布基材来制备聚氨酯涂料的方法，和b）含有至少一种对应于下式的化合物的异氰酸酯反应性组分（I ）其中X表示在100℃或更低的温度下具有n价并且对异氰酸酯基团呈惰性的有机基团，R 1和R 2可以相同或不同，表示在一个或多个基团上对于异氰酸酯基团是惰性的有机基团 温度为100℃以下时，R 3和R 4可以相同或不同，表示在100℃以下的温度下对异氰酸酯基具有惰性的氢或有机基团，n表示至少为 并且在100℃或更低的温度下固化涂料组合物。
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公开(公告)号：US5126170A
公开(公告)日：1992-06-30
申请号：US540536
申请日：1990-06-19
申请人： Christian Zwiener , Josef Pedain , Lothar Kahl , Klaus Nachtkamp
发明人： Christian Zwiener , Josef Pedain , Lothar Kahl , Klaus Nachtkamp
IPC分类号： B05D7/24 , C08G18/30 , C08G18/34 , C08G18/38 , C08G18/62 , C08G18/78 , C08G18/79 , C09D175/00 , C09D175/04
CPC分类号： C08G18/6229 , C08G18/3821 , C08G18/7831 , C08G18/792
摘要： The present invention relates to a process for the preparation of a polyurethane coating by coating a substrate with a coating composition containinga) a polyisocyanate component andb) an isocyanate-reactive component containing at least one compound corresponding to the formula ##STR1## wherein X represents an organic group which has a valency of n and is inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.1 and R.sup.2 may be identical or different and represent organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less,R.sup.3 and R.sup.4 may be identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100.degree. C. or less andn represents an integer with a value of at least 2,and curing the coating composition at a temperature of 100.degree. C. or less.
摘要翻译： 本发明涉及通过用包含a）多异氰酸酯组分的涂料组合物涂布基材来制备聚氨酯涂料的方法，和b）含有至少一种对应于下式的化合物的异氰酸酯反应性组分（I ）其中X表示在100℃或更低的温度下具有n价并且对异氰酸酯基团呈惰性的有机基团，R 1和R 2可以相同或不同，表示在一个或多个基团上对于异氰酸酯基团是惰性的有机基团 温度为100℃以下时，R 3和R 4可以相同或不同，表示在100℃以下的温度下对异氰酸酯基具有惰性的氢或有机基团，n表示至少为 并且在100℃或更低的温度下固化涂料组合物。
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公开(公告)号：US5672736A
公开(公告)日：1997-09-30
申请号：US555200
申请日：1995-11-08
申请人： Martin Brahm , Lutz Schmalstieg , Josef Pedain
发明人： Martin Brahm , Lutz Schmalstieg , Josef Pedain
IPC分类号： C07C273/18 , C07C275/60 , C08G18/78 , C09D175/00 , C07C263/00
CPC分类号： C08G18/7837 , C07C275/60
摘要： The present invention relates to a process for preparing polyisocyanates containing allophanate groups by reacting compounds a), which i) contain urethane groups, but which are substantially free of hydroxyl groups and isocyanate groups, ii) have an average of at least two urethane groups per molecule, iii) are prepared by reacting organic isocyanates a1) with organic hydroxyl compounds a2) and iv) have an average molecular weight of at most 2,500, with excess quantities, based on the urethane groups, of distillable organic polyisocyanates b) to form polyisocyanates containing allophanate groups and subsequently removing by distillation the unreacted excess of component b) to a residual content of less than 0.5 wt. %, provided that polyisocyanates a1) and polyisocyanates b) are different. The present invention also relates to the products obtained from this process and to their use as binders or binder components in coating compositions.
