公开(公告)号：US20070292703A1

公开(公告)日：2007-12-20

申请号：US10571118

申请日：2003-09-12

申请人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Naoki Wakita

发明人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Naoki Wakita

IPC分类号： C08L101/00 ,  B32B25/08 ,  C08K5/00

CPC分类号： B32B25/08 ,  B29C66/71 ,  B29C66/7212 ,  B29C66/7392 ,  B29C66/7394 ,  C08J5/12 ,  C08K5/0008 ,  C08K5/0025 ,  C08K5/005 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31569 ,  Y10T428/31663 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31826 ,  Y10T428/31833 ,  Y10T428/31855 ,  Y10T428/31931 ,  Y10T428/31935 ,  C08L21/00 ,  B29K2307/04 ,  B29K2077/00 ,  B29K2309/08 ,  B29K2277/10 ,  B29K2069/00 ,  B29K2075/00 ,  B29K2067/00 ,  B29K2063/00 ,  B29K2079/08

摘要： A resin composition comprises a resin, a vulcanization-activating agent, and a stabilizer. The vulcanization-activating agent may be a compound having a plurality of polymerizable unsaturated bonds (e.g., a compound having a plurality of (meth)acryloyl groups). The stabilizer may be an antioxidant, or a light stabilizer (particularly, a stabilizer is capable of capturing a radical). Use of the resin composition as a resin material ensures to directly join between a resin and a rubber certainly and firmly. The proportion of the vulcanization-activating agent may be about 0.1 to 10 parts by weight relative to 100 parts by weight of the resin. The proportion of the stabilizer may be about 0.01 to 5 parts by weight relative to 100 parts by weight of the resin. The present invention provides a resin composition excellent in adhesiveness to a rubber.

摘要翻译： 树脂组合物包含树脂，硫化活化剂和稳定剂。 硫化活化剂可以是具有多个聚合性不饱和键的化合物（例如具有多个（甲基）丙烯酰基的化合物）。 稳定剂可以是抗氧化剂或光稳定剂（特别是稳定剂能够捕获基团）。 树脂组合物作为树脂材料的使用确保了树脂和橡胶之间的直接连接。 相对于100重量份的树脂，硫化活化剂的比例可以为约0.1〜10重量份。 相对于100重量份树脂，稳定剂的比例可以为约0.01至5重量份。 本发明提供了对橡胶的粘合性优异的树脂组合物。

公开(公告)号：US08029910B2

公开(公告)日：2011-10-04

申请号：US12773621

申请日：2010-05-04

申请人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Naoki Wakita

发明人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Naoki Wakita

IPC分类号： B32B27/36 ,  B32B27/40 ,  B32B27/00 ,  B32B27/08

CPC分类号： B32B25/08 ,  B29C66/71 ,  B29C66/7212 ,  B29C66/7392 ,  B29C66/7394 ,  C08J5/12 ,  C08K5/0008 ,  C08K5/0025 ,  C08K5/005 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31569 ,  Y10T428/31663 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31826 ,  Y10T428/31833 ,  Y10T428/31855 ,  Y10T428/31931 ,  Y10T428/31935 ,  C08L21/00 ,  B29K2307/04 ,  B29K2077/00 ,  B29K2309/08 ,  B29K2277/10 ,  B29K2069/00 ,  B29K2075/00 ,  B29K2067/00 ,  B29K2063/00 ,  B29K2079/08

摘要： The present invention is directed to a composite comprising a resin element comprising a resin composition and a vulcanized rubber element formed by vulcanizing an unvulcanized rubber, wherein the resin composition comprises a resin, a vulcanization-activating agent for improving adhesiveness of the resin to a rubber, and a stabilizer, and the resin composition and the vulcanized rubber are directly joined together.

