2-benzoylcyclohexane-1,3-dione as herbicides
    4.
    发明授权
    2-benzoylcyclohexane-1,3-dione as herbicides 有权
    2-苯甲酰基环己烷-1,3-二酮作为除草剂

    公开(公告)号:US06432881B1

    公开(公告)日:2002-08-13

    申请号:US09485231

    申请日:2000-02-07

    IPC分类号: C07D23112

    摘要: 2-Benzoylcyclohexane-1,3-diones of formula I : where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, alkyl, haloalkyl, alkoxy, alkenyl, alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3 (n=0, 1, 2), —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen or optionally substituted alkyl, haloalkyl, alkenyl, alkynyl, phenyl or phenylalkyl; Q is optionally substituted cyclohexane-2-yl-1,3-dione; X1 is optionally substituted alkylene, propenylene, alkenylene or alkynylene; R4 is hydrogen or optionally substituted alkyl, alkenyl, alkynyl, phenyl, phenylalkyl; Het is a three- to six-membered, optionally substituted heterocyclic or heteroaromatic group; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of formula I, compositions comprising them, and the use of the compounds of formula I and the compositions comprising them for controlling harmful plants are described.

    摘要翻译: 式I的2-苯甲酰基环己烷-1,3-二酮其中:R1和R2各自为氢,巯基,硝基,卤素,氰基,氰硫基,烷基,卤代烷基,烷氧基,烯基,炔基,-OR3,-OCOR3,-OSO2R3 ,-S(O)n R 3(n = 0,1,2),-SO 2 OR 3,-SO 2 N(R 3)2,-NR 3 SO 2 R 3或-NR 3 COR 3; R 3是氢或任选取代的烷基,卤代烷基,烯基,炔基,苯基或苯基 Q是任选取代的环己烷-2-基-1,3-二酮; X 1是任选取代的亚烷基,亚丙烯基,亚烯基或亚炔基; R 4是氢或任选取代的烷基,烯基,炔基,苯基,苯基烷基; 至六元,任选取代的杂环或杂芳族基团;及其农业上有用的盐,制备式I化合物的方法和中间体,包含它们的组合物,以及式I化合物及其组合物用于控制有害植物的用途 被描述。

    2-benzoyl-cyclohexane-1,3-diones
    7.
    发明授权

    公开(公告)号:US06559100B1

    公开(公告)日:2003-05-06

    申请号:US09485223

    申请日:2000-02-07

    IPC分类号: C07D2604

    摘要: Substituted 2-benzoylcyclohexane-1,3-diones of the formula I where: R1 and R2 are each hydrogen, mercapto, nitro, halogen, cyano, thiocyanato, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-alkynyl, —OR3, —OCOR3, —OSO2R3, —S(O)nR3, —SO2OR3, —SO2N(R3)2, —NR3SO2R3 or —NR3COR3; R3 is hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl or phenyl-C1-C6-alkyl; where the abovementioned alkyl radicals may be partially or fully halogenated and/or may carry one to three of the following groups: hydroxyl, mercapto, amino, cyano, R3, —OR3, —SR3, —N(R3)2, ═NOR3, —OCOR3, —SCOR3, —NR3COR3, —CO2R3, —COSR3, —CON(R3)2, C1-C4-alkyliminooxy, C1-C4-alkoxyamino, C1-C4-alkylcarbonyl, C1-C4-alkoxy-C2-C6-alkoxycarbonyl, C1-C4-alkylsulfonyl, heterocyclyl, heterocyclyloxy, phenyl, benzyl, hetaryl, phenoxy, benzyloxy and hetaryloxy, where the eight last mentioned radicals may in turn be substituted; n is 0, 1 or 2; Q is a cyclohexane-1,3-dione ring with or without substitution which is attached in position 2; X1 is a straight-chain or branched C1-C6-alkylene, a C2-C6-alkenylene or a C2-C6-alkynylene chain, where the abovementioned alkylene, alkenylene or alkynylene radicals may be partially halogenated and/or may carry one to three of the following groups: —OR4, —OCOR4, —OCONHR4 or —OSO2R4; except for those of the abovementioned alkenylene radicals where the double bond is &agr;,&bgr; to the phenyl ring and where Het is linked to the double bond via the &bgr; position; R4 is hydrogen, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, phenyl, phenyl-C1-C6-alkyl, where the abovementioned alkyl, alkenyl or alkynyl radicals may be partially or fully halogenated and/or may be substituted by one or more of the following radicals: hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; Het is a three- to six-membered partially or fully saturated heterocyclic group or a three- to six-membered heteroaromatic group having up to three hetero atoms selected from the group consisting of: nitrogen, oxygen or sulfur, where the abovementioned heterocyclic or heteroaromatic group may be partially or fully halogenated and/or may be substituted by R5; R5 is hydrogen, hydroxyl, mercapto, amino, cyano, nitro, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy, where the alkyl radicals may in each case be substituted by in each case one or more of the following radicals: cyano, formyl, C1-C4-alkylamino, C1-C4-dialkylamino, C1-C4-alkoxycarbonyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkoxy, C1-C4-haloalkoxy; and agriculturally useful salts thereof, processes and intermediates for preparing compounds of the formula I, compositions comprising them, and the use of the compounds of the formula I and compositions comprising them for controlling harmful plants are described.

