公开(公告)号：US5707717A

公开(公告)日：1998-01-13

申请号：US209573

申请日：1994-03-10

申请人： Masanori Shibahara ,  Masatoshi Nakayama

发明人： Masanori Shibahara ,  Masatoshi Nakayama

IPC分类号： B29C33/56 ,  C03B11/08 ,  C03B40/00 ,  C03C17/34 ,  C23C16/02 ,  C23C16/26 ,  C03B19/02

CPC分类号： C03B11/086 ,  B29C33/56 ,  C03B40/00 ,  C03C17/3441 ,  C23C16/0272 ,  C23C16/26 ,  B29K2907/04 ,  C03B2215/10 ,  C03B2215/11 ,  C03B2215/12 ,  C03B2215/24 ,  C03B2215/34 ,  Y10T428/24942 ,  Y10T428/24975 ,  Y10T428/24983 ,  Y10T428/265 ,  Y10T428/30 ,  Y10T428/31678

摘要： A protectively coated article comprises a substrate of a material selected from the group consisting of alloys containing at least Co, Ni, or Fe, ceramics, and glass and which has only a slight affinity for a diamond-like thin film, an intermediate carbon layer formed on the substrate, the intermediate layer having a hardness Hv in the range from 1000 to 5000 kg/mm2, or harder than the substrate but less hard than a diamond-like thin film to be formed thereon, and a diamond-like thin film formed further thereon. The interposition of the intermediate layer permits the diamond-like thin film to be bound securely to a substrate surface which has a slight affinity for the film.

摘要翻译： 一种保护涂层制品包括选自由至少含有Co，Ni或Fe，陶瓷和玻璃的合金的材料的基底，并且其对于类金刚石薄膜仅具有轻微的亲和力，中间碳层 形成在基板上，中间层的硬度Hv在1000-5000kg / mm2的范围内，或比基板硬，但难于形成在其上的类金刚石薄膜，并且金刚石状薄膜 形成在其上。 中间层的插入允许类金刚石薄膜牢固地结合到对薄膜具有轻微亲和性的基底表面。

公开(公告)号：US5827613A

公开(公告)日：1998-10-27

申请号：US209571

申请日：1994-03-10

申请人： Masatoshi Nakayama ,  Masanori Shibahara

发明人： Masatoshi Nakayama ,  Masanori Shibahara

IPC分类号： B29C33/56

CPC分类号： B29C33/56 ,  Y10T428/12771 ,  Y10T428/12806 ,  Y10T428/12812 ,  Y10T428/12826 ,  Y10T428/12833 ,  Y10T428/12931 ,  Y10T428/30 ,  Y10T428/31678

摘要： Articles having a diamond-like protective film formed thereon, each comprising a substrate of a material selected from the group consisting of alloys containing at least Co, Ni, or Fe, ceramics, and glass and which has only a slight affinity for a diamond-like thin film, an Mo film formed on the substrate, and a diamond-like thin film formed further thereon. Such articles are manufactured by a method which comprises holding a grid made of Mo close to the surface of the substrate, bombarding the grid and the substrate surface with a bombarding gas consisting of inert gas atoms of Ar or the like, thereby removing contaminants from the surface and depositing Mo atoms on the substrate surface to form an Mo film thereon, ionizing a low-molecular-weight hydrocarbon or a feed gas capable of producing a low-molecular-weight hydrocarbon upon decomposition or reaction, and then accelerating the resulting ions and depositing the same on the Mo film to form a diamond-like film thereon. The substrate is preferably a metallic mold constructed of a hardened steel. The Mo film enhances the bond of the diamond-like film to the substrate and improves the strength of the mold surface.

摘要翻译： 在其上形成有金刚石状保护膜的制品，每个包含选自由至少含有Co，Ni或Fe的合金，陶瓷和玻璃组成的组的基材，并且其对金刚石 - 形成在基板上的Mo膜，以及形成在其上的金刚石状薄膜。 这样的制品通过以下方法制造：将由Mo制成的栅格保持在基板的表面附近，用Ar等惰性气体原子的轰击气体轰击栅格和基板表面，由此从 在基板表面上沉积Mo原子以在其上形成Mo膜，在分解或反应时电离低分子量烃或能够产生低分子量烃的进料气体，然后加速所得离子和 将其沉积在Mo膜上以在其上形成类金刚石膜。 基板优选为由硬化钢构成的金属模。 Mo膜增强了类金刚石膜与基材的结合，提高了模具表面的强度。

公开(公告)号：US5541003A

公开(公告)日：1996-07-30

申请号：US209337

申请日：1994-03-10

申请人： Masatoshi Nakayama ,  Masanori Shibahara

发明人： Masatoshi Nakayama ,  Masanori Shibahara

IPC分类号： B29C33/56 ,  B29C45/37 ,  C23C16/02 ,  C23C16/26 ,  B32B9/00

CPC分类号： C23C16/0272 ,  B29C33/56 ,  B29C45/37 ,  C23C16/26 ,  B29K2883/00 ,  B29K2907/04 ,  Y10T428/24975 ,  Y10T428/30

摘要： Articles protectively coated with a diamond-like thin film firmly bonded to the substrates are obtained by forming an intermediate layer composed of an amorphous mixture of silicon and carbon on a substrate of a material which has only a slight affinity for such a diamond-like thin film, and forming a diamond-like thin film further thereon.

