摘要:
Quadridentate Cu.sup.II and Zn.sup.II phenoxyl complexes and phenoxyl radical complexes thereof, in which one ligand L is bonded to each metal atom and H.sub.2 L stands for the general formula ##STR1## in which the bridge-unit Q stands for --S--, --O--, --N(R.sup.3)--, --P(R.sup.4)--, or ortho-NH--C.sub.6 H.sub.4 --NH-- and R.sup.1 and R.sup.2 stand for radical-stabilizing residues.Preferred radical complexes include ##STR2## The radical complexes are oxidation catalysts for oxidizing organic substrates with O.sub.2 in the course of which H.sub.2 O.sub.2 is also formed.
摘要翻译:其中一个配体L与每个金属原子键合的二元CuII和ZnII苯氧基络合物和苯氧基自由基配合物,H2L代表桥单元Q代表-S-,-O-,-N( R3) - ,-P(R4) - 或邻NH-C6H4-NH-,R1和R2代表自由基稳定残基。 优选的自由基络合物包括自由基配合物是氧化有机底物与氧气的氧化催化剂,其中还形成了H 2 O 2。
摘要:
An additive for middle distillates with a maximum sulfur content of 0.05 percent by weight, comprising at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).
摘要:
The present invention provides an additive for improving the cold flow properties of vegetable or animal fuel oil. The additive comprises A) a copolymer of ethylene and 8–21 mol % of at least one acrylic or vinyl ester having a C1–C18-alkyl radical and B) a comb polymer of at least one C8–C16-alkyl ester of an ethylenically unsaturated dicarboxylic acid and at least one C10–C20-olefin, wherein the sum Q Q = ∑ i w 1 i · n 1 i + ∑ j w 2 j · n 2 j of the molar averages of the carbon chain distributions in the alkyl side chains of the olefins (monomer 1) and the fatty alcohols (monomer 2) is from 23 to 27. In Q, w1 and w2 are the molar proportions of the individual chain lengths in the comb polymer from the different monomers 1 and 2, and n1 and n2 are the side chain carbon atom lengths, excluding comb polymer bonded carbon atoms of monomer 1, and the running variables i and j are the individual side chain lengths in the particular monomer groups.
摘要:
An additive for low-sulfur mineral oil distillates having improved cold flowability and paraffin dispersancy, comprising at least one ester of an alkoxylated polyol and at least one polar nitrogen-containing paraffin dispersant.
摘要:
The invention provides a fuel oil composition F) comprising F1) 89-50% by volume of a fuel oil of mineral origin and F2) 11-50% by volume of a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units composed of B1) at least one olefin as monomer 1 which bears at least one C8-C18-alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16-alkyl radical bonded via an ester moiety, where the sum Q Q = ∑ i w 1 i · n 1 i + ∑ j w 2 j · n 2 j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the ester groups of monomer 2 on the other is from 21.0 to 28.0, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the ester groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radicals of the ester groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals in the ester groups of monomer 2.
摘要:
The invention relates to additives for middle distillates with a maximum sulfur content of 0.05 percent by weight, containing at least one fatty acid ester of alkoxylated polyols with at least 3 OH groups (A) and at least one alkylphenol-aldehyde resin (C).
摘要:
The invention provides a fuel oil composition comprising a fuel oil of mineral origin and a fuel oil of vegetable and/or animal origin and as a cold additive, the constituents, at least one copolymer composed of ethylene and 8-21 mol % of at least one acrylic and vinyl ester having a C1-C18 alkyl radical and at least one comb polymer containing structural units composed of at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety.
摘要:
A middle distillate having a maximum um sulfur content of 0.05% by weight and containing fatty acid esters of alkoxylated polyols having at least 3 OH groups (A) and also at least one cold flow improver (B). The cold flow improver includes at least one copolymer of ethylene and one or more ethylenically unsaturated carboxylic esters having an ethylene portion of from 60 to 90 mol %.
摘要:
The invention provides a composition comprising A) Solvent Naphtha having a naphthalene content of less than 1% by weight, B) a middle distillate cold flow improver and C) a solubilizing additive selected from aliphatic or alicyclic C1- to C22-alcohols, cycloaliphatic hydrocarbons and monocyclic aromatic hydrocarbons.
摘要:
The invention provides a fuel oil composition F) comprising F1) a fuel oil of mineral origin and F2) a fuel oil of vegetable and/or animal origin, and, as a cold additive, the constituents A) at least one copolymer composed of ethylene and 8-21 mol% of at least one acrylic or vinyl ester having a C1-C18-alkyl radical and B) at least one comb polymer containing structural units composed of B1) at least one olefin as monomer 1 which bears at least one C8-C18 alkyl radical on the olefinic double bond, and B2) at least one ethylenically unsaturated dicarboxylic acid as monomer 2 which bears at least one C8-C16 alkyl radical bonded via an amide and/or imide moiety, where the sum Q Q = ∑ i w 1 i · n 1 i + ∑ j w 2 j · n 2 j of the molar averages of the carbon chain length distributions in the alkyl radicals of monomer 1 on the one hand and the alkyl radicals of the amide and/or imide groups of monomer 2 on the other is from 21.0 to 28.0, where w1 is the molar proportion of the individual chain lengths in the alkyl radicals of monomer 1, w2 is the molar proportion of the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2, n1 are the individual chain lengths in the alkyl radicals of monomer 1, n2 are the individual chain lengths in the alkyl radical of the amide and/or imide groups of monomer 2, i is the serial variable for the individual chain lengths in the alkyl radicals of monomer 1, and j is the serial variable for the individual chain lengths in the alkyl radicals of the amide and/or imide groups of monomer 2.