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公开(公告)号：US6139747A
公开(公告)日：2000-10-31
申请号：US212823
申请日：1998-12-16
CPC分类号： C02F1/26 , C02F2103/36 , Y10S210/05
摘要： A process for cleaning up the wastewaters which originate from the preparation of alcohols. The alcohol preparation includes an aldolization reaction followed by hydrogenation and then alcohol distillation. The resulting wastewaters include 3 wastewater fractions from respective steps in the alcohol preparation. The process for cleaning up these wastewaters include the steps of (a) combining two of the three fractions and adjusting the pH of the combination, (b) bringing at least one of the fractions into contact with a coalescing filter, and (c) extracting a mixture of all three fractions.
摘要翻译： 一种净化源自醇类制品的废水的方法。 醇制剂包括醛醇化反应，然后氢化，然后进行醇蒸馏。 所得的废水包括来自醇制剂中各步骤的3个废水馏分。 净化这些废水的方法包括以下步骤：（a）将三种馏分中的两种混合并调节组合的pH值，（b）使至少一种馏分与聚结过滤器接触，和（c）萃取 所有三个分数的混合物。
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公开(公告)号：US6096931A
公开(公告)日：2000-08-01
申请号：US204597
申请日：1998-12-03
IPC分类号： B01J23/755 , C07B61/00 , C07C29/141 , C07C31/02 , C07C29/14
CPC分类号： C07C29/141
摘要： In a process for preparing alcohols comprising the hydrogenation of aldehydes in the presence of a hydrogenation catalyst in the gas phase, the improvement comprising adding nitrogen-containing bases to the aldehyde to be hydrogenated, whereby the formation of by-products is largely suppressed and isolation of the desired alcohols in high selectivity and correspondingly high yield is made possible.
摘要翻译： 在包含在气相中的氢化催化剂存在下醛的氢化制备醇的方法中，改进包括向待氢化的醛中加入含氮碱，从而大大抑制副产物的形成和分离 的所需醇以高选择性和相应的高收率成为可能。
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公开(公告)号：US06358419B1
公开(公告)日：2002-03-19
申请号：US08641514
申请日：1996-05-01
申请人： Mariola Rötzheim , Wolfgang Greb , Wolfgang Zgorzelski , Carl Dieter Frohning , Klaus Denkmann , Heinz Kalbfell
发明人： Mariola Rötzheim , Wolfgang Greb , Wolfgang Zgorzelski , Carl Dieter Frohning , Klaus Denkmann , Heinz Kalbfell
IPC分类号： C02F144
CPC分类号： C02F1/26 , C02F2101/34 , C02F2103/36 , C02F2209/06 , Y10S210/05 , Y10S210/908 , Y10S210/909
摘要： Wastewater from the aldolization reaction is purified by adjusting its pH to 0 to 6, followed by extraction with monohydric alcohols having at least 8 carbon atoms, hydrocarbons having at least 6 carbon atoms, and mixtures thereof. In some cases, adjustment of the pH causes the formation of an organic phase, which is separated from the remaining wastewater before extraction.
摘要翻译： 通过将其pH调节至0至6，然后用具有至少8个碳原子的一元醇，具有至少6个碳原子的烃及其混合物进行萃取来纯化来自醛糖醛酸化反应的废水。 在某些情况下，pH的调节会导致有机相的形成，其在萃取之前与剩余废水分离。
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公开(公告)号：US08445728B2
公开(公告)日：2013-05-21
申请号：US13138813
申请日：2010-03-18
申请人： Wolfgang Greb , Rainer Lukas , Klaus Schmid , Wolfgang Zgorzelski , Jörg Arnold
发明人： Wolfgang Greb , Rainer Lukas , Klaus Schmid , Wolfgang Zgorzelski , Jörg Arnold
IPC分类号： C07C45/50
摘要： The invention relates to a method for reprocessing a liquid product of a hydroformylation reaction, wherein the liquid phase produced in a release stage is supplied to a separating device from which a liquid flow containing rhodium is guided away via a filter, where solids thereby separated are taken out of the process and the filtrate obtained is guided back into the hydroformylation reaction.
