公开(公告)号：US20140272201A1

公开(公告)日：2014-09-18

申请号：US14202757

申请日：2014-03-10

Applicant: NITTO DENKO CORPORATION

Inventor： Ai TAKEDA ,  Katsuhiko KAMIYA ,  Kiyoe SHIGETOMI ,  Takahiro NONAKA

IPC: C09J133/08

CPC classification number: C09J133/066 ,  B32B2457/202 ,  B32B2457/208 ,  C09J7/22 ,  C09J7/38 ,  G02F1/13338 ,  Y10T428/1077 ,  Y10T428/2887 ,  Y10T428/2891

Abstract: It is an object of the invention to provide a pressure-sensitive adhesive capable of forming a pressure-sensitive adhesive layer having high resistance to sebum and high resistance to moisture-induced clouding and also having low dielectric constant. The invention relates to a pressure-sensitive adhesive comprising a (meth)acryl-based polymer obtained by polymerization of a monomer component containing 65 to 88 parts by weight of an alkyl (meth)acrylate having an alkyl group of 8 to 22 carbon atoms and 12 to 35 parts by weight of an alkyl (meth)acrylate having a secondary hydroxyl group based on 100 parts by weight of the total amount of the alkyl (meth)acrylate having an alkyl group of 8 to 22 carbon atoms and the alkyl (meth)acrylate having a secondary hydroxyl group.

Abstract translation: 本发明的目的是提供一种压敏粘合剂，其能够形成具有高耐皮脂性和高耐湿性引起的混浊并且也具有低介电常数的压敏粘合剂层。 本发明涉及一种压敏粘合剂，其包含通过聚合含有65至88重量份具有8至22个碳原子的烷基的（甲基）丙烯酸烷基酯的单体组分而获得的（甲基）丙烯酰基聚合物和 12〜35重量份基于碳原子数为8〜22的烷基的（甲基）丙烯酸烷基酯的总计100重量份的具有仲羟基的（甲基）丙烯酸烷基酯和（甲基）丙烯酸烷基酯 ）具有仲羟基的丙烯酸酯。

公开(公告)号：US20140147668A1

公开(公告)日：2014-05-29

申请号：US14171199

申请日：2014-02-03

Applicant: NITTO DENKO CORPORATION

Inventor： Masato YAMAGATA ,  Masayuki OKAMOTO ,  Kiyoe SHIGETOMI ,  Ryo KANNO

IPC: C09J7/02

CPC classification number: C08L33/12 ,  C08F220/14 ,  C08F220/18 ,  C08G77/46 ,  C08L33/10 ,  C08L2205/05 ,  C09D171/02 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J133/06 ,  C09J183/12 ,  C09J2201/622 ,  C09J2203/318 ,  C09J2433/00 ,  Y10T428/2848 ,  Y10T428/2891 ,  C08F2220/1858 ,  C08F220/20 ,  C08F2220/1875 ,  C08F2220/1841 ,  C08F2220/1825 ,  C08F226/10 ,  C08L33/06

Abstract: A pressure-sensitive adhesive composition includes: 100 parts by mass of a polymer (A) having a glass transition temperature lower than 0° C.; 0.05 parts by mass to 3 parts by mass of a (meth)acrylic polymer (B) having a weight average molecular weight (MwB) of 1000≦MwB

Abstract translation: 压敏粘合剂组合物包括：100质量份的玻璃化转变温度低于0℃的聚合物（A）; 0.05质量份〜3质量份的重均分子量（MwB）为1000＆lt; 1EE的（甲基）丙烯酸系聚合物（B）; MwB <30000，作为单体单元，含有（甲基） 由以下通式（1）表示的脂环结构： 0.005质量份〜1质量份的离子性化合物（C）; 和0.01质量份〜2.5质量份具有聚氧化烯链的化合物（D）。 CH2 = C（R1）COOR2（1）[其中R1是氢原子或甲基，R2是具有脂环结构的脂环族烃基]

