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    Pyrazolyldioxothiochromanoyl derivatives
    2.
    发明授权
    Pyrazolyldioxothiochromanoyl derivatives 失效
    吡唑并二恶唑烷基衍生物

    公开(公告)号：US06326333B1

    公开(公告)日：2001-12-04

    申请号：US09674961

    申请日：2000-11-08

    申请人： Matthias Witschel ,  Klaus Langemann ,  Wolfgang von Deyn ,  Ulf Misslitz ,  Ernst Baumann ,  Stefan Engel ,  Guido Mayer ,  Ulf Neidlein ,  Oliver Wagner ,  Martina Otten ,  Karl-Otto Westphalen ,  Helmut Walter

    发明人： Matthias Witschel ,  Klaus Langemann ,  Wolfgang von Deyn ,  Ulf Misslitz ,  Ernst Baumann ,  Stefan Engel ,  Guido Mayer ,  Ulf Neidlein ,  Oliver Wagner ,  Martina Otten ,  Karl-Otto Westphalen ,  Helmut Walter

    IPC分类号： A01N4356

    CPC分类号： C07D409/06 ,  A01N43/56 ,  C07D409/14 ,  C07F9/65586

    摘要： Pyrazolyldioxothiochromanoyl derivatives of the formula I where: X is oxygen, sulfur, S═O, S(═O)2, CR4R5, C═O or C═NR6, R1 is hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl, aminosulfonyl with or without substitution or sulfonylamino with or without substitution; R2 is alkyl, haloalkyl, alkoxy or haloalkoxy; R3 is hydrogen, alkyl or halogen; R4, R5 are hydrogen, nitro, halogen, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, haloalkylthio, alkylsulfinyl, haloalkylsulfinyl, alkylsulfonyl, haloalkylsulfonyl or substituted amino; or R4 and R5 together form a chain which may be substituted and/or interrupted by oxygen or sulfur; or a methylidene group with or without substitution; l is 0 to 4; R7 is substituted pyrazol-4-ylcarbonyl or substituted pyrazol-4-ylmethylidene; and agriculturally useful salts thereof.

    摘要翻译： 式I的吡唑并二氧代二氢吲哚基衍生物其中：X为氧，硫，S = O，S（= O）2，CR4R5，C = O或C = NR6，R1为氢，硝基，卤素，氰基，烷基，卤代烷基，烷氧基， 卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷基亚磺酰基，烷基磺酰基，卤代烷基磺酰基，有或无取代的氨基磺酰基或具有或不具有取代基的磺酰基氨基; R2是烷基，卤代烷基，烷氧基或卤代烷氧基; R3是氢，烷基或卤素; R4，R5是氢， 硝基，卤素，氰基，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，卤代烷硫基，烷基亚磺酰基，卤代烷基亚磺酰基，烷基磺酰基，卤代烷基磺酰基或取代的氨基; 或R 4和R 5一起形成可被氧或硫取代和/或中断的链; 或具有或不具有取代基的亚甲基; l为0至4; R 7为取代的吡唑-4-基羰基或取代的吡唑-4-基亚甲基;及其农业上有用的盐。

    2-benzoylcyclohexane-1,3-dione as herbicides
    3.
    发明授权
    2-benzoylcyclohexane-1,3-dione as herbicides 有权
    2-苯甲酰基环己烷-1,3-二酮作为除草剂

    公开(公告)号：US06432881B1

    公开(公告)日：2002-08-13

    申请号：US09485231

    申请日：2000-02-07

    申请人： Stefan Engel ,  Joachim Rheinheimer ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Matthias Witschel ,  Martina Otten ,  Helmut Walter ,  Karl-Otto Westphalen

    发明人： Stefan Engel ,  Joachim Rheinheimer ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Matthias Witschel ,  Martina Otten ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC分类号： C07D23112

    CPC分类号： A01N43/56 ,  C07D207/20 ,  C07D303/22 ,  C07D305/06 ,  C07D307/28 ,  C07D333/16

    摘要： 2-Benzoylcyclohexane-1,3-diones of formula I : where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxy, alkenyl, alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3 (n=0, 1, 2), —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen or optionally substituted alkyl, haloalkyl, alkenyl, alkynyl, phenyl or phenylalkyl; Q is optionally substituted cyclohexane-2-yl-1,3-dione; X1 is optionally substituted alkylene, propenylene, alkenylene or alkynylene; R4 is hydrogen or optionally substituted alkyl, alkenyl, alkynyl, phenyl, phenylalkyl; Het is a three- to six-membered, optionally substituted heterocyclic or heteroaromatic group; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of formula I, compositions comprising them, and the use of the compounds of formula I and the compositions comprising them for controlling harmful plants are described.

    摘要翻译： 式I的2-苯甲酰基环己烷-1,3-二酮其中：R1和R2各自为氢，巯基，硝基，卤素，氰基，氰硫基，烷基，卤代烷基，烷氧基，烯基，炔基，-OR3，-OCOR3，-OSO2R3 ，-S（O）n R 3（n = 0,1,2），-SO 2 OR 3，-SO 2 N（R 3）2，-NR 3 SO 2 R 3或-NR 3 COR 3; R 3是氢或任选取代的烷基，卤代烷基，烯基，炔基，苯基或苯基 Q是任选取代的环己烷-2-基-1,3-二酮; X 1是任选取代的亚烷基，亚丙烯基，亚烯基或亚炔基; R 4是氢或任选取代的烷基，烯基，炔基，苯基，苯基烷基; 至六元，任选取代的杂环或杂芳族基团;及其农业上有用的盐，制备式I化合物的方法和中间体，包含它们的组合物，以及式I化合物及其组合物用于控制有害植物的用途 被描述。

