摘要:
The present invention provides a galvannealed steel sheet excellent in the adhesion with a base steel sheet and a manufacturing method thereof. The galvannealed steel sheet according to the invention has, in an interface between a galvannealed layer and the base steel sheet thereon the galvannealed layer is formed, an irregularity that has a depth of 10 nm or more at a pitch of 0.5 μm or less at least one per 5 μm of a length of the interface.
摘要:
Stainless steel for fuel cell separators contains C: ≦0.03%, Si: ≦1.0%, Mn: ≦1.0%, S: ≦0.01%, P: ≦0.05%, Al: ≦0.20%, N: ≦0.03%, Cr: 16 to 40%, and one or more of Ni: ≦20%, Cu: ≦0.6% and Mo: ≦2.5%, the balance being Fe and inevitable impurities. According to X-ray photoelectron spectroscopy, the surface of the stainless steel contains fluorine and provides a 3.0 or higher ratio of the total of atomic concentrations of Cr and Fe in other than the metallic forms calculated from data resulting from the separation of peaks of Cr and Fe into metallic peaks and peaks other than the metallic peaks to the total of atomic concentrations of Cr and Fe in the metallic forms calculated from data resulting from the separation of peaks of Cr and Fe into metallic peaks and peaks other than the metallic peaks.
摘要:
Stainless steel for fuel cell separators are provided which exhibit stable contact resistance characteristics and excellent practical utility. The stainless steel contains not less than 16 mass % of Cr. When the surface configuration of the stainless steel is analyzed with a scanning electron microscope at a spatial resolution of not more than 0.1 μm, the surface modulus is not less than 1.02. Preferably, the chemical composition further includes C: not more than 0.03%, Si: not more than 1.0%, Mn: not more than 1.0%, S: not more than 0.01%, P: not more than 0.05%, Al: not more than 0.20%, N: not more than 0.03%, Cr: 16 to 40%, and one or more of Ni: not more than 20%, Cu: not more than 0.6% and Mo: not more than 2.5%, the balance being Fe and inevitable impurities.
摘要:
Provided are an apparatus for continuous electrolytic treatment of a steel sheet that is suitable for producing a surface-treated steel sheet and a method for producing the surface-treated steel sheet using the apparatus for continuous electrolytic treatment of a steel sheet. The apparatus includes N pairs of tabular electrodes having a length L and being arranged to respectively face two surfaces of a steel sheet. Each electrode includes n sections arranged in the longitudinal direction of the electrode and disposed on the surface of the electrode facing the steel sheet surface. Each section is constituted by a conductive portion including an electrode portion having a length T1 and a nonconductive portion made by making an electrode portion having a length T2 nonconductive, where n×N≧10, 0.96≧T2/(T1+T2)≧0.05, and 0.9≧T1/L≧0.1.
摘要:
Disclosed is a manufacturing method for steel sheets for containers that enables reliable, continuous manufacture of steel sheets, with excellent film adhesion qualities, for containers. The manufacturing method for steel sheets for containers is a method in which a film containing Zr is formed on the surface of the steel sheets by immersing, and/or subjecting to electrolytic treatment, the steel sheets in a solution containing Zr ions, F ions, and at least one reaction accelerating component selected from a group including Al ions, boric acid ions, Cu ions, Ca ions, metal Al, or metal Cu.
摘要:
A coated steel sheet includes a corrosion-resistant coating composed of at least one layer selected from the group consisting of a Ni layer, a Sn layer, an Fe—Ni alloy layer, an Fe—Sn alloy layer, and an Fe—Ni—Sn alloy layer disposed on at least one surface of a steel sheet, and an adhesive coating disposed on the corrosion-resistant coating, the adhesive coating containing Zr and further containing at least one metal element selected from the group consisting of Co, Fe, Ni, V, Cu, Mn, and Zn, in total, at a ratio by mass of 0.01 to 10 with respect to Zr. The coated steel sheet has excellent humid resin adhesion and corrosion resistance, in which streaky surface defects do not occur.
摘要:
Provided are an apparatus for continuous electrolytic treatment of a steel sheet that is suitable for producing a surface-treated steel sheet and a method for producing the surface-treated steel sheet using the apparatus for continuous electrolytic treatment of a steel sheet. The apparatus includes N pairs of tabular electrodes having a length L and being arranged to respectively face two surfaces of a steel sheet. Each electrode includes n sections arranged in the longitudinal direction of the electrode and disposed on the surface of the electrode facing the steel sheet surface. Each section is constituted by a conductive portion including an electrode portion having a length T1 and a nonconductive portion made by making an electrode portion having a length T2 nonconductive, where n×N≧10, 0.96≧T2/(T1+T2)≧0.05, and 0.9≧T1/L≧0.1.
摘要:
A method to evaluate the corrosion resistance of a can to a content includes filling the can with the content to form a specimen, setting the specimen in an apparatus capable of blocking an outside atmosphere from entering the specimen, optionally saturating the content with nitrogen gas to expel dissolved oxygen present in the content, thereafter while maintaining the temperature of the content at a constant temperature in the range of 25 to 60° C., applying a constant potential that is more anodic than an immersion potential by 50 mV to 200 mV to the can of the specimen, and evaluating the corrosion resistance of the can to the content based on the accumulated amount of electricity generated during a time appropriately selected from 6 to 48 hours immediately after the application of the constant potential.
摘要:
A method for analyzing a metallic material includes the steps of electrolyzing a metal sample in an electrolyte; removing the electrolyzed metal sample from the electrolyte; immersing the metal sample removed from the electrolyte into a dispersive solution that is different from the electrolyte to separate at least one selected from the group consisting of a precipitate and an inclusion deposited on the metal sample; and analyzing the at least one selected from the group consisting of a precipitate and an inclusion extracted into the dispersive solution.
摘要:
A method for analyzing a metallic material includes the steps of electrolyzing a metal sample in an electrolyte; removing the electrolyzed metal sample from the electrolyte; immersing the metal sample removed from the electrolyte into a dispersive solution that is different from the electrolyte to separate at least one selected from the group consisting of a precipitate and an inclusion deposited on the metal sample; and analyzing the at least one selected from the group consisting of a precipitate and an inclusion extracted into the dispersive solution.