摘要翻译： 本发明涉及通过使具有氨基甲酸酯基但不含羟基和异氰酸酯基的化合物a）反应制备含有脲基甲酸酯基团的多异氰酸酯的方法，ii）基本上不含羟基和异氰酸酯基团，ii）平均具有至少两个氨基甲酸酯基团 分子，iii）通过使有机异氰酸酯a1）与有机羟基化合物a2）和iv）具有至多2500的平均分子量，基于氨基甲酸酯基团的过量的可蒸馏有机多异氰酸酯b）来制备，以形成多异氰酸酯 含有脲基甲酸酯基团，随后通过蒸馏将未反应的组分b）过量除去至少于0.5wt。 ％，条件是多异氰酸酯a1）和多异氰酸酯b）不同。 本发明还涉及从该方法获得的产品及其作为涂料组合物中的粘合剂或粘合剂组分的用途。
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7.发明授权Aqueous polyurethane dispersions having improved water and solvent resistance 失效具有改善的耐水和耐溶剂性的水性聚氨酯分散体公开(公告)号：US06248415B1
公开(公告)日：2001-06-19
申请号：US09118657
申请日：1998-07-17
IPC分类号： C08J300
CPC分类号： C08G18/6659 , C08G18/0823 , C08G18/7837 , Y10T428/16 , Y10T428/167 , Y10T428/31551 , Y10T428/31591 , Y10T428/31989
摘要： The present invention relates to aqueous polyurethane dispersions prepared from a polyisocyanate component and one or more isocyanate-reactive compounds wherein at least 5% by weight of polyisocyanate component is a diisocyanate corresponding to formula (I) wherein R is a difunctional, C4 to C18, aliphatic, cycloaliphatic or aromatic hydrocarbon residue obtained by removing the NCO groups from an organic diisocyanate and R′ is a monofunctional, C1 to C18 hydrocarbon radical, which may contain ether oxygen atoms. The present invention also relates to the use of these PUR dispersions for coating any substrates, preferably wood substrates, such as parquet flooring.
摘要翻译： 本发明涉及由多异氰酸酯组分和一种或多种异氰酸酯反应性化合物制备的水性聚氨酯分散体，其中至少5重量％的多异氰酸酯组分是对应于式（I）的二异氰酸酯，其中R是双官能的，C 4至C 18的脂族 ，通过从有机二异氰酸酯除去NCO基团而获得的脂环族或芳族烃残基，R'是可以含有醚氧原子的单官能的C1-C18烃基。本发明还涉及这些PUR分散体用于涂覆任何 基材，优选木质基材，例如镶木地板。
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8.发明授权Process for the production of isocyanurate polyisocyanates, the compounds obtained by this process and their use 失效生产异氰酸酯聚异氰酸酯的方法，本方法获得的化合物及其用途
公开(公告)号：US5076958A
公开(公告)日：1991-12-31
申请号：US329902
申请日：1989-03-28
CPC分类号： C08G18/4238 , C08G18/3221 , C08G18/3253 , C08G18/3296 , C08G18/4205 , C08G18/4277 , C08G18/792 , C08G18/8016 , C08G18/8061
摘要： The present invention is directed to a process for the production of isocyanurate polyisocyanates by the partial trimerization of the isocyanate groups of aliphatic diisocyanates in the presence of catalysts which accelerate the trimerization of isocyanate groups, termination of the trimerization reaction at the particular degree of trimerization required and removal of unreacted starting diisocyanate and, optionally, other volatile constituents, characterized in that at least one diol containing ester groups and having an average molecular weight of 350 to 950 is added to the reaction mixture at any time before removal of the excess starting diisocyanate in a quantity of 1 to 50% by weight, based on the weight of the diisocyanate used as starting material, the type of reactants and the quantitative ratios between them being selected so that, on completion of the reaction, at least 10% by weight free starting diisocyanate is still present in the reaction mixture, not including any inert solvent used, and the molar ratio of isocyanurate groups to urethane groups in the end products is about 20:1 to 0.2:1.The present invention is also directed to the isocyanurate polyisocyanates obtained by this process and the use of these isocyanurate polyisocyanates, optionally blocked by blocking agents for isocyanate groups, for the production of polyurethane plastics, particularly two-component polyurethane lacquers.