    2-benzoyl-cyclohexane-1,3-diones
    6.
    发明授权
    2-benzoyl-cyclohexane-1,3-diones 失效

    公开(公告)号：US06559100B1

    公开(公告)日：2003-05-06

    申请号：US09485223

    申请日：2000-02-07

    申请人： Stefan Engel ,  Joachim Rheinheimer ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Matthias Witschel ,  Martina Otten ,  Helmut Walter ,  Karl-Otto Westphalen

    发明人： Stefan Engel ,  Joachim Rheinheimer ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Matthias Witschel ,  Martina Otten ,  Helmut Walter ,  Karl-Otto Westphalen

    IPC分类号： C07D2604

    CPC分类号： C07D307/58 ,  A01N43/80 ,  C07D261/04

    摘要： Substituted 2-benzoylcyclohexane-1,3-diones of the formula I where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3, —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups: hydroxyl, mercapto, amino, cyano, R3, —OR3, —SR3, —N(R3)2, ═NOR3, —OCOR3, —SCOR3, —NR3COR3, —CO2R3, —COSR3, —CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted; n is 0, 1 or 2; Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2; X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups: —OR4, —OCOR4, —OCONHR4 or —OSO2R4; except for those of the abovementioned alkenylene radicals where the double bond is &agr;,&bgr; to the phenyl ring and where Het is linked to the double bond via the &bgr; position; R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals: hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of: nitrogen, oxygen or sulfur, where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5; R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals: cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.

    Benzylidenepyrazolones, their preparation and use
    7.
    发明授权
    Benzylidenepyrazolones, their preparation and use 失效
    亚苄基吡唑啉酮，其制备和用途

    公开(公告)号：US06500950B1

    公开(公告)日：2002-12-31

    申请号：US09765626

    申请日：2001-01-22

    申请人： Joachim Rheinheimer ,  Matthias Witschel ,  Stefan Engel ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Martina Otten ,  Karl-Otto Westphalen ,  Helmut Walter

    发明人： Joachim Rheinheimer ,  Matthias Witschel ,  Stefan Engel ,  Ernst Baumann ,  Wolfgang von Deyn ,  Regina Luise Hill ,  Guido Mayer ,  Ulf Misslitz ,  Oliver Wagner ,  Martina Otten ,  Karl-Otto Westphalen ,  Helmut Walter

    IPC分类号： C07D41310

    CPC分类号： C07D413/06 ,  A01N43/56 ,  A01N43/78 ,  A01N43/80 ,  C07D231/16 ,  C07D231/20

    摘要： Benzylidenepyrazolones of the formula I, where the substituents and the index n have the following meanings: R1 is unsubstituted or substituted C1-C6-alkyl; R2 is unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, halogen, nitro, cyano; R3 is hydrogen, halogen, nitro, cyano, a group NR5R6, OCOR5, NR5COR6, CO2R5, —COSR5, —CONR5R6, C1-C4-alkoxyiminoalkyl, C1-C6-alkylcarbonyl, unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, unsubstituted or substituted C1-C6-alkylthio, unsubstituted or substituted C2-C6-alkenyl, unsubstituted or substituted C2-C6-alkynyl, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, an unsubstituted or substituted 5- or 6-membered saturated or unsaturated heterocycle which may contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulfur atoms as ring members; R4 is C1-C6-alkyl, C1-C4-haloalkyl; R3 and R4 form an optionally substituted saturated or unsaturated 2- or 3-membered bridge which may contain a sulfur atom which may be oxidized to the sulfoxide or sulfone; R5 is hydrogen or unsubstituted or substituted C1-C6-alkyl; R6 is unsubstituted or substituted C1-C6-alkyl; R7 is hydrogen, C1-C6-alkyl or C1-C4-haloalkyl; n is 0,1 or 2, X is hydrogen, chlorine or bromine; where the compounds claimed may be present both in the trans and in the cis form or as a mixture of these isomers, are described.

    摘要翻译： 式I的亚苄基吡唑酮，其中取代基和指数n具有以下含义：R 1是未取代的或取代的C 1 -C 6 - 烷基; R 2是未取代的或取代的C 1 -C 6 - 烷基，未取代或取代的C 1 -C 6 - 烷氧基，卤素 硝基，氰基; R 3是氢，卤素，硝基，氰基，NR 5 R 6，OCOR 5，NR 5 COR 6，CO 2 R 5，-COSR 5，-CONR 5 R 6，C 1 -C 4烷氧基亚氨基烷基，C 1 -C 6烷基羰基，未取代或取代的C 1 -C 6 - 未取代或取代的C 1 -C 6 - 烷硫基，未取代或取代的C 2 -C 6 - 烯基，未取代或取代的C 2 -C 6 - 炔基，未取代或取代的苯基，未取代或取代的苯氧基，未取代的 或可以含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的取代的5或6元饱和或不饱和杂环; R 4是C 1 -C 6烷基，C 1 -C 4卤代烷基; R 3和 R4形成任选取代的饱和或不饱和的2-或3-元 桥可以含有可被氧化成亚砜或砜的硫原子; R5是氢或未取代或取代的C1-C6-烷基; R6是未取代的或取代的C1-C6-烷基; R7是氢，C1-C6-烷基 或C 1 -C 4卤代烷基; n为0,1或2，X为氢，氯或溴;其中要求保护的化合物可以以反式和顺式形式存在，或以这些异构体的混合物存在。