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1.发明授权High resilient flexible urethane foam and flexible molded foams based on allophanate modified isocyanates 失效高弹性弹性聚氨酯泡沫和基于脲基甲酸酯改性异氰酸酯的柔性模塑泡沫公开(公告)号：US06271279B1
公开(公告)日：2001-08-07
申请号：US09613366
申请日：2000-07-10
IPC分类号： C08G1810
CPC分类号： C08G18/6685 , C08G18/4072 , C08G18/7837 , C08G2101/0008 , C08G2101/005 , C08G2101/0083
摘要： This invention relates to a process for the preparation of a flexible foam. This process comprising reacting a liquid, storage stable, allophanate-modified polyisocyanate having an NCO group content of about 20 to about 42%, with an isocyanate-reactive component, in the presence of a blowing agent and at least one catalyst, wherein the relative amounts of the polyisocyanate and the isocyanate-reactive component are such that the NCO index if from about 70 to about 130.
摘要翻译： 本发明涉及柔性泡沫的制备方法。 该方法包括在发泡剂和至少一种催化剂的存在下使具有约20至约42％的NCO基团含量的液体，储存稳定的脲基甲酸酯改性的多异氰酸酯与异氰酸酯反应性组分反应，其中相对 多异氰酸酯和异氰酸酯反应性组分的量使得NCO指数如果为约70至约130。
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2.发明授权Process for preparing closed-cell water-blown rigid polyurethane foams having improved mechanical properties 失效制备具有改进的机械性能的闭孔水喷硬质聚氨酯泡沫体的方法公开(公告)号：US07750058B2
公开(公告)日：2010-07-06
申请号：US12241146
申请日：2008-09-30
IPC分类号： C08G18/28
CPC分类号： C08G18/409 , C08G18/10 , C08G18/4072 , C08G2101/0025 , C08G2101/0058 , C08G2101/0083 , Y10T428/31573 , Y10T428/31583 , Y10T428/31587 , Y10T428/31605 , C08G18/40
摘要： The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention. Foams produced according to the present invention have reduced friability and acceptable adhesion to substrates as well as acceptable compressive strength.
摘要翻译： 本发明涉及一种制备具有至少80％闭孔含量的水喷硬质聚氨酯泡沫体的方法，该方法包括使a）至少一种多元醇混合物，其由（i）至少一种聚合物多元醇组成; （ii）至少一种羟值在约200至约800范围内的多元醇; 和（iii）任选地，至少一种羟值在约25至约115范围内的多元醇; 其中b）至少一种聚合异氰酸酯和/或其预聚物; 在c）任选的情况下，至少一种催化剂; d）水; 和e）任选的至少一种添加剂或助剂。 本发明还涉及通过本发明的方法生产的闭孔水喷硬质聚氨酯泡沫体。 本发明还涉及用于生产本发明的水喷硬质聚氨酯泡沫的聚氨酯泡沫形成混合物。 根据本发明生产的泡沫具有降低的脆性和对基材的可接受的粘合性以及可接受的抗压强度。
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3.发明申请Process for preparing closed-cell water-blown rigid polyurethane foams having improved mechanical properties 失效制备具有改进的机械性能的闭孔水喷硬质聚氨酯泡沫体的方法公开(公告)号：US20090036562A1
公开(公告)日：2009-02-05
申请号：US12241146
申请日：2008-09-30
CPC分类号： C08G18/409 , C08G18/10 , C08G18/4072 , C08G2101/0025 , C08G2101/0058 , C08G2101/0083 , Y10T428/31573 , Y10T428/31583 , Y10T428/31587 , Y10T428/31605 , C08G18/40
摘要： The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention. Foams produced according to the present invention have reduced friability and acceptable adhesion to substrates as well as acceptable compressive strength.
摘要翻译： 本发明涉及一种制备具有至少80％闭孔含量的水喷硬质聚氨酯泡沫体的方法，该方法包括使a）至少一种多元醇混合物，其由（i）至少一种聚合物多元醇组成; （ii）至少一种羟值在约200至约800范围内的多元醇; 和（iii）任选地，至少一种羟值在约25至约115范围内的多元醇; 其中b）至少一种聚合异氰酸酯和/或其预聚物; 在c）任选的情况下，至少一种催化剂; d）水; 和e）任选的至少一种添加剂或助剂。 本发明还涉及通过本发明的方法生产的闭孔水喷硬质聚氨酯泡沫体。 本发明还涉及用于生产本发明的水喷硬质聚氨酯泡沫的聚氨酯泡沫形成混合物。 根据本发明生产的泡沫具有降低的脆性和对基材的可接受的粘合性以及可接受的抗压强度。
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公开(公告)号：US06833390B2
公开(公告)日：2004-12-21
申请号：US10200532
申请日：2002-07-22
IPC分类号： C08G1828
CPC分类号： C08G18/409 , C08G18/10 , C08G18/4072 , C08G2101/0025 , C08G2101/0058 , C08G2101/0083 , Y10T428/31573 , Y10T428/31583 , Y10T428/31587 , Y10T428/31605 , C08G18/40
摘要： The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention. Foams produced according to the present invention have reduced friability and acceptable adhesion to substrates as well as acceptable compressive strength.