摘要翻译： 本发明涉及一种复合材料，其包括树脂组合物和通过硫化未硫化橡胶形成的硫化橡胶元件的树脂组分，其中树脂组合物包含树脂，用于提高树脂与橡胶的粘合性的硫化活化剂 和稳定剂，并且树脂组合物和硫化橡胶直接接合在一起。

公开(公告)号：US07989540B2

公开(公告)日：2011-08-02

申请号：US10571118

申请日：2003-09-12

申请人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Naoki Wakita

发明人： Toru Ikuta ,  Hajime Komada ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Naoki Wakita

IPC分类号： C09B67/00 ,  C08G75/02 ,  C08G67/02

CPC分类号： B32B25/08 ,  B29C66/71 ,  B29C66/7212 ,  B29C66/7392 ,  B29C66/7394 ,  C08J5/12 ,  C08K5/0008 ,  C08K5/0025 ,  C08K5/005 ,  Y10T428/31507 ,  Y10T428/31511 ,  Y10T428/31533 ,  Y10T428/3154 ,  Y10T428/31551 ,  Y10T428/31569 ,  Y10T428/31663 ,  Y10T428/31721 ,  Y10T428/31725 ,  Y10T428/31786 ,  Y10T428/31826 ,  Y10T428/31833 ,  Y10T428/31855 ,  Y10T428/31931 ,  Y10T428/31935 ,  C08L21/00 ,  B29K2307/04 ,  B29K2077/00 ,  B29K2309/08 ,  B29K2277/10 ,  B29K2069/00 ,  B29K2075/00 ,  B29K2067/00 ,  B29K2063/00 ,  B29K2079/08

摘要： A resin composition comprises a resin, a vulcanization-activating agent, and a stabilizer. The vulcanization-activating agent may be a compound having a plurality of polymerizable unsaturated bonds (e.g., a compound having a plurality of (meth)acryloyl groups). The stabilizer may be an antioxidant, or a light stabilizer (particularly, a stabilizer is capable of capturing a radical). Use of the resin composition as a resin material ensures to directly join between a resin and a rubber certainly and firmly. The proportion of the vulcanization-activating agent may be about 0.1 to 10 parts by weight relative to 100 parts by weight of the resin. The proportion of the stabilizer may be about 0.01 to 5 parts by weight relative to 100 parts by weight of the resin.The present invention provides a resin composition excellent in adhesiveness to a rubber.

摘要翻译： 树脂组合物包含树脂，硫化活化剂和稳定剂。 硫化活化剂可以是具有多个聚合性不饱和键的化合物（例如具有多个（甲基）丙烯酰基的化合物）。 稳定剂可以是抗氧化剂或光稳定剂（特别是稳定剂能够捕获基团）。 树脂组合物作为树脂材料的使用确保了树脂和橡胶之间的直接连接。 相对于100重量份的树脂，硫化活化剂的比例可以为约0.1〜10重量份。 相对于100重量份树脂，稳定剂的比例可以为约0.01至5重量份。 本发明提供了对橡胶的粘合性优异的树脂组合物。

公开(公告)号：US07534494B2

公开(公告)日：2009-05-19

申请号：US10536393

申请日：2003-12-01

申请人： Naoki Wakita ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

发明人： Naoki Wakita ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

IPC分类号： B32B27/34 ,  B32B27/40 ,  B28B5/00

CPC分类号： B32B27/08 ,  B29K2075/00 ,  B29K2077/00 ,  B32B27/34 ,  B32B27/40 ,  Y10T428/31562

摘要： In a molded composite article formed by directly joining a resin member comprising a polyamide-series resin to a resin member comprising a thermoplastic polyurethane-series resin, as the polyamide-series resin, a polyamide-series resin having an amino group of not less than 10 mmol/kg is used. The molded composite article may be produced by heating at least any one of the polyamide-series resin and the thermoplastic polyurethane-series resin to join to the other resin.

