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    Transparent coated resin composite
    2.
    发明授权
    Transparent coated resin composite 失效
    透明涂层树脂复合材料

    公开(公告)号：US4029842A

    公开(公告)日：1977-06-14

    申请号：US609857

    申请日：1975-09-02

    申请人： Masaru Yoshida ,  Hiroshi Okubo ,  Isao Kaetsu

    发明人： Masaru Yoshida ,  Hiroshi Okubo ,  Isao Kaetsu

    IPC分类号： B05D7/00 ,  B05D7/02 ,  B29D11/00 ,  B32B27/00 ,  C08J7/04 ,  C09D183/04 ,  C09K3/00 ,  B32B27/08 ,  G02C7/02

    CPC分类号： B05D7/536 ,  B05D7/02 ,  B29D11/00865 ,  C08J7/045 ,  C09D183/04 ,  C08J2333/12 ,  C08J2491/06 ,  Y10T428/263 ,  Y10T428/269 ,  Y10T428/31663 ,  Y10T428/31667

    摘要： A transparent coated resin composite comprising: (a) a resin substrate mainly comprising polymethyl methacrylate, (b) a precoating which is formed of a silicon compound selected from the group consisting of methacryloxyalkyltrialkoxysilanes, aminoalkyl-trialkoxysilanes, vinyltris(alkoxyalkoxy)silanes, vinyltrialkoxysilanes and hydrolysates thereof on said substrate, and (c) an over-coating which is formed of a silicon compound selected from the group consisting of glycidoxyalkyltrialkoxysilanes, N-aminoalkylaminoalkyl-trialkoxysilanes, (3,4-epoxycyclohexyl)alkyltrialkoxysilanes and hydrolysates thereof on said precoating is provided. The over-coating may contain other polymerizable monomers. The over-coating which provides the substrate with the good abrasion resistance and anti-fogging property is firmly bonded to the substrate by virtue of the precoating and exhibits excellent abrasion resistance as well as anti-fogging property without impairing the optical characteristics of methyl methacrylate resins.

    摘要翻译： 一种透明涂层树脂复合材料，包括：（a）主要包含聚甲基丙烯酸甲酯的树脂基材，（b）由选自甲基丙烯酰氧基烷基三烷氧基硅烷，氨基烷基 - 三烷氧基硅烷，乙烯基三（烷氧基烷氧基）硅烷，乙烯基三烷氧基硅烷和乙烯基三烷氧基硅烷的硅化合物形成的预涂层， （c）由选自缩水甘油氧基烷基三烷氧基硅烷，N-氨基烷基氨基烷基 - 三烷氧基硅烷，（3,4-环氧环己基）烷基三烷氧基硅烷及其在所述预涂层上的水解产物组成的组中的硅化合物形成的覆盖层是 提供。 覆盖层可能含有其他可聚合单体。 通过预涂层将基材提供良好的耐磨性和防雾性的覆盖层牢固地结合到基材上，并且在不损害甲基丙烯酸甲酯树脂的光学特性的情况下表现出优异的耐磨性和防雾性 。

    Thermosetting resin composition comprising an [(2,3-epoxypropoxy)alkyl]trialkyloxysilane
    7.
    发明授权
    Thermosetting resin composition comprising an [(2,3-epoxypropoxy)alkyl]trialkyloxysilane 失效
    包含{8（2,3-环氧丙氧基）烷基{9三烷氧基硅烷的热固性树脂组合物

    公开(公告)号：US4049867A

    公开(公告)日：1977-09-20

    申请号：US643890

    申请日：1975-12-23

    申请人： Akihiko Ito ,  Isao Kaetsu ,  Hiroshi Okubo ,  Masamichi Kato ,  Koichiro Hayashi ,  Yuji Maeda

    发明人： Akihiko Ito ,  Isao Kaetsu ,  Hiroshi Okubo ,  Masamichi Kato ,  Koichiro Hayashi ,  Yuji Maeda

    IPC分类号： C08G59/36 ,  C08G77/48 ,  C08G77/60 ,  B32B27/38 ,  B32B27/08

    CPC分类号： C08G77/60 ,  C08G59/36 ,  C08G77/48 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31667

    摘要： A novel thermosetting resin composition comprising at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane and at least one selected from polymers, prepolymers, copolymers and coprepolymers of epoxy-group-containing vinyl monomers, which may further contain at least one selected from polymers, prepolymers, copolymers and coprepolymers of vinyl monomers containing no epoxy group, is disclosed. This composition is cured by heating with addition of a ring-opening polymerization catalyst and remarkably improves surface hardness, abrasion resistance, weathering resistance, chemical resistances, heat resistances, etc. of acrylic resins and many other plastic materials without imparing the inherent transparency and other optical properties of these materials when it is applied on the surface of them and cured.