摘要翻译： 本发明涉及一种用于再加氢甲酰化反应的液体产物的方法，其中在释放阶段产生的液相被供应到分离装置，通过过滤器将含有铑的液体流引导离开，其中由此分离的固体是 将所得滤液引导回加氢甲酰化反应中。
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公开(公告)号：US06685896B2
公开(公告)日：2004-02-03
申请号：US10181393
申请日：2002-09-05
IPC分类号： C22B1100
CPC分类号： B01J31/2409 , B01J31/2404 , B01J31/403 , B01J31/4046 , B01J31/4092 , B01J2231/321 , B01J2531/822 , B01J2531/985 , B01J2540/12 , B01J2540/32 , C07F15/008 , C22B3/0043 , C22B11/048 , Y02P10/214 , Y02P10/234 , Y02P20/584
摘要： The invention relates to a method for separating and recovering rhodium from reaction products of oxosynthesis, especially reaction products containing cobalt. The invention also relates to the reuse of rhodium as a catalyst for hydroformulation and to a catalyst for hydroformulation itself. The inventive method is characterized by the following: extraction of the organic solution with an aqueous phosphate solution or a phosphate solution, water washing, oxidative treatment of the organic phase, and extraction of the organic phase with an aqueous water-soluble arylphosphine solution.
摘要翻译： 本发明涉及从氧合合反应产物中分离回收铑的方法，特别是含有钴的反应产物。 本发明还涉及铑作为加氢配制催化剂的再利用以及用于加氢成型本身的催化剂。 本发明的方法的特征在于：用磷酸水溶液或磷酸盐溶液萃取有机溶液，水洗，有机相的氧化处理，并用水溶性芳基膦溶液萃取有机相。
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公开(公告)号：US06855851B2
公开(公告)日：2005-02-15
申请号：US10701416
申请日：2003-10-30
申请人： Wolfgang Zgorzelski , Wilhelm Glick
发明人： Wolfgang Zgorzelski , Wilhelm Glick
IPC分类号： C07C29/94 , C07C29/141 , C07C29/80 , C07C29/88 , C07C31/125 , C07C45/82 , C07C47/02 , C07C29/14 , C07C27/04
CPC分类号： C07C29/80 , C07C29/141 , C07C29/88 , C07C31/125 , C07C31/12
摘要： The present invention relates to a process for producing aliphatic C3-C10-alcohols, in particular 2-ethylhexanol, from high boilers by thermal treatment in the presence of an alkali metal compound and subsequent hydrogenation of the volatile products.
摘要翻译： 本发明涉及通过在碱金属化合物的存在下热处理和随后氢化挥发性产物从高沸点生产脂族C 3 -C 10醇，特别是2-乙基己醇的方法。
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公开(公告)号：US5475161A
公开(公告)日：1995-12-12
申请号：US824745
申请日：1992-01-17
IPC分类号： B01J23/755 , B01J23/86 , C07B61/00 , C07C29/141 , C07C29/145 , C07C29/17 , C07C31/02 , C07C29/136 , C07C29/14
CPC分类号： C07C29/141 , C07C29/145 , C07C29/172
摘要： A process for the preparation of alcohols by reaction of organic carbonyl compounds with hydrogen in two stages at elevated temperature and, optionally, elevated pressure. In the first stage, hydrogen and the carbonyl compounds are fed as a gas to a copper-containing catalyst and reacted to 80 to 99.5 percent of the theoretical conversion. In the second stage, the reaction product of the first stage is fed to a nickel/alumina/zirconium dioxide catalyst as a liquid, along with hydrogen. The carbonyl compounds used include aldehydes and their derivatives and, in particular, aliphatic unsaturated and saturated aldehydes.
