Fluorinated metal-organic frameworks for hydrocarbon storage
    3.
    发明授权
    Fluorinated metal-organic frameworks for hydrocarbon storage 有权
    用于碳氢化合物储存的氟化金属 - 有机骨架

    公开(公告)号:US08715395B2

    公开(公告)日:2014-05-06

    申请号:US13269451

    申请日:2011-10-07

    IPC分类号: C07F1/10 B01J20/22

    摘要: Fluorinated metal-organic frameworks (“FMOFs”) are capable of adsorbing and desorbing hydrocarbons, namely, C6-C8 hydrocarbon oil components (n-hexane, cyclohexane, benzene and toluene). FMOFs can be arranged in a variety of configurations and have internal hollow channels and cavities. In FMOFs, hydrogen atoms have been substituted completely or partially with fluorine atoms or fluorinated groups in each linking organic ligand. These FMOFs can adsorb C6-C8 hydrocarbons, up to 500 kg/m3 as demonstrated for toluene, through a combination of superhydrophobicity and capillary action. No water adsorption was detectable even under extreme conditions including moist air near 100% relative humidity and immersion in water for multiple weeks, demonstrating far superior water resistance to BPL carbon and zeolites. These materials are stable and can be readily recycled by simple desorption many times. The FMOFs have applications in removal or containment of organics, particularly in the fields of oil spill cleanup and hydrocarbon storage.

    摘要翻译: 氟化金属 - 有机骨架(“FMOF”)能够吸附和解吸碳氢化合物,即C6-C8烃油组分(正己烷,环己烷,苯和甲苯)。 FMOF可以以各种配置布置并具有内部空心通道和空腔。 在FMOF中,氢原子在每个连接的有机配体中被氟原子或氟化基团完全或部分取代。 通过超疏水性和毛细作用的组合,这些FMOF可以吸附高达500kg / m 3的C6-C8烃,如用于甲苯所证明的那样。 即使在极端条件下也无法检测到水分吸附,包括接近100%相对湿度的潮湿空气并浸入水中多个星期,这表明对BPL碳和沸石具有极好的耐水性。 这些材料是稳定的,并且可以通过简单的解吸多次循环使用。 FMOF应用于去除或遏制有机物,特别是在溢油清除和碳氢化合物储存领域。

    FLUORINATED METAL-ORGANIC FRAMEWORKS FOR HYDROCARBON STORAGE
    4.
    发明申请
    FLUORINATED METAL-ORGANIC FRAMEWORKS FOR HYDROCARBON STORAGE 有权
    用于储存的氟化金属有机物质

    公开(公告)号:US20120118153A1

    公开(公告)日:2012-05-17

    申请号:US13269451

    申请日:2011-10-07

    IPC分类号: B01D53/02 C07F1/10

    摘要: Fluorinated metal-organic frameworks (“FMOFs”) are capable of adsorbing and desorbing hydrocarbons, namely, C6-C8 hydrocarbon oil components (n-hexane, cyclohexane, benzene and toluene). FMOFs can be arranged in a variety of configurations and have internal hollow channels and cavities. In FMOFs, hydrogen atoms have been substituted completely or partially with fluorine atoms or fluorinated groups in each linking organic ligand. These FMOFs can adsorb C6-C8 hydrocarbons, up to 500 kg/m3 as demonstrated for toluene, through a combination of superhydrophobicity and capillary action. No water adsorption was detectable even under extreme conditions including moist air near 100% relative humidity and immersion in water for multiple weeks, demonstrating far superior water resistance to BPL carbon and zeolites. These materials are stable and can be readily recycled by simple desorption many times. The FMOFs have applications in removal or containment of organics, particularly in the fields of oil spill cleanup and hydrocarbon storage.