    摘要翻译： 一种新型热固性树脂组合物，其包含至少一种[（2,3-环氧丙氧基）烷基]三烷氧基硅烷和选自含环氧基的乙烯基单体的聚合物，预聚物，共聚物和共聚物中的至少一种，其可以进一步包含至少一种选择 来自不含环氧基的乙烯基单体的聚合物，预聚物，共聚物和共聚物。 通过加入开环聚合催化剂加热固化该组合物，并显着提高丙烯酸树脂和许多其它塑料材料的表面硬度，耐磨性，耐候性，耐化学性，耐热性等，而不会影响固有的透明度等 这些材料在其表面上施加并固化时的光学性质。

    Transparent resin composite
    8.
    发明授权
    Transparent resin composite 失效
    透明树脂复合材料

    公开(公告)号：US3955035A

    公开(公告)日：1976-05-04

    申请号：US495169

    申请日：1974-08-06

    申请人： Akihiko Ito ,  Isao Kaetsu ,  Hiroshi Okubo ,  Masamichi Kato ,  Koichiro Hayashi

    发明人： Akihiko Ito ,  Isao Kaetsu ,  Hiroshi Okubo ,  Masamichi Kato ,  Koichiro Hayashi

    IPC分类号： C08J7/04 ,  B32B27/00 ,  C09D183/04 ,  C09D183/06 ,  B32B27/38 ,  B32B27/08

    CPC分类号： C09D183/06 ,  Y10T428/263 ,  Y10T428/269 ,  Y10T428/31511 ,  Y10T428/31663 ,  Y10T428/31667

    摘要： Transparent resin composites comprising a substrate of a transparent plastic material coated with a cured film of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane or of at least one [(2,3-epoxypropoxy)alkyl]trialkoxysilane and at least one transparent polymer compatible with said silane are provided. The resin composites have excellent abrasion resistance, surface hardness, heat resistance, chemical resistance, weathering resistance, etc. well retaining the transparency and other optical characteristics of the substrate resin. These resin composites can be used as transparent plastic panels, lenses, etc.

    摘要翻译： 透明树脂复合材料包括涂覆有至少一种[（2,3-环氧丙氧基）烷基]三烷氧基硅烷或至少一种[（2,3-环氧丙氧基）烷基]三烷氧基硅烷的固化膜的透明塑料材料的基材，并且至少 提供了与所述硅烷相容的一种透明聚合物。 该树脂复合材料具有优异的耐磨性，表面硬度，耐热性，耐化学性，耐候性等，保持了基材树脂的透明性和其它光学特性。 这些树脂复合材料可用作透明塑料板，透镜等。

    Process for producing a slow release composite
    9.
    发明授权
    Process for producing a slow release composite 失效
    缓释复合材料的制备方法

    公开(公告)号：US4582719A

    公开(公告)日：1986-04-15

    申请号：US514026

    申请日：1983-07-15

    申请人： Isao Kaetsu ,  Masaharu Asano ,  Minoru Kumakura ,  Masaru Yoshida

    发明人： Isao Kaetsu ,  Masaharu Asano ,  Minoru Kumakura ,  Masaru Yoshida

    IPC分类号： A01N25/10 ,  A61K9/20 ,  A61K9/22 ,  A61K9/52 ,  B01J19/12 ,  B05D3/06

    CPC分类号： A01N25/10 ,  A61K9/2063

    摘要： A process is, herein disclosed, for producing a slow release composite having a physiologically active substance encapsulated therein, which comprises preparing a system wherein one or more physiologically active substances are in contact with protein from one or more protein sources, and bringing said system into direct contact with steam at temperatures between 50.degree. C. and 100.degree. C. to denature the protein and make the same hydrophobic, to thereby make a slow release composite having the physiologically active substance dispersed, fixed and encapsulated therein. And a process is also disclosed for producing a slow release composite which comprises preparing a mixture of one or more hydrophilic polymerizable monomers containing the body fluid and/or isotonic solution, protein from one or more protein sources, and one or more physiologically active substances, subjecting the mixture to direct contact with steam and irradiation with light or ionizing radiation, said treatment with steam being performed either before or simultaneously with irradiation with light or ionizing radiation.

