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    Process for the Preparation of Random Radical Copolymers, and Active Substance Compositions Obtainable Therefrom
    2.
    发明申请
    Process for the Preparation of Random Radical Copolymers, and Active Substance Compositions Obtainable Therefrom 审中-公开
    制备随机自由基共聚物及其可获得的活性物质组合物的方法

    公开(公告)号：US20110237439A1

    公开(公告)日：2011-09-29

    申请号：US13132117

    申请日：2009-11-30

    申请人： Holger Tuerk ,  Cedric Dieleman ,  Hans-Guenter Bohrmann ,  Sebastian Koltzenburg

    发明人： Holger Tuerk ,  Cedric Dieleman ,  Hans-Guenter Bohrmann ,  Sebastian Koltzenburg

    IPC分类号： A01N25/00 ,  C08F2/06 ,  C08F20/58 ,  A01P3/00 ,  A01P13/00

    CPC分类号： A01N25/10 ,  A01N43/653 ,  A01N47/24 ,  C08F2/04 ,  C08F2/06 ,  C08F220/06 ,  C08F220/18 ,  C08F220/56 ,  C08F220/58 ,  A01N2300/00

    摘要： A process for the preparation of random radical copolymers which comprises a) at least one olefinically unsaturated sulfonic acid of the formula (I), where n is 0 to 10; X is 0 or NR5; R1 is hydrogen or methyl; R2, R3 independently of one another are hydrogen or C1- to C6-alkyl and R5 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, salts thereof or mixtures of acid and salts and b) at least two structurally different olefinically unsaturated monomers of the formula (II), where Y is O or NR7; R5 is hydrogen or methyl; R6 is alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 is hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, it being possible for the aryl radicals to be monosubstituted or polysubstituted, and c) if appropriate, one or more olefinically unsaturated monomers which differ structurally from components (a) and (b), d) at least one initiator being dissolved either (i) in a solvent mixture comprising water and a water-soluble organic solvent with a boiling point of less than 140° C. or (ii) being dissolved in one or more pure alcohols by heating, and being polymerized in solution, where the polymer formed remains in solution. The copolymers which are obtainable by the process are suitable as formulation adjuvants in agrochemical active substance compositions.

    摘要翻译： 一种制备无规自由基共聚物的方法，其包括a）至少一种式（I）的烯属不饱和磺酸，其中n为0至10; X为0或NR5; R1是氢或甲基; R 2，R 3彼此独立地是氢或C 1 -C 6 - 烷基，R 5是氢，烷基，芳基，烷基芳基，芳基烷基，烷氧基烷基，芳氧基烷基，烷氧基芳基，羟基烷基，（二）烷基氨基烷基，（二）烷基氨基芳基，（二） 芳基氨基烷基，烷基芳基氨基烷基或烷基芳基氨基芳基，芳基可以是单取代或多取代的，其盐或酸和盐的混合物，以及b）至少两种结构不同的具有式（II）的烯属不饱和单体，其中Y是O或 NR7; R5是氢或甲基; R6是烷基，羟基烷基，（二）烷基氨基烷基或（二）烷基氨基芳基，R7是氢，烷​​基，芳基，烷基芳基，芳基烷基，烷氧基烷基，芳氧基烷基，烷氧基芳基，羟基烷基，（二）烷基氨基烷基，（二）烷基氨基芳基，（二） 烷基芳基氨基烷基或烷基芳基氨基芳基，芳基可以被单取代或多取代，以及c）如果合适的话，一种或多种在结构上与组分（a）和（b）不同的烯属不饱和单体，d）至少一个引发剂 （i）在包含水和沸点小于140℃的水溶性有机溶剂的溶剂混合物中溶解，或（ii）通过加热溶解在一种或多种纯醇中，并在溶液中聚合， 所形成的聚合物保留在溶液中。 可通过该方法获得的共聚物适合作为农药活性物质组合物中的制剂佐剂。

    FUNCTIONALIZED HIGHLY BRANCHED MELAMINE-POLYAMINE POLYMERS
    10.
    发明申请
    FUNCTIONALIZED HIGHLY BRANCHED MELAMINE-POLYAMINE POLYMERS 审中-公开
    功能齐全的高分子量的甲酰胺聚合物

    公开(公告)号：US20120252987A1

    公开(公告)日：2012-10-04

    申请号：US13516426

    申请日：2010-12-15

    申请人： Maxim Peretolchin ,  Marta Reinoso Garcia ,  Holger Tuerk ,  Daniel Schoenfelder ,  Sophia Ebert

    发明人： Maxim Peretolchin ,  Marta Reinoso Garcia ,  Holger Tuerk ,  Daniel Schoenfelder ,  Sophia Ebert

    IPC分类号： C08G73/02 ,  C07D251/70

    CPC分类号： C08G73/0273 ,  C04B24/166 ,  C04B24/243 ,  C04B24/32 ,  C04B2103/408 ,  C08G73/0644 ,  C08G83/005 ,  C08G83/006 ,  C08L79/02 ,  C08L79/04 ,  C11D1/90 ,  C11D1/92 ,  C11D3/28

    摘要： The present invention relates to a method for producing amphiphilic functionalized highly branched melamine-polyamine polymers by condensing melamine and optionally a melamine derivate having at least one different amine having at least two primary amino groups and optionally also with urea and/or at least one urea derivative and/or with at least one at least difunctional diisocyanate or polyisocyanate and/or at least one carbolic acid having at least two carboxyl groups or at least one derivative thereof, optionally quaternizing a portion of the amino groups of the polymer thereby obtained, reacting the polymer thus obtained with at least one compound capable of undergoing a condensation or addition reaction with amino groups, and optionally quaternizing at least part of the amino groups of the polymer obtained in the first step. The invention further relates to the amphiphilic functionalized highly branched melamine-polyamine polymers that can be obtained by the method according to the invention, and to the use thereof as surface active agents.

    摘要翻译： 本发明涉及通过将三聚氰胺和任选地具有至少一种具有至少两个伯氨基的不同胺和任选地还含有尿素和/或至少一种尿素的三聚氰胺衍生物缩合制备两亲官能化的高度支化的三聚氰胺 - 聚胺聚合物的方法 衍生物和/或与至少一种至少二官能二异氰酸酯或多异氰酸酯和/或至少一种具有至少两个羧基基团的至少一种碳酸或至少一种衍生物，任选季铵化所得聚合物的一部分氨基，从而使 由此获得的聚合物与至少一种能够与氨基进行缩合或加成反应的化合物，以及任选季铵化至少部分第一步获得的聚合物的氨基。 本发明还涉及通过本发明的方法获得的两亲官能化的高度支化的三聚氰胺 - 聚胺聚合物及其作为表面活性剂的用途。