公开(公告)号：US20170002235A1

公开(公告)日：2017-01-05

申请号：US15266653

申请日：2016-09-15

Applicant: NITTO DENKO CORPORATION

Inventor： Masatsugu HIGASHI ,  Kiyoe SHIGETOMI ,  Koji SHITARA ,  Akiko TANAKA ,  Katsuhiko KAMIYA ,  Azusa ISEKI

IPC: C09J7/02 ,  H01B5/00

CPC classification number: H01B5/002 ,  B32B7/12 ,  B32B27/08 ,  B32B27/306 ,  B32B27/36 ,  B32B2307/202 ,  B32B2307/412 ,  B32B2307/516 ,  B32B2457/00 ,  B32B2457/202 ,  B32B2457/204 ,  C08F220/18 ,  C08F222/1006 ,  C08F226/06 ,  C08G18/6266 ,  C08G18/8029 ,  C08G2170/40 ,  C09J7/385 ,  C09J133/14 ,  C09J175/04 ,  C09J2203/318 ,  C09J2433/00 ,  C09J2467/006 ,  G02F1/13338 ,  G02F2202/28 ,  Y10T428/2891 ,  C08F2220/1875 ,  C08F220/20 ,  C08F2220/1858 ,  C08F226/10

Abstract: A pressure-sensitive adhesive of the invention include a (meth)acryl-based polymer obtained by polymerization of a monomer component including 30 to 99.5% by weight of an alkyl (meth)acrylate having an alkyl group of 10 to 18 carbon atoms at an ester end and 0.5 to 50% by weight of a cyclic nitrogen-containing monomer. The pressure-sensitive adhesive has a satisfactory level of adhesive performance and can form a pressure-sensitive adhesive layer with a lower dielectric constant and reliable moisture resistance.

Abstract translation: 本发明的压敏粘合剂包括通过聚合含有30至99.5重量％的具有10至18个碳原子的烷基的（甲基）丙烯酸烷基酯的单体组分而获得的（甲基）丙烯酸类聚合物， 酯末端和0.5〜50重量％的含环状含氮单体。 该粘合剂具有令人满意的粘合性能，可以形成具有较低介电常数和可靠的耐湿性的压敏粘合剂层。

公开(公告)号：US20130177758A1

公开(公告)日：2013-07-11

申请号：US13778880

申请日：2013-02-27

Applicant: Nitto Denko Corporation

Inventor： Kiyoe SHIGETOMI ,  Masayuki OKAMOTO ,  Masato YAMAGATA ,  Jun AKIYAMA

IPC: C09J177/00 ,  C09J7/02 ,  C09J133/10

CPC classification number: C09J177/00 ,  C08K7/00 ,  C08L57/02 ,  C09J7/10 ,  C09J7/22 ,  C09J7/385 ,  C09J133/06 ,  C09J133/10 ,  C09J2201/36 ,  C09J2201/606 ,  C09J2205/106 ,  C09J2205/11 ,  C09J2400/00 ,  C09J2400/24 ,  C09J2433/00 ,  Y10T428/249986 ,  Y10T428/2848 ,  Y10T428/2891

Abstract: An acrylic pressure-sensitive adhesive composition contains 100 parts by mass of an acrylic polymer (A), 1 to 70 parts by mass of a (meth)acrylic polymer (B) having a weight average molecular weight (Mw) of 1000≦Mw

Abstract translation: 丙烯酸类压敏粘合剂组合物含有100质量份丙烯酸类聚合物（A），1〜70质量份重均分子量（Mw）为1000〜（Mw）的（甲基）丙烯酸系聚合物（B） 30000和1〜50质量份氢化增粘树脂（C）。 （甲基）丙烯酸系聚合物（B）是作为粘合剂组合物的重均分子量小于丙烯酸类聚合物（A）的聚合物，与氢化增粘树脂（C ）。

公开(公告)号：US20190111641A1

公开(公告)日：2019-04-18

申请号：US16089143

申请日：2016-03-29

Applicant: ESSILOR INTERNATIONAL ,  NITTO DENKO CORPORATION

Inventor： Violaine COUE ,  Catherine BERGER ,  Manuela DESOUSA ,  Tatsuya SUZUKI ,  Katsuhiko KAMIYA ,  Kiyoe SHIGETOMI ,  Shinji HOSHINO ,  Junichi NAKAYAMA