摘要翻译： 本发明涉及通过在促进异氰酸酯基团三聚化的催化剂存在下部分三聚异氰酸酯基团的异氰酸酯基团的生产来制备异氰脲酸酯多异氰酸酯的方法，在特定的三聚反应程度下终止三聚反应所需的 并除去未反应的起始二异氰酸酯和任选的其它挥发性成分，其特征在于在除去过量的起始二异氰酸酯之前的任何时间将至少一种含有酯基并且平均分子量为350至950的二醇加入到反应混合物中 以1至50重量％的量，以用作起始原料的二异氰酸酯的重量计，反应物的类型和它们之间的定量比被选择，使得在反应完成时，至少10重量％ 游离的起始二异氰酸酯仍然存在于反应混合物中，不包括任何内部 t溶剂，最终产物中异氰脲酸酯基与氨基甲酸酯基的摩尔比为约20:1至0.2:1。 本发明还涉及通过该方法获得的异氰脲酸酯多异氰酸酯以及任选被异氰酸酯基团的封闭剂封闭的这些异氰脲酸酯多异氰酸酯用于生产聚氨酯塑料，特别是双组分聚氨酯漆的用途。
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9.发明授权Diphenylmethane diisocyanate based polyisocyanates containing allophanate groups and having blocked isocyanate groups 失效含有脲基甲酸酯基并具有封端异氰酸酯基团的二苯基甲烷二异氰酸酯基聚异氰酸酯
公开(公告)号：US5705593A
公开(公告)日：1998-01-06
申请号：US709801
申请日：1996-09-10
IPC分类号： C07C275/60 , C08G18/78 , C08G18/80 , C09D175/00 , C09D175/04 , C07C273/18
CPC分类号： C08G18/7837 , C07C275/60 , C08G18/8093
摘要： The present invention relates to polyisocyanates prepared from diphenylmethane diisocyanate wherein at least 95% of the isocyanate groups are blocked with diethyl malonate and wherein the polyisocyanates have, based on solids, A) a content of unblocked and blocked isocyanate groups (calculated as NCO) of 9% to 13%, B) a content of allophanate groups (calculated as C.sub.2 HN.sub.2 O.sub.3, molecular weight 101) of 3% to 9% and C) a calculated average functionality of 2.0 to 2.5. The present invention also relates to a process for the production of these polyisocyanates and to their use as crosslinking agents for organic polyhydroxyl compounds in polyurethane stoving lacquers.
摘要翻译： 本发明涉及由二苯基甲烷二异氰酸酯制备的多异氰酸酯，其中至少95％的异氰酸酯基团用丙二酸二乙酯封闭，其中多异氰酸酯基于固体A具有未封端和封闭的异氰酸酯基团的含量（以NCO计算） 9％〜13％，B）脲基甲酸酯基（含量为C2HN2O3，分子量101）含量为3％〜9％，C）计算出的平均官能度为2.0〜2.5。 本发明还涉及一种生产这些多异氰酸酯的方法，以及它们在聚氨酯烘烤漆中用作有机多羟基化合物的交联剂的用途。
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10.发明授权Isocyanate prepolymers containing ether and ester groups a process for their preparation and their use for the production of coating, sealing or casting composition 失效含有醚和酯类的异氰酸酯预处理剂其制备及其用于生产涂料，密封或铸造组合物的方法
公开(公告)号：US5151484A
公开(公告)日：1992-09-29
申请号：US823226
申请日：1992-01-21
IPC分类号： C08G18/10 , C08G18/42 , C08G18/48 , C09D175/06 , C09D175/08 , C09K3/10
CPC分类号： C08G18/4891 , C08G18/10 , C08G2190/00
摘要： The present invention relates to isocyante prepolymers containing ether and ester groups, having an isocyanate content of 1.9% to 25% by weight and based on the reaction product ofA) a polyisocyanate component containing at least one organic polyisocyanate having an average molecular weight of 168 to 1000,B) an organic polyhydroxyl component containing at least one polyhydroxyl compound containing ether and ester groups, having an average hydroxyl functionality of 2 to 3 and an average hydroxyl number of 40 to 90 and based on the esterification products ofi) polyether polyols having an average hydroxyl number of 200 to 600 withii) from 25 to 67 equivalent-%, based on the hydroxyl groups of component (i) and the carboxyl groups of component (ii), of an organic carboxylic acid component containing at least one organic monocarboxylic acid or a mixture of at least one organic monocarboxylic acid with up to 20 carboxyl equivalent-%, based on all the carboxylic acids, of polybasic organic carboxylic acids.The present invention also relates to a process for the preparation of these isocyanate prepolymers containing ether and ester groups and to their as binders or binding components in low solvent or solvent-free polyurethane coating compositions, sealing compositions or casting compositions.
摘要翻译： 本发明涉及含有醚和酯基的异氰酸酯预聚物，其异氰酸酯含量为1.9〜25重量％，基于A）含有至少一种平均分子量为168的有机多异氰酸酯的多异氰酸酯组分的反应产物 至100，B）含有至少一种含醚和酯基的多羟基化合物的有机多羟基组分，其平均羟基官能度为2至3，平均羟值为40至90，并基于i）聚醚多元醇的酯化产物 平均羟基数为200至600，其中ii）基于组分（i）的羟基和组分（ii）的羧基），含有至少一个有机羧酸组分的25至67当量％ 有机单羧酸或至少一种有机一元羧酸与至多20％羧基当量％的混合物，基于所有羧酸，多元组织 c羧酸。 本发明还涉及在低溶剂或无溶剂的聚氨酯涂料组合物，密封组合物或浇铸组合物中制备含有醚和酯基的这些异氰酸酯预聚物以及它们作为粘合剂或粘结组分的方法。
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