摘要翻译： 通过将由硅和碳的无定形混合物组成的中间层形成在对这种类似金刚石的薄的仅具有轻微亲和性的材料的基材上，从而获得牢固地结合到基底上的金刚石状薄膜的保护性涂覆的物品 并在其上进一步形成类金刚石薄膜。

公开(公告)号：US5677051A

公开(公告)日：1997-10-14

申请号：US651902

申请日：1996-05-21

申请人： Kunihiro Ueda ,  Masatoshi Nakayama ,  Kiyoshi Yazu ,  Koji Kobayashi ,  Hiromichi Kanazawa

发明人： Kunihiro Ueda ,  Masatoshi Nakayama ,  Kiyoshi Yazu ,  Koji Kobayashi ,  Hiromichi Kanazawa

IPC分类号： G11B5/72 ,  G11B5/84 ,  G11B5/66

CPC分类号： G11B5/8408 ,  G11B5/72 ,  Y10S427/106 ,  Y10S428/90 ,  Y10T428/265 ,  Y10T428/30 ,  Y10T428/31544 ,  Y10T428/31678

摘要： A magnetic recording medium possessing excellent electromagnetic characteristics, corrosion resistance, durability, abrasion resistance and lubricity, has an undercoat layer, a ferromagnetic metal layer, a protective layer and a lubricating layer formed in this order on a non-magnetic substrate, or has an undercoat layer, a ferromagnetic metal layer, an intercepting layer, a protective layer and a lubricating layer formed in this order on a non-magnetic substrate, wherein the protective layer is a plasma-polymerized hydrogen-containing carbon film having a refractive index of 1.90 or more and a contact angle of less than 80 degrees, the film thickness of the protective layer or the total film thickness of the protective layer and the intercepting layer is 30 to 150 .ANG., the undercoat layer, as well as the intercepting layer, is a film formed of silicon oxide represented by SiOx (x=1.8-1.95), and the lubricating layer is formed of a compound selected from the group consisting of polar perfluoropolyethers, non-polar perfluoropolyethers, perfluorocarboxylic acids, phosphazens, perfluoroalkylates and perfluoroacrylate compounds; and a method for producing the recording medium.

摘要翻译： 具有优异的电磁特性，耐腐蚀性，耐久性，耐磨性和润滑性的磁记录介质具有在非磁性基板上依次形成的底涂层，强磁性金属层，保护层和润滑层，或具有 底涂层，强磁性金属层，截留层，保护层和润滑层，其依次形成在非磁性基板上，其中保护层是折射率为1.90的等离子体聚合的含氢碳膜 以上，接触角小于80度，保护层的膜厚或保护层和截留层的总膜厚为30〜150安培，底涂层以及截留层为 由SiOx（x = 1.8-1.95）表示的由氧化硅形成的膜，并且润滑层由选自p 全氟聚醚，非极性全氟聚醚，全氟羧酸，磷腈，全氟烷基化物和全氟丙烯酸酯化合物; 以及记录介质的制造方法。

公开(公告)号：US4988573A

公开(公告)日：1991-01-29

申请号：US379344

申请日：1989-07-13

申请人： Masatoshi Nakayama ,  Kunihiro Ueda ,  Masatoshi Okamura

发明人： Masatoshi Nakayama ,  Kunihiro Ueda ,  Masatoshi Okamura

IPC分类号： C23C16/30 ,  G11B23/087

CPC分类号： G11B23/08785 ,  C23C16/30 ,  G11B23/08757 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31663 ,  Y10T428/31699

摘要： A plasma-polymerized film covers a surface of a medium related member which constructs or is disposed in a casing in which a tape or disk-shaped recording medium is receiving for travel or rotating motion. The film contains C, F and at least one element of Si, B, P and N. The total content of F and at least one element of Si, B, P, and N ranges from 5 to 40 atom % of the film, and the atomic ratio of (Si+B+P+N)/F ranges from 2/10 to 5/1.

摘要翻译： 等离子体聚合膜覆盖介质相关部件的表面，其构造或设置在其中带或盘状记录介质被接收用于行进或旋转运动的壳体中。 该膜含有C，F和Si，B，P和N中的至少一种元素.F和Si，B，P和N中的至少一种元素的总含量为5至40原子％ （Si + B + P + N）/ F的原子比为2/10〜5/1。

公开(公告)号：US4900622A

公开(公告)日：1990-02-13

申请号：US97607

申请日：1987-09-16

申请人： Masatoshi Nakayama ,  Koji Kobayashi ,  Kunihiro Ueda ,  Mitsuru Takai ,  Shigeo Kurose

发明人： Masatoshi Nakayama ,  Koji Kobayashi ,  Kunihiro Ueda ,  Mitsuru Takai ,  Shigeo Kurose

IPC分类号： C23C14/22 ,  G11B5/66

CPC分类号： C23C14/226 ,  G11B5/66 ,  Y10S428/90 ,  Y10T428/265

摘要： A magnetic recording medium comprising a ferromagnetic metal thin film comprised predominantly of cobalt on a substrate is improved in durability and performance by forming the ferromagnetic metal thin film as a multi-layered structure including at least two layers, one or both of which contain an organic polymer. A plasma-polymerized film may be provided as an interlayer between the layers of the metal thin film or as a topcoat.

摘要翻译： 包含主要由钴在基片上的强磁性金属薄膜的磁记录介质通过形成强磁性金属薄膜作为包括至少两层的多层结构而提高了耐久性和性能，其中一层或两层含有有机层 聚合物。 等离子体聚合膜可以作为金属薄膜层之间的中间层或顶涂层而提供。