摘要翻译： 通过有机羰基化合物与氢在升高的温度和任选的高压下两步反应制备醇的方法。 在第一阶段，将氢气和羰基化合物作为气体加入到含铜催化剂中，并反应至理论转化率的80-99.5％。 在第二阶段中，将第一阶段的反应产物与氢一起作为液体加入到镍/氧化铝/二氧化锆催化剂中。 所用的羰基化合物包括醛及其衍生物，特别是脂族不饱和醛和饱和醛。
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公开(公告)号：US4684750A
公开(公告)日：1987-08-04
申请号：US900389
申请日：1986-08-26
申请人： Gunther Kessen , Boy Cornils , Wilhelm Gick , Ernst Wiebus , Joseph Hibbel , Hanswilhelm Bach , Wolfgang Zgorzelski
发明人： Gunther Kessen , Boy Cornils , Wilhelm Gick , Ernst Wiebus , Joseph Hibbel , Hanswilhelm Bach , Wolfgang Zgorzelski
IPC分类号： C07C29/16 , B01J31/00 , B01J31/24 , C07B61/00 , C07C27/00 , C07C29/141 , C07C29/17 , C07C31/125 , C07C39/02 , C07C45/00 , C07C45/45 , C07C45/50 , C07C45/74 , C07C45/82 , C07C47/02 , C07C47/052 , C07C47/21 , C07C67/00
CPC分类号： C07C45/74 , C07C29/175 , C07C45/50 , C07C45/82
摘要： A process for the production of 2-ethyl-hexanol comprising reacting propene with carbon monoxide and hydrogen, in the presence of an aqueous catalyst containing rhodium and at least one sulfonated triarylphosphine, to form an aqueous phase and an organic phase, said organic phase comprising a mixture of materials having boiling points lower than that of n-butanal and substances having boiling points equal to or higher than that of n-butanal, said materials including i-butanal, separating said material from said substances, subjecting said substances to aldol condensation, in the presence of aqueous alkali, to form 2-ethyl hexenal, first hydrogenating said 2-ethyl-hexenal in a gas phase in the presence of a first hydrogenation catalyst and thereafter hydrogenating said 2-ethyl-hexenal in a liquid phase to form 2-ethyl-hexanol in the presence of a second hydrogenation catalyst.
摘要翻译： 一种生产2-乙基己醇的方法，包括在含有铑和至少一种磺化三芳基膦的含水催化剂存在下使丙烯与一氧化碳和氢气反应，形成水相和有机相，所述有机相包含 沸点低于正丁醛和沸点等于或高于正丁醛的物质的混合物，所述材料包括异丁醛，将所述物质与所述物质分离，使所述物质进行醛醇缩合 在碱水溶液存在下，形成2-乙基己烯醛，首先在气相中在第一氢化催化剂存在下氢化所述2-乙基己烯，然后在液相中氢化所述2-乙基己烯醛以形成 2-乙基己醇在第二氢化催化剂存在下反应。
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公开(公告)号：US20120108852A1
公开(公告)日：2012-05-03
申请号：US13138813
申请日：2010-03-18
申请人： Wolfgang Greb , Rainer Lukas , Klaus Schmid , Wolfgang Zgorzelski , Jörg Arnold
发明人： Wolfgang Greb , Rainer Lukas , Klaus Schmid , Wolfgang Zgorzelski , Jörg Arnold
IPC分类号： C07C47/00
摘要： The invention relates to a method for reprocessing a liquid product of a hydroformylation reaction, wherein the liquid phase produced in a release stage is supplied to a separating device from which a liquid flow containing rhodium is guided away via a filter, where solids thereby separated are taken out of the process and the filtrate obtained is guided back into the hydroformylation reaction.
摘要翻译： 本发明涉及一种用于再加氢甲酰化反应的液体产物的方法，其中在释放阶段产生的液相被供应到分离装置，通过过滤器将含有铑的液体流引导离开，其中由此分离的固体是 将所得滤液引导回加氢甲酰化反应中。
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公开(公告)号：US6137013A
公开(公告)日：2000-10-24
申请号：US211937
申请日：1998-12-15
CPC分类号： C07C45/86
摘要： A method of stabilizing aliphatic C.sub.3 -C.sub.14 -aldehydes against polymerization and autocondensation by the addition of alkaline substances to the aldehydes wherein the alkaline substances used are alkali metal hydroxides, alkaline earth metal hydroxides, alkali metal carbonates, alkaline earth metal carbonates or alkali metal carboxylates which are added to the aldehyde to be stabilized in amounts of 0.05-20 ppm, based on the aldehyde.
摘要翻译： 通过向醛中添加碱性物质来稳定脂肪族C 3 -C 14醛对聚合和自缩合的方法，其中使用的碱性物质是碱金属氢氧化物，碱土金属氢氧化物，碱金属碳酸盐，碱土金属碳酸盐或碱金属羧酸盐 基于醛加入到待稳定的醛中，其量为0.05-20ppm。
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