摘要翻译： 在通过将包含聚酰胺系树脂的树脂构件直接连接到包含热塑性聚氨酯系树脂的树脂构件而形成的模制复合制品中，作为聚酰胺系树脂，具有不小于 使用10 mmol / kg。 可以通过加热聚酰胺系树脂和热塑性聚氨酯系树脂中的至少任一种来与另一种树脂接合来制造成型复合体。

公开(公告)号：US20060108708A1

公开(公告)日：2006-05-25

申请号：US10536393

申请日：2003-12-01

申请人： Naoki Wakita ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

发明人： Naoki Wakita ,  Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

IPC分类号： B29C65/00

CPC分类号： B32B27/08 ,  B29K2075/00 ,  B29K2077/00 ,  B32B27/34 ,  B32B27/40 ,  Y10T428/31562

摘要： In a molded composite article formed by directly joining a resin member comprising a polyamide-series resin to a resin member comprising a thermoplastic polyurethane-series resin, as the polyamide-series resin, a polyamide-series resin having an amino group of not less than 10 mmol/kg is used. The molded composite article may be produced by heating at least any one of the polyamide-series resin and the thermoplastic polyurethane-series resin to join to the other resin.

公开(公告)号：US20070172670A1

公开(公告)日：2007-07-26

申请号：US11579960

申请日：2005-05-01

申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

IPC分类号： B32B27/00

CPC分类号： C08L77/00 ,  B29C45/0001 ,  B29C45/1657 ,  B29C45/1676 ,  B29C47/0004 ,  B29C47/0021 ,  B29C49/0005 ,  B29C51/002 ,  B29C65/02 ,  B29C66/71 ,  B29C66/712 ,  B29C66/7212 ,  B29C66/73152 ,  B29C66/7392 ,  B29C66/91411 ,  B29K2075/00 ,  B29K2077/00 ,  B29K2101/12 ,  B29K2995/007 ,  C08G2410/00 ,  C08L75/04 ,  C08L2666/20 ,  B29C65/00 ,  B29K2309/08 ,  B29K2067/00

摘要： In a molded composite article formed by directly bonding a resin member comprising a polyamide-series resin to a resin member comprising a thermoplastic polyurethane-series resin, the polyamide-series resin comprises a polyamide block copolymer containing (A) a polyether segment having at least one terminal imino group. The polyamide-series resin may comprise a polyamide-series resin having a free amino group in a concentration of not less than about 10 mmol/kg. The molded composite article is producible, for example, by heating at least one of the polyamide-series resin and the thermoplastic polyurethane-series resin to bond the former to the latter. Thus obtained molded composite article is suitable for a member of a shoe and an industrial roll. In such a process, the polyamide-series resin member and the thermoplastic polyurethane-series resin member both of which are different in nature from each other can be directly and firmly bonded together.

摘要翻译： 在通过将包含聚酰胺系树脂的树脂构件直接结合到包含热塑性聚氨酯系树脂的树脂构件而形成的模制复合制品中，所述聚酰胺系树脂包含聚酰胺嵌段共聚物，所述聚酰胺嵌段共聚物含有（A）至少具有至少 一个终端亚氨基组。 聚酰胺系树脂可以含有游离氨基浓度不低于约10mmol / kg的聚酰胺系树脂。 成型复合制品例如可以通过加热聚酰胺系树脂和热塑性聚氨酯系树脂中的至少一种来将前者粘合到后者。 这样获得的模制复合制品适用于鞋和工业辊的构件。 在这种方法中，两者彼此之间的性质不同的聚酰胺系树脂部件和热塑性聚氨酯系树脂部件可以直接且牢固地结合在一起。

公开(公告)号：US07740943B2

公开(公告)日：2010-06-22

申请号：US11579960

申请日：2005-05-01

申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

IPC分类号： B29C45/14 ,  B32B27/24 ,  B32B27/34 ,  B32B27/40

CPC分类号： C08L77/00 ,  B29C45/0001 ,  B29C45/1657 ,  B29C45/1676 ,  B29C47/0004 ,  B29C47/0021 ,  B29C49/0005 ,  B29C51/002 ,  B29C65/02 ,  B29C66/71 ,  B29C66/712 ,  B29C66/7212 ,  B29C66/73152 ,  B29C66/7392 ,  B29C66/91411 ,  B29K2075/00 ,  B29K2077/00 ,  B29K2101/12 ,  B29K2995/007 ,  C08G2410/00 ,  C08L75/04 ,  C08L2666/20 ,  B29C65/00 ,  B29K2309/08 ,  B29K2067/00

