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公开(公告)号:US06174975B1
公开(公告)日:2001-01-16
申请号:US09006536
申请日:1998-01-13
申请人: Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
发明人: Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
IPC分类号: C08F426
CPC分类号: C08F4/26 , C07C225/22 , C07C251/86 , C07D207/335 , C07F15/04 , C08F10/00 , C08F12/04 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08F2410/03 , C08F2500/02 , C08F2500/03 , C08F2500/12 , C08F2500/04 , C08F220/10 , C08F2500/10 , C08F210/14 , C08F4/80 , C08F210/06 , C08F4/7006 , C08F4/7004 , C08F4/7021 , C08F4/7019 , C08F4/7026
摘要: Selected olefins such as ethylene and &agr;-olefins are polymerized by nickel [II] complexes of certain monoanionic ligands. The polyolefins are useful in many applications such as molding resins, film, fibers and others. Also described are many novel nickel compounds and their precursors, as well a novel ligands.
摘要翻译: 选择的烯烃如乙烯和α-烯烃由某些单阴离子配体的镍[II]络合物聚合。 聚烯烃可用于许多应用中,例如模制树脂,薄膜,纤维等。 还描述了许多新型的镍化合物及其前体,以及新的配体。
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公开(公告)号:US06613915B1
公开(公告)日:2003-09-02
申请号:US09417323
申请日:1999-10-13
申请人: Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
发明人: Lynda Kaye Johnson , Alison Margaret Anne Bennett , Lin Wang , Anju Parthasarathy , Elisabeth Hauptman , Robert D. Simpson , Jerald Feldman , Edward Bryan Coughlin , Steven Dale Ittel
IPC分类号: C07F1504
CPC分类号: C08F4/26 , C07C225/22 , C07C251/86 , C07D207/335 , C07F15/04 , C08F10/00 , C08F12/04 , C08F110/02 , C08F110/14 , C08F210/02 , C08F210/16 , C08F2410/03 , C08F2500/02 , C08F2500/03 , C08F2500/12 , C08F2500/04 , C08F220/10 , C08F2500/10 , C08F210/14 , C08F4/80 , C08F210/06 , C08F4/7006 , C08F4/7004 , C08F4/7021 , C08F4/7019 , C08F4/7026
摘要: Selected olefins such as ethylene and &agr;-olefins are polymerized by nickel [II] complexes of certain monoanionic ligands. The polyolefins are useful in many applications such as molding resins, film, fibers and others. Also described are many novel nickel compounds and their precursors, as well a novel ligands.
摘要翻译: 选择的烯烃如乙烯和α-烯烃由某些单阴离子配体的镍[II]络合物聚合。 聚烯烃可用于许多应用中,例如模制树脂,薄膜,纤维等。 还描述了许多新型的镍化合物及其前体,以及新的配体。
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公开(公告)号:US5866663A
公开(公告)日:1999-02-02
申请号:US891332
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Lin Wang , Zhen-Yu Yang
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US6034259A
公开(公告)日:2000-03-07
申请号:US891398
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US5886224A
公开(公告)日:1999-03-23
申请号:US891403
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Samuel David Arthur , Jerald Feldman , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Samuel David Arthur , Jerald Feldman , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号: B01J31/00 , B01J37/00 , C07C2/32 , C07C69/52 , C07C251/08 , C07F7/00 , C07F15/00 , C07F19/00 , C08F4/02 , C08F4/06 , C08F4/60 , C08F4/70 , C08F4/80 , C08F10/00 , C08F10/02 , C08F10/06 , C08F10/08 , C08F12/30 , C08F20/06 , C08F110/02 , C08F110/06 , C08F110/14 , C08F132/04 , C08F210/02 , C08F210/14 , C08F210/16 , C08F220/10 , C08F232/00 , C08F232/04 , C08F255/00 , C08L23/02
CPC分类号: C08F110/02 , C08F110/06 , C08F210/02 , C08F210/14 , C08F210/16 , C08L23/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/14 , C08F232/00 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是在它们的微结构方面,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚来合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US06310163B1
公开(公告)日:2001-10-30
申请号:US08899002
申请日:1997-07-10
申请人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
发明人: Maurice S. Brookhart , Lynda Kaye Johnson , Christopher Moore Killian , Samuel David Arthur , Jerald Feldman , Elizabeth Forrester McCord , Stephan James McLain , Kristina Ann Kreutzer , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Steven Dale Ittel , Anju Parthasarathy , Daniel Joseph Tempel
IPC分类号: C08F22010
CPC分类号: C08F110/02 , C08F10/00 , C08F10/02 , C08F10/06 , C08F110/06 , C08F110/14 , C08F210/02 , C08F210/14 , C08F210/16 , C08F232/00 , C08L23/02 , Y10S430/165 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/24942 , Y10T428/2878 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , Y10T428/31938 , Y10T442/20 , Y10T442/60 , Y10T442/626
摘要: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear &agr;-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected &agr;-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected &agr;-diimine nickel complexes with ethylene.