    Benzylidenepyrazolones, their preparation and use
    8.
    发明授权
    Benzylidenepyrazolones, their preparation and use 失效
    亚苄基吡唑啉酮,其制备和用途

    公开(公告)号:US06500950B1

    公开(公告)日:2002-12-31

    申请号:US09765626

    申请日:2001-01-22

    IPC分类号: C07D41310

    摘要: Benzylidenepyrazolones of the formula I, where the substituents and the index n have the following meanings: R1 is unsubstituted or substituted C1-C6-alkyl; R2 is unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, halogen, nitro, cyano; R3 is hydrogen, halogen, nitro, cyano, a group NR5R6, OCOR5, NR5COR6, CO2R5, —COSR5, —CONR5R6, C1-C4-alkoxyiminoalkyl, C1-C6-alkylcarbonyl, unsubstituted or substituted C1-C6-alkyl, unsubstituted or substituted C1-C6-alkoxy, unsubstituted or substituted C1-C6-alkylthio, unsubstituted or substituted C2-C6-alkenyl, unsubstituted or substituted C2-C6-alkynyl, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy, an unsubstituted or substituted 5- or 6-membered saturated or unsaturated heterocycle which may contain up to 4 nitrogen atoms and/or up to 2 oxygen or sulfur atoms as ring members; R4 is C1-C6-alkyl, C1-C4-haloalkyl; R3 and R4 form an optionally substituted saturated or unsaturated 2- or 3-membered bridge which may contain a sulfur atom which may be oxidized to the sulfoxide or sulfone; R5 is hydrogen or unsubstituted or substituted C1-C6-alkyl; R6 is unsubstituted or substituted C1-C6-alkyl; R7 is hydrogen, C1-C6-alkyl or C1-C4-haloalkyl; n is 0,1 or 2, X is hydrogen, chlorine or bromine; where the compounds claimed may be present both in the trans and in the cis form or as a mixture of these isomers, are described.

    摘要翻译: 式I的亚苄基吡唑酮,其中取代基和指数n具有以下含义:R 1是未取代的或取代的C 1 -C 6 - 烷基; R 2是未取代的或取代的C 1 -C 6 - 烷基,未取代或取代的C 1 -C 6 - 烷氧基,卤素 硝基,氰基; R 3是氢,卤素,硝基,氰基,NR 5 R 6,OCOR 5,NR 5 COR 6,CO 2 R 5,-COSR 5,-CONR 5 R 6,C 1 -C 4烷氧基亚氨基烷基,C 1 -C 6烷基羰基,未取代或取代的C 1 -C 6 - 未取代或取代的C 1 -C 6 - 烷硫基,未取代或取代的C 2 -C 6 - 烯基,未取代或取代的C 2 -C 6 - 炔基,未取代或取代的苯基,未取代或取代的苯氧基,未取代的 或可以含有至多4个氮原子和/或至多2个氧或硫原子作为环成员的取代的5或6元饱和或不饱和杂环; R 4是C 1 -C 6烷基,C 1 -C 4卤代烷基; R 3和 R4形成任选取代的饱和或不饱和的2-或3-元 桥可以含有可被氧化成亚砜或砜的硫原子; R5是氢或未取代或取代的C1-C6-烷基; R6是未取代的或取代的C1-C6-烷基; R7是氢,C1-C6-烷基 或C 1 -C 4卤代烷基; n为0,1或2,X为氢,氯或溴;其中要求保护的化合物可以以反式和顺式形式存在,或以这些异构体的混合物存在。