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    High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith
    4.
    发明授权
    High zeolite content and attrition resistant catalyst, methods for preparing the same and catalyzed processes therewith 有权
    高沸石含量和耐磨耗催化剂，其制备方法和催化方法

    公开(公告)号：US06916757B2

    公开(公告)日：2005-07-12

    申请号：US10151560

    申请日：2002-05-20

    申请人： Michael S. Ziebarth ,  Terry G. Roberie ,  Philip S. Deitz

    发明人： Michael S. Ziebarth ,  Terry G. Roberie ,  Philip S. Deitz

    IPC分类号： B01J27/14 ,  B01J29/40 ,  B01J37/00 ,  B01J29/06

    CPC分类号： B01J29/40 ,  B01J27/14 ,  B01J37/0045 ,  B01J2229/26 ,  B01J2229/42

    摘要： A catalyst composition suitable for reacting hydrocarbons, e.g., conversion processes such as fluidized catalytic cracking (FCC) of hydrocarbons, comprises attrition resistant particulate having a high level (30-85%) of stabilized zeolites having a constraint index of 1 to 12. The stabilized zeolite is bound by a phosphorous compound, alumina and optional binders wherein the alumina added to make the catalyst is about 10% by weight or less and the molar ratio of phosphorous (P2O5) to total alumina is sufficient to obtain an attrition index of about 20 or less. The composition can be used as a catalyst per se or as additive catalyst to a conventional catalyst and is especially suitable for enhancing yields of light olefins, and particularly ethylene, produced during conversion processes.

    摘要翻译： 适用于使烃类反应的催化剂组合物，例如转化过程如烃类的流化催化裂化（FCC），包括具有约1到12的约定指数的稳定沸石的高水平（30-85％）的耐磨颗粒。 稳定的沸石由磷化合物，氧化铝和任选的粘合剂结合，其中加入的氧化铝制成催化剂的量为约10重量％或更少，磷的摩尔比（P 总氧化铝足以获得约20或更小的磨耗指数。 该组合物本身可用作催化剂或作为常规催化剂的添加剂催化剂，特别适用于提高转化过程中产生的轻质烯烃，特别是乙烯的产率。

    Compositions for use in catalytic cracking to make reduced sulfur content gasoline
    8.
    发明授权
    Compositions for use in catalytic cracking to make reduced sulfur content gasoline 失效
    用于催化裂化以降低硫含量汽油的组合物

    公开(公告)号：US6036847A

    公开(公告)日：2000-03-14

    申请号：US624727

    申请日：1996-03-26

    申请人： Michael S. Ziebarth ,  Michael D. Amiridis ,  Robert H. Harding ,  Richard F. Wormsbecher

    发明人： Michael S. Ziebarth ,  Michael D. Amiridis ,  Robert H. Harding ,  Richard F. Wormsbecher

    IPC分类号： C10G11/05 ,  C10G11/02

    CPC分类号： C10G11/05

    摘要： Compositions which contain a titania component have been found which provide reduction of sulfar levels in the gasoline resulting from FCC processes (and other cracking processes conducted in the absence of added hydrogen) without the need for feedstock pretreatments nor added hydrogen. The compositions preferably also contain an alumina supported Lewis acid component. These compositions are preferably used as particles in admixture with catalytic cracking catalyst particles in the circulating catalyst inventory.

    摘要翻译： 已经发现含有二氧化钛组分的组合物，其不需要原料预处理，也不需要加氢，其可以提供由FCC方法（以及在不加氢气的情况下进行的其它裂解方法）导致的汽油中硫磺含量的降低。 组合物优选还含有负载氧化铝的路易斯酸组分。 这些组合物优选在循环催化剂清单中用作与催化裂化催化剂颗粒混合的颗粒。

    Gasoline sulfur reduction in fluid catalytic cracking
    9.
    发明授权
    Gasoline sulfur reduction in fluid catalytic cracking 有权
    汽油硫化液流化催化裂化

    公开(公告)号：US07803267B2

    公开(公告)日：2010-09-28

    申请号：US11118541

    申请日：2005-04-29

    申请人： Arthur W. Chester ,  Terry G. Roberie ,  Hye Kyung C. Timken ,  Michael S. Ziebarth

    发明人： Arthur W. Chester ,  Terry G. Roberie ,  Hye Kyung C. Timken ,  Michael S. Ziebarth

    IPC分类号： C10G11/05

    CPC分类号： B01J29/076 ,  B01J29/072 ,  B01J29/166 ,  B01J2229/42 ,  C10G11/05

    摘要： The sulfur content of liquid cracking products, especially the cracked gasoline, of the catalytic cracking process is reduced by the use of a sulfur reduction catalyst composition comprising a porous molecular sieve which contains a metal in an oxidation state above zero within the interior of the pore structure of the sieve as well as a cerium component which enhances the stability and sulfur reduction activity of the catalyst. The molecular sieve is normally a faujasite such as USY. The primary sulfur reduction component is normally a metal of Period 3 of the Periodic Table, preferably vanadium. The sulfur reduction catalyst may be used in the form of a separate particle additive or as a component of an integrated cracking/sulfur reduction catalyst.

    摘要翻译： 通过使用包含多孔分子筛的硫还原催化剂组合物来减少液体裂解产物，特别是裂化汽油的硫含量，所述硫还原催化剂组合物在孔内部含有高于零的氧化态的金属 筛子的结构以及提高催化剂的稳定性和硫还原活性的铈组分。 分子筛通常是诸如USY的八面沸石。 初级硫还原组分通常是元素周期3的金属，优选为钒。 硫还原催化剂可以以单独的颗粒添加剂的形式使用，也可以作为综合的裂解/硫还原催化剂的组分使用。