    摘要翻译: 氟化金属 - 有机骨架(“FMOF”)能够吸附和解吸碳氢化合物,即C6-C8烃油组分(正己烷,环己烷,苯和甲苯)。 FMOF可以以各种配置布置并具有内部空心通道和空腔。 在FMOF中,氢原子在每个连接的有机配体中被氟原子或氟化基团完全或部分取代。 通过超疏水性和毛细作用的组合,这些FMOF可以吸附高达500kg / m 3的C6-C8烃,如用于甲苯所证明的那样。 即使在极端条件下也无法检测到水分吸附,包括接近100%相对湿度的潮湿空气并浸入水中多个星期,这表明对BPL碳和沸石具有极好的耐水性。 这些材料是稳定的,并且可以通过简单的解吸多次循环使用。 FMOF应用于去除或遏制有机物,特别是在溢油清除和碳氢化合物储存领域。

    Suture Fixation Arthroscope Apparatus of the Temporomandibular Joint Disk
    5.
    发明申请
    Suture Fixation Arthroscope Apparatus of the Temporomandibular Joint Disk 审中-公开
    颞下颌关节盘缝合固定关节镜装置

    公开(公告)号:US20110106111A1

    公开(公告)日:2011-05-05

    申请号:US12992085

    申请日:2010-02-05

    IPC分类号: A61B17/04

    摘要: A suture fixation arthroscope apparatus of the temporomandibular joint (TMJ) disk comprises a first suture needle and a first inner core, a second suture needle and a second inner core, and a third suture needle. The tail ends of the first and second suture needles are connected with a big handle via a valve panel, a vertical groove is opened towards the center of a circle of the surface of the big handle, a horizontal groove which is the same size as the vertical groove is vertically set at the place of the big handle connecting the valve panel. The first inner core includes a seamless tube and a top welded with wire snares, the second inner core includes a seamless tube and a top welded with a crochet hook, the radian near the tails of the first and second inner cores is 90 degrees, a small handle is connected at the tails. The first and second inner cores can pass through the vertical groove of the big handle of the first and second suture needles respectively, the corner of the 90 degrees tail is able to lock rightwards or leftwards at the horizontal groove, the wire snare or the crochet hook at the top of inner cores are able to come out from the top of the suture needles.

    摘要翻译: 颞下颌关节(TMJ)盘的缝合线固定关节镜装置包括第一缝合针和第一内芯,第二缝合针和第二内芯以及第三缝合针。 第一缝合针和第二缝合针的尾端通过阀板与大把手连接,垂直槽朝向大把手表面的圆的中心开口,水平槽的尺寸与 垂直槽垂直设置在连接阀面板的大把手的位置。 第一内芯包括无缝管和顶部焊接有线圈,第二内芯包括无缝管和顶部焊接有钩针,在第一和第二内芯的尾部附近的弧度为90度, 小把手连接在尾部。 第一和第二内芯可分别穿过第一和第二缝合针的大手柄的垂直槽,90度的尾部的角部能够在水平凹槽处向右或向左锁定,线圈或钩针 内芯顶部的钩子能够从缝合针的顶部出来。

    Method for depositing high-quality microcrystalline semiconductor materials
    7.
    发明申请
    Method for depositing high-quality microcrystalline semiconductor materials 失效
    沉积高品质微晶半导体材料的方法

    公开(公告)号:US20050164474A1

    公开(公告)日:2005-07-28

    申请号:US10765435

    申请日:2004-01-27

    摘要: A process for the plasma deposition of a layer of a microcrystalline semiconductor material is carried out by energizing a process gas which includes a precursor of the semiconductor material and a diluent with electromagnetic energy so as to create a plasma therefrom. The plasma deposits a layer of the microcrystalline semiconductor material onto the substrate. The concentration of the diluent in the process gas is varied as a function of the thickness of the layer of microcrystalline semiconductor material which has been deposited. Also disclosed is the use of the process for the preparation of an N-I-P type photovoltaic device.

    摘要翻译: 微晶半导体材料层的等离子体沉积的方法是通过对包含半导体材料的前体的工艺气体和具有电磁能量的稀释剂进行激励,从而产生等离子体来进行的。 等离子体将一层微晶半导体材料沉积到基底上。 处理气体中稀释剂的浓度随着沉积的微晶半导体材料层的厚度而变化。 还公开了该方法用于制备N-I-P型光伏器件的用途。

    BACK REFLECTOR WITH NANOCRYSTALLINE PHOTOVOLTAIC DEVICE
    8.
    发明申请
    BACK REFLECTOR WITH NANOCRYSTALLINE PHOTOVOLTAIC DEVICE 审中-公开
    背光反射器与纳米晶体光电器件

    公开(公告)号:US20130000717A1

    公开(公告)日:2013-01-03

    申请号:US13537954

    申请日:2012-06-29

    IPC分类号: H01L31/0232 H01L31/18

    摘要: A photovoltaic device and processes of manufacture are provided that employ particularly configured, textured back reflector structures that maintain a smooth, non-textured surface at the interface between the lowermost doped layer of semiconductor material and the intrinsic, light absorbing layer of nanocrystalline semiconductor material. The back reflector structure provides exhibit both superior short circuit current and a superior fill factor to a photovoltaic device such as those using nanocrystalline semiconductor materials.