摘要翻译: 本文公开了聚合乙烯,无环烯烃和/或选择的环烯烃,和任选选择的烯属酯或羧酸和其它单体的方法。 聚合由选择的过渡金属化合物,有时是其他助催化剂催化。 由于一些聚合表现出活性聚合的某些特性,因此可以容易地制备嵌段共聚物。 所生产的许多聚合物通常是新颖的,特别是关于它们的微观结构,这给出了其中一些不寻常的性质。 公开了许多新颖的催化剂,以及一些制备它们的新方法。 制备的聚合物可用作弹性体,模塑树脂,粘合剂等。本文还描述了通过使用作为催化剂体系的乙烯低聚法合成线性α-烯烃,将具有选定的α-二亚胺配体的镍化合物和 选择的Lewis或布朗斯台德酸,或通过使选择的α-二亚胺镍络合物与乙烯接触。
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公开(公告)号:US6103920A
公开(公告)日:2000-08-15
申请号:US899032
申请日:1997-07-23
申请人: Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James Mclain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
发明人: Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James Mclain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
IPC分类号: C07F15/04 , C08F4/06 , C08F4/70 , C08F10/00 , C08F10/02 , C08F12/00 , C08F12/04 , C08F12/08 , C08F32/08 , C08F36/00 , C08F36/20 , C08F110/02 , C08F210/02
CPC分类号: C08F32/08 , C07F15/04 , C08F10/00 , C08F10/02 , C08F12/08 , C08F110/02 , C08F210/02
摘要: Disclosed herein is a process for the polymerization of ethylene, norbornenes and styrenes, by contacting in solution a selected nickel compound and a selected compound which is or can coordinated to the nickel with the olefin(s). The polymers produced are useful for films and molding resins.
摘要翻译: 本文公开了通过使溶液中的选定的镍化合物和选择的与镍与烯烃配位的化合物接触来聚合乙烯,降冰片烯和苯乙烯的方法。 所生产的聚合物可用于膜和模制树脂。
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公开(公告)号:US5714556A
公开(公告)日:1998-02-03
申请号:US671392
申请日:1996-06-27
申请人: Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
发明人: Lynda Kaye Johnson , Jerald Feldman , Kristina Ann Kreutzer , Stephan James McLain , Alison Margaret Anne Bennett , Edward Bryan Coughlin , Dennis Scott Donald , Lissa Taka Jennings Nelson , Anju Parthasarathy , Xing Shen , Wilson Tam , Yueli Wang
IPC分类号: C07F15/04 , C08F4/06 , C08F4/70 , C08F10/00 , C08F10/02 , C08F12/00 , C08F12/04 , C08F12/08 , C08F32/08 , C08F36/00 , C08F36/20 , C08F110/02 , C08F210/02
CPC分类号: C08F32/08 , C07F15/04 , C08F10/00 , C08F10/02 , C08F12/08 , C08F110/02 , C08F210/02
摘要: Disclosed herein is a process for the polymerization of ethylene, norbornenes and styrenes, by contacting in solution a selected nickel compound and a selected compound which is or can coordinated to the nickel with the olefin(s). The polymers produced are useful for films and molding resins.
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公开(公告)号:US07041764B2
公开(公告)日:2006-05-09
申请号:US10919181
申请日:2004-08-16
IPC分类号: C08F210/16 , C08F4/80 , C08F4/70
CPC分类号: C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/04 , C08F2500/02 , C08F2500/10 , C08F4/7042
摘要: Ethylene and/or propylene, and α-olefins may be copolymerized by contacting then with certain iron or cobalt complexes of selected 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines). The polymers produced, some of which are novel, are useful as molding resins.
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公开(公告)号:US06803432B2
公开(公告)日:2004-10-12
申请号:US10251041
申请日:2002-09-20
IPC分类号: C08F4602
CPC分类号: C08F10/00 , C08F210/16 , C08F210/14 , C08F2500/04 , C08F2500/02 , C08F2500/10 , C08F4/7042
摘要: Ethylene and/or propylene, and &agr;-olefins may be copolymerized by contacting then with certain iron or cobalt complexes of selected 2,6-pyridinecarboxaldehydebis(imines) and 2,6-diacylpyridinebis(imines). The polymers produced, some of which are novel, are useful as molding resins.
摘要翻译: 乙烯和/或丙烯和α-烯烃可以通过与选定的2,6-吡啶甲醛二(亚胺)和2,6-二酰基吡啶双(亚胺)的某些铁或钴络合物接触而共聚。 所生产的聚合物,其中一些是新颖的,可用作模制树脂。
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