IPC: B29D11/00

Abstract: The invention relates to a functionalized laminated optical element comprising: —An optical base element; —A functional film structure consisting of a single layer or a multilayer structure; —A layer of a pressure-sensitive adhesive of optical quality, placed between one surface of the optical base element and the functional film structure so as to permanently retain said functional film structure on the surface of the optical base element. Said functionalized laminated optical element maintains its integrity after typical processing of an optical article which includes wheel edging. More particularly the invention relates to the use of a specific adhesive system for improving the wheel edging resistance of functionalized laminated optical element. The functional laminated optical may be an ophthalmic lens.

公开(公告)号：US20170081557A1

公开(公告)日：2017-03-23

申请号：US15371416

申请日：2016-12-07

Applicant: NITTO DENKO CORPORATION

Inventor： Kiyoe SHIGETOMI ,  Ryo KANNO

IPC: C09J7/02 ,  C08F220/18 ,  C09J5/00 ,  C09J133/14

Abstract: A pressure-sensitive adhesive sheet has a substrate and a pressure-sensitive adhesive layer laminated on at least one side of the substrate. The pressure-sensitive adhesive layer contains a (meth)acrylic polymer having a weight average molecular weight of 10000 or more but less than 50000. Pressure-sensitive adhesive force, occurring after 30 minutes since the pressure-sensitive adhesive layer was attached to an ABS plate, is 1.0 [N/20 mm] or less, pressure-sensitive adhesive force, occurring after 24 hours since the pressure-sensitive adhesive layer was attached to an ABS plate, is 2.5 [N/20 mm] or less, and pressure-sensitive adhesive force, occurring after 30 minutes at 23° C. since the pressure-sensitive adhesive layer was attached to an ABS plate and then heated at 80° C. for 5 minutes, is 6.5 [N/20 mm] or more.

公开(公告)号：US20160032154A1

公开(公告)日：2016-02-04

申请号：US14882748

申请日：2015-10-14

Applicant: NITTO DENKO CORPORATION

Inventor： Ryo KANNO ,  Kiyoe SHIGETOMI

IPC: C09J133/08 ,  C09J7/02

CPC classification number: C09J133/08 ,  C09J7/385 ,  C09J143/04 ,  C09J2203/318 ,  C09J2203/326 ,  C09J2433/00

Abstract: A pressure-sensitive adhesive composition according to an embodiment includes: 100 parts by mass of a polymer (A) having a glass transition temperature lower than 0° C.; and 0.1 to 20 parts by mass of a polymer (B) that contains, as monomer units, both a monomer having a functional group equivalent (Fge) of 1000 g/mol≦Fge

Abstract translation: 根据一个实施方案的压敏粘合剂组合物包括：100质量份具有玻璃化转变温度低于0℃的聚合物（A）; 和0.1〜20质量份含有作为单体单元的官能团当量（Fge）为1000g / mol＆lt; 1lE; Fge <15000g / mol并具有聚有机硅氧烷骨架的单体的聚合物（B） 单体，其均聚物的玻璃化转变温度为40℃以上，重均分子量（MwB）为10000＆nlE; MwB＆nlE; 100000。

公开(公告)号：US20150024198A1

公开(公告)日：2015-01-22

申请号：US14506225

申请日：2014-10-03

Applicant: NITTO DENKO CORPORATION

Inventor： Masato YAMAGATA ,  Masayuki OKAMOTO ,  Kiyoe SHIGETOMI ,  Ryo KANNO

IPC: C09J133/14 ,  C09J7/02

CPC classification number: C09J133/14 ,  B32B7/12 ,  B32B27/08 ,  B32B27/283 ,  B32B27/308 ,  B32B2307/21 ,  B32B2307/412 ,  B32B2551/00 ,  C08G77/46 ,  C08L33/10 ,  C09J7/20 ,  C09J7/22 ,  C09J7/38 ,  C09J7/385 ,  C09J133/04 ,  C09J133/06 ,  C09J201/00 ,  C09J2483/00 ,  G02B1/14 ,  G02B5/30 ,  Y10T428/2891 ,  Y10T428/31663