摘要： In a molded composite article formed by directly bonding a resin member comprising a polyamide-series resin to a resin member comprising a thermoplastic polyurethane-series resin, the polyamide-series resin comprises a polyamide block copolymer containing (A) a polyether segment having at least one terminal imino group. The polyamide-series resin may comprise a polyamide-series resin having a free amino group in a concentration of not less than about 10 mmol/kg. The molded composite article is producible, for example, by heating at least one of the polyamide-series resin and the thermoplastic polyurethane-series resin to bond the former to the latter. Thus obtained molded composite article is suitable for a member of a shoe and an industrial roll. In such a process, the polyamide-series resin member and the thermoplastic polyurethane-series resin member both of which are different in nature from each other can be directly and firmly bonded together.

摘要翻译： 在通过将包含聚酰胺系树脂的树脂构件直接结合到包含热塑性聚氨酯系树脂的树脂构件而形成的模制复合制品中，所述聚酰胺系树脂包含聚酰胺嵌段共聚物，所述聚酰胺嵌段共聚物含有（A）至少具有至少 一个终端亚氨基组。 聚酰胺系树脂可以含有游离氨基浓度不低于约10mmol / kg的聚酰胺系树脂。 成型复合制品例如可以通过加热聚酰胺系树脂和热塑性聚氨酯系树脂中的至少一种来将前者粘合到后者。 这样获得的模制复合制品适用于鞋和工业辊的构件。 在这种方法中，两者彼此之间的性质不同的聚酰胺系树脂部件和热塑性聚氨酯系树脂部件可以直接且牢固地结合在一起。

公开(公告)号：US08173262B2

公开(公告)日：2012-05-08

申请号：US10574265

申请日：2004-09-30

申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

IPC分类号： B32B27/34 ,  B32B27/40

CPC分类号： B32B27/40 ,  B32B7/10 ,  B32B27/08 ,  B32B27/16 ,  B32B27/285 ,  B32B27/34 ,  B32B2274/00 ,  B32B2307/536 ,  B32B2307/538 ,  B32B2437/02 ,  C08G2410/00 ,  C08L27/12 ,  C08L29/10 ,  C08L75/04 ,  C09D175/04 ,  Y10T428/2933 ,  Y10T428/31551 ,  Y10T428/31562 ,  C08L2666/04

摘要： In a molded composite article, a resin member comprising a non-urethane thermoplastic resin and a resin member comprising a thermoplastic polyurethane resin are directly joined with each other. The non-urethane thermoplastic resin comprises at least one member selected from the group consisting of a polyamide component having an alicyclic ring and an amino group-containing compound, or each of the non-urethane thermoplastic resins and the thermoplastic polyurethane has a polyether segment. Even if the base resin is a non-urethane thermoplastic resin, the present invention provides a direct and firm bonding between the non-urethane thermoplastic resin member and the thermoplastic polyurethane resin member.

摘要翻译： 在成型复合制品中，包含非聚氨酯热塑性树脂的树脂构件和包含热塑性聚氨酯树脂的树脂构件彼此直接接合。 非聚氨酯热塑性树脂包括选自具有脂环族的聚酰胺成分和含氨基化合物的组中的至少一种，或者各非氨基甲酸乙酯系热塑性树脂和热塑性聚氨酯均具有聚醚链段。 即使基础树脂是非聚氨酯热塑性树脂，本发明也提供了非聚氨酯热塑性树脂构件和热塑性聚氨酯树脂构件之间的直接和牢固的粘结。

公开(公告)号：US20070122615A1

公开(公告)日：2007-05-31

申请号：US10574265

申请日：2004-09-30

申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Hajime Komada ,  Toru Ikuta