    摘要翻译： 本文公开了一种用于生产包含其中的生理活性物质的缓释复合物的方法，其包括制备其中一种或多种生理活性物质与来自一种或多种蛋白质来源的蛋白质接触的系统，并将所述系统引入 在50℃至100℃的温度下直接与蒸汽接触以使蛋白质变性并制成相同的疏水性，从而制备其生理活性物质分散，固定和包封的缓释复合物。 还公开了用于生产缓释复合物的方法，其包括制备含有体液和/或等渗溶液的一种或多种亲水性可聚合单体，来自一种或多种蛋白质来源的蛋白质和一种或多种生理活性物质的混合物， 使混合物与蒸汽直接接触并用光或电离辐射照射，所述用蒸汽进行的处理在用光或电离辐射照射之前或同时进行。

    Process for producing a multi-layered slow release composite
    10.
    发明授权
    Process for producing a multi-layered slow release composite 失效
    制备多层缓释复合材料的方法

    公开(公告)号：US4359483A

    公开(公告)日：1982-11-16

    申请号：US233135

    申请日：1981-02-10

    申请人： Isao Kaetsu ,  Masaru Yoshida

    发明人： Isao Kaetsu ,  Masaru Yoshida

    IPC分类号： A61K9/00 ,  A61K9/20 ,  A61K9/22 ,  A61K9/24 ,  A61K9/70 ,  A01N1/02 ,  B05D3/00 ,  B05D3/06

    CPC分类号： A61K9/70 ,  A61K9/2027 ,  A61K9/209 ,  Y10T428/2998

    摘要： A process is herein disclosed for producing a multi-layered slow release composite comprising: a first step wherein one or more physiologically active substances is mixed with one member selected from the group consisting of one or more supercooling polymerizable vinyl monomers, one or more natural or synthetic polymeric substances and a mixture thereof, and the mixture is given a predetermined shape and subjected to a physical treatment to form a slow release composite; a second step wherein a predetermined thickness of coating of one member selected from the group consisting of one or more supercooling polymerizable vinyl monomers, one or more natural or synthetic polymeric substances and a mixture thereof is formed on the surface of said slow release composite, which then is subjected to a physical treatment so that a layer wherein no physiologically active substance is encapsulated is formed on the surface of said slow release composite; a third step wherein a predetermined thickness of coating of a mixture of one or more physiologically active substances with one member selected from the group consisting of one or more supercooling polymerizable vinyl monomers, one or more natural or synthetic polymeric substances and a mixture thereof is formed on the surface of the slow release composite having the layer provided in the second step wherein no physiologically active substance is encapsulated, said composite then is subjected to a physical treatment to form a layer wherein the physiologically active substance is encapsulated.

    摘要翻译： 本文公开了一种用于生产多层缓释复合材料的方法，其包括：第一步骤，其中将一种或多种生理活性物质与选自一种或多种过冷可聚合乙烯基单体，一种或多种天然或 合成的聚合物质及其混合物，并给出预定的形状并进行物理处理以形成缓释复合材料; 第二步骤，其中在所述缓释复合材料的表面上形成预定厚度的选自由一种或多种过冷可聚合乙烯基单体，一种或多种天然或合成聚合物质及其混合物组成的组的涂层，其中 然后进行物理处理，使得在所述缓释复合材料的表面上形成不包裹生理活性物质的层; 第三步骤，其中形成预定厚度的一种或多种生理活性物质与选自一种或多种过冷可聚合乙烯基单体，一种或多种天然或合成聚合物质及其混合物的组分的混合物的涂层 在其中没有包裹生理活性物质的第二步中提供的具有层的缓释复合物的表面上，然后将所述复合物进行物理处理以形成其中包封生理活性物质的层。