Abstract: A pressure-sensitive adhesive composition includes: 100 parts by mass of a polymer (A) (Tg:lower than 0° C.); 0.05 to 3 parts by mass of a (meth)acrylic polymer (B) (MWB:1000≦MWB

Abstract translation: 压敏粘合剂组合物包括：100质量份聚合物（A）（Tg：低于0℃）; 0.05〜3质量份（甲基）丙烯酸系聚合物（B）（MWB：1000＆amp; MW; MWB <50000，Tg：30〜300℃） 和由以下通式（C1）〜（C3）中的任一个表示的具有聚氧化烯链的有机聚硅氧烷化合物（C）。 [在（C1）〜（C3）中，R1为一价有机基团，R2〜R4各自为亚烷基，R5为氢或有机基，a和b分别为0〜1000的整数 但是，它们一次不是0）; 在（C1）中，m和n分别为0〜1000的整数（但一次不为0）; 和（C2）和（C3）中，m为1〜2000的整数。]

公开(公告)号：US20130274419A1

公开(公告)日：2013-10-17

申请号：US13911194

申请日：2013-06-06

Applicant: NITTO DENKO CORPORATION

Inventor： Masayuki OKAMOTO ,  Masahito NIWA ,  Jun AKIYAMA ,  Kiyoe SHIGETOMI

IPC: C09J133/08

CPC classification number: C09J133/08 ,  C08F120/18 ,  C08F220/14 ,  C08F220/18 ,  C08F222/1006 ,  C08F2220/1858 ,  C09J133/06 ,  C08F226/08 ,  C08F220/06

Abstract: An acrylic pressure-sensitive adhesive composition contains: an acrylic polymer (A); and a (meth)acrylic polymer (B) that includes, as a monomer unit, a (meth)acrylic monomer having a tricyclic or higher alicyclic structure and that has a weight average molecular weight of 1000 or more and less than 30000.

Abstract translation: 丙烯酸类压敏粘合剂组合物包含：丙烯酸类聚合物（A）; 和作为单体单元的（甲基）丙烯酸系聚合物（B），其具有三环或更高脂环结构的重均分子量为1000以上且小于30000的（甲基）丙烯酸单体。

公开(公告)号：US20160369136A1

公开(公告)日：2016-12-22

申请号：US15181517

申请日：2016-06-14

Applicant: NITTO DENKO CORPORATION

Inventor： Tatsuya SUZUKI ,  Katsuhiko KAMIYA ,  Kiyoe SHIGETOMI ,  Shinji HOSHINO

IPC: C09J133/08 ,  C09J7/02

CPC classification number: C09J7/385 ,  C09J133/06 ,  C09J2433/00 ,  C08F2220/1825 ,  C08F220/20 ,  C08F2220/1841 ,  C08F220/04

Abstract: Provided is a PSA composition for forming a PSA comprising a (meth)acrylic polymer, comprising, as monomeric components constituting the (meth)acrylic polymer: (A) a C2-18 alkyl (meth)acrylate, (B) an alicyclic monomer, and (C) a monomer having at least either a hydroxyl group or a carboxyl group. The average number of carbons of alkyl group in the (A) is 8 or less. The monomeric components comprise the (C) at 3% by weight or greater while the weights Wb and Wc of the (B) and (C) satisfy a relationship 0.8≦Wb/Wc.

Abstract translation: 提供一种用于形成包含（甲基）丙烯酸类聚合物的PSA的粘合剂组合物，其包含作为构成（甲基）丙烯酸类聚合物的单体成分：（A）（甲基）丙烯酸C2-18烷基酯，（B）脂环族单体， 和（C）至少具有羟基或羧基的单体。 （A）中烷基的碳原子数平均数为8以下。 单体组分包含3重量％以上的（C），（B）和（C）的重量Wb和Wc满足0.8≤Wb/ Wc的关系。