IPC分类号： D02G3/00

CPC分类号： B32B27/40 ,  B32B7/10 ,  B32B27/08 ,  B32B27/16 ,  B32B27/285 ,  B32B27/34 ,  B32B2274/00 ,  B32B2307/536 ,  B32B2307/538 ,  B32B2437/02 ,  C08G2410/00 ,  C08L27/12 ,  C08L29/10 ,  C08L75/04 ,  C09D175/04 ,  Y10T428/2933 ,  Y10T428/31551 ,  Y10T428/31562 ,  C08L2666/04

摘要： In a molded composite article, a resin member comprising a non-urethane-series thermoplastic resin and a resin member comprising a thermoplastic polyurethane-series resin are directly joined with each other; and the non-urethane-series thermoplastic resin is a non-urethane-series thermoplastic resin (Ib) or (IIb), and the non-urethane-series thermoplastic resin and the thermoplastic polyurethane-series resin fulfill a following requirement (Ia) or (IIa), (Ia): the non-urethane-series thermoplastic resin (Ib) comprises at least one member selected from the group consisting of a polyamide component having an alicyclic ring, and an amino group-containing compound, or (IIa): each of the non-urethane-series thermoplastic resin (IIb) and the thermoplastic polyurethane-series resin has a polyether segment. The resin composition (Ib) may be a resin composition (Ib-2) containing a non-urethane-series thermoplastic resin and the amino group-containing compound. The molded composite article can be produced by heating at least one selected from the non-urethane-series thermoplastic resin and thermoplastic polyurethane-series resin to join the other. Even if the base resin is a non-urethane-series thermoplastic resin, the present invention achieves a direct and firm bonding between the non-urethane-series thermoplastic resin member and the thermoplastic polyurethane-series resin member which were different in properties from each other by a simple process.

摘要翻译： 在成型复合制品中，包含非氨基甲酸酯类热塑性树脂的树脂构件和包含热塑性聚氨酯系树脂的树脂构件彼此直接接合; 非氨基甲酸酯系热塑性树脂为非氨基甲酸酯系热塑性树脂（Ib）或（IIb），非氨基甲酸酯系热塑性树脂和热塑性聚氨酯系树脂满足以下要求（Ia）或 （IIa），（Ia）：非氨基甲酸酯系热塑性树脂（Ib）包含选自具有脂环式的聚酰胺成分和含氨基化合物的组中的至少一种，或（IIa） ：非聚氨酯系热塑性树脂（IIb）和热塑性聚氨酯系树脂均具有聚醚链段。 树脂组合物（Ib）可以是含有非氨基甲酸酯系热塑性树脂和含氨基化合物的树脂组合物（Ib-2）。 可以通过加热选自非氨基甲酸酯系热塑性树脂和热塑性聚氨酯系树脂中的至少一种来加成成型复合体。 即使基础树脂是非氨基甲酸乙酯系热塑性树脂，本发明也可以实现非氨基甲酸乙酯系热塑性树脂部件与热塑性聚氨酯系树脂部件之间的直接且牢固的结合， 通过一个简单的过程。

公开(公告)号：US10750815B2

公开(公告)日：2020-08-25

申请号：US14000139

申请日：2011-03-11

申请人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Tomohiro Kawahara

发明人： Mitsuteru Mutsuda ,  Hiroaki Arita ,  Tomohiro Kawahara

IPC分类号： A43B13/02 ,  A43B13/04 ,  B32B25/08 ,  B32B27/34 ,  B32B27/40 ,  A43B13/12 ,  A43B13/24 ,  B29D35/14 ,  B29C35/02 ,  C08G69/26 ,  C08L77/06

摘要： A sheet for forming a shoe sole, useful for efficiently joining a crosslinked rubber layer as a stud and a thermoplastic elastomer layer as a sole, is provided.The sheet comprises a resin component (A) containing a polyamide resin (a) and having an amino group concentration of not less than 10 mmol/kg and a flexural modulus of not less than 300 MPa in accordance with ISO178. The polyamide resin (a) may contain a polyamide resin having a melting point of not less than 165° C. at a predetermined concentration (e.g., not less than 30% by weight) in the total polyamide resin (a).