    摘要翻译: 提供光伏器件和制造工艺,其采用特别配置的纹理化后反射器结构,其在半导体材料的最下掺杂层和纳米晶体半导体材料的本征光吸收层之间的界面处保持光滑的非纹理表面。 背反射器结构提供了优异的短路电流和对诸如使用纳米晶体半导体材料的光伏器件的光伏器件的优异的填充因子。

    TANDEM PHOTOVOLTAIC DEVICE WITH DUAL FUNCTION SEMICONDUCTOR LAYER
    9.
    发明申请
    TANDEM PHOTOVOLTAIC DEVICE WITH DUAL FUNCTION SEMICONDUCTOR LAYER 审中-公开
    具有双功能半导体层的TANDEM光伏器件

    公开(公告)号:US20110220177A1

    公开(公告)日:2011-09-15

    申请号:US12721153

    申请日:2010-03-10

    IPC分类号: H01L31/05 H01B1/00 H01B1/04

    摘要: A tandem photovoltaic device includes at least two photovoltaic cells stacked in an optical and electrical series relationship. At least one of the tandem cells includes a dual function semiconductor layer fabricated from a dual function semiconductor material. This dual function layer is an electronically active constituent of the cell. The dual function layer also is optically active and creates a reflective condition which redirects a portion of the light which has passed through the cell back through the cell's active layers to photo generate additional photocurrent. Use of the dual function material eliminates the need for incorporating separate semiconductor and reflective layers in a photovoltaic device. Further disclosed are exemplary formulations of some dual function materials.

    摘要翻译: 串联光伏器件包括至少两个以光学和电子系列关系堆叠的光伏电池。 串联电池中的至少一个包括由双功能半导体材料制成的双功能半导体层。 该双重功能层是电池的电子活性成分。 双重功能层也是光学活性的并且产生反射状态,其将已经通过单元的光的一部分重新定向穿过单元的活性层,以产生额外的光电流。 使用双功能材料消除了在光伏器件中并入分离的半导体和反射层的需要。 进一步公开的是一些双功能材料的示例性配方。

    METHOD AND APPARATUS FOR THE LASER SCRIBING OF ULTRA LIGHTWEIGHT SEMICONDUCTOR DEVICES
    10.
    发明申请
    METHOD AND APPARATUS FOR THE LASER SCRIBING OF ULTRA LIGHTWEIGHT SEMICONDUCTOR DEVICES 失效
    超轻型半导体器件激光扫描的方法和装置

    公开(公告)号:US20080233715A1

    公开(公告)日:2008-09-25

    申请号:US12053712

    申请日:2008-03-24

    IPC分类号: H01L21/268 B23K26/00

    摘要: A system for the laser scribing of semiconductor devices includes a laser light source operable to selectably deliver laser illumination at a first wavelength and at a second wavelength which is shorter than the first wavelength. The system further includes a support for a semiconductor device and an optical system which is operative to direct the laser illumination from the light source to the semiconductor device. The optical system includes optical elements which are compatible with the laser illumination of the first wavelength and the laser illumination of the second wavelength. In specific instances, the first wavelength is long wavelength illumination such as illumination of at least 1000 nanometers, and the second wavelength is short wavelength illumination which in specific instances is 300 nanometers or shorter. By the use of the differing wavelengths, specific layers of the semiconductor device may be scribed without damage to subjacent layers. Also disclosed are specific scribing processes.

    摘要翻译: 用于半导体器件的激光刻划的系统包括可操作以可选择地提供比第一波长短的第一波长和第二波长的激光照明的激光光源。 该系统还包括用于半导体器件和光学系统的支撑件,该系统可操作以将激光照明从光源引导到半导体器件。 光学系统包括与第一波长的激光照射和第二波长的激光照射兼容的光学元件。 在具体情况下,第一波长是诸如至少1000纳米的照明的长波长照明,而第二波长是在特定情况下为300纳米或更短的短波长照明。 通过使用不同的波长,半导体器件的特定层可以被划刻而不损坏下层。 还公开了具体的划线工艺。