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公开(公告)号：US5510445A
公开(公告)日：1996-04-23
申请号：US343402
申请日：1994-11-22
CPC分类号： C08G18/6529 , C08G18/5024 , C08G18/5027 , C08G18/6685 , C08G18/758 , C08G2120/00 , Y10S264/77
摘要： This invention relates to a one-step process for preparing polyurea elastomers comprising reaction at an isocyanate index of from 90 to 200 of(a) one or more aliphatic and/or cycloaliphatic diisocyanates;(b) 25 to 70 equivalent percent, relative to the total of components (b) and (c), of one or more liquid amine-terminated polymers containing at least two aromatically bound isocyanate-reactive primary or secondary amino groups and/or aliphatically bound isocyanate-reactive secondary amino groups and having a molecular weight of from 400 to 6000; and(c) 75 to 30 equivalent percent, relative to the total of components (b) and (c), of one or more aromatic diamine chain extenders having a molecular weight of from 108 to 399, optionally in admixture with one or more crosslinkers.
摘要翻译： 本发明涉及制备聚脲弹性体的一步法，该方法包括（a）一种或多种脂族和/或脂环族二异氰酸酯的异氰酸酯指数为90至200的反应; （b）相对于组分（b）和（c）的总量为25至70当量的一种或多种含有至少两个芳族结合的异氰酸酯反应性伯或仲氨基的液体胺封端的聚合物和/或脂族 结合的异氰酸酯反应性仲氨基并且分子量为400至6000; 和（c）相对于组分（b）和（c）的总量为75至30当量的一种或多种分子量为108至399的芳族二胺增链剂，任选地与一种或多种交联剂 。
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公开(公告)号：US20130023599A1
公开(公告)日：2013-01-24
申请号：US13627127
申请日：2012-09-26
申请人： Yu-Ling Hsiao , Richard G. Skorpenske , Bryan D. Kaushiva , Kenneth G. McDaniel , Jose F. Pazos , Stanley L. Hager , Karl W. Haider
发明人： Yu-Ling Hsiao , Richard G. Skorpenske , Bryan D. Kaushiva , Kenneth G. McDaniel , Jose F. Pazos , Stanley L. Hager , Karl W. Haider
IPC分类号： C07C51/367 , C08G18/68
CPC分类号： C08G18/4891 , C08G18/4866 , C08G2101/0008 , C08G2101/005
摘要： The present invention provides polyurethane foams and elastomers made with an alkoxylated vegetable oil hydroxylate replacing at least a portion of the typically used petroleum-based polyol(s). Also provided are processes for making the inventive foams and elastomers and for making alkoxylated vegetable oil hydroxylates. The alkoxylated vegetable oil hydroxylates are environmentally-friendly, bio-based polyols which advantageously also offer the potential of improved hydrophobicity in polyurethane foams and elastomers. The inventive polyurethane foams and elastomers may find use in a wide variety of products such as automobile interior parts, polyurethane structural foams, floor coatings and athletic running tracks.
摘要翻译： 本发明提供用烷氧基化植物油羟基化物制备的聚氨酯泡沫和弹性体，代替至少一部分通常使用的石油基多元醇。 还提供了制备本发明的泡沫和弹性体以及用于制备烷氧基化植物油羟基化物的方法。 烷氧基化植物油羟基化物是环境友好的基于生物的多元醇，其有利地还提供聚氨酯泡沫和弹性体中改善的疏水性的潜力。 本发明的聚氨酯泡沫和弹性体可以用于各种各样的产品，例如汽车内部部件，聚氨酯结构泡沫，地板涂料和运动跑道。
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7.发明申请公开(公告)号：US20100331517A1
公开(公告)日：2010-12-30
申请号：US12880231
申请日：2010-09-13
IPC分类号： C08G64/02
CPC分类号： C08G64/183 , C08G64/32 , C08G65/2663
摘要： The present invention relates to a polyether carbonate polyol made by copolymerizing a starter molecule with carbon dioxide, at a pressure ranging from about 10 psia to about 2,000 psia, and an alkylene oxide, at a temperature ranging from about 50° C. to about 190° C. and in the presence of from about 0.001 Wt. % to about 0.2 wt. % of a substantially non-crystalline double metal cyanide (DMC) catalyst, wherein the polyol has an incorporated carbon dioxide content of from about 1 wt. % to about 40 wt. %, wherein the ratio of cyclic carbonate by-product to total carbonate is less than about 0.3 and wherein the weight percentages are based on the weight of the polyol. The inventive polyether carbonate polyols may find use in producing polyurethane foams, elastomers, coatings, sealants and adhesives with improved properties.
摘要翻译： 本发明涉及一种聚醚碳酸酯多元醇，其通过将起始分子与二氧化碳在约10psia至约2,000psia的压力和烯化氧的温度范围内共聚而制备，温度为约50℃至约190℃ 在约0.001Wt的存在下。 ％至约0.2wt。 ％的基本上非结晶的双金属氰化物（DMC）催化剂，其中所述多元醇具有约1wt。 ％至约40wt。 ％，其中环状碳酸酯副产物与总碳酸盐的比例小于约0.3，并且其中重量百分比基于多元醇的重量。 本发明的聚醚碳酸酯多元醇可用于生产具有改进性能的聚氨酯泡沫，弹性体，涂料，密封剂和粘合剂。
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8.发明授权公开(公告)号：US06762214B1
公开(公告)日：2004-07-13
申请号：US10391312
申请日：2003-03-18
IPC分类号： C08G1828
CPC分类号： C08G18/482 , C08G18/4018 , C08G18/5024 , C08G65/2627 , C08G65/2648 , C08G2101/0025 , C08G2101/005
摘要： The present invention relates to a process for the preparation of rigid foams comprising reacting a polyisocyanate component with an isocyanate-reactive component in the present of a blowing agent. Suitable isocyanate-reactive components for the presently claimed invention comprises polyether polyols having an OH number of from 200 to 800 and containing from 3 to 8 hydroxyl groups wherein the level of alkalinity present in the polyether polyol is equivalent to a hydroxide ion level of from about 0.006% to about 0.21% by weight.
摘要翻译： 本发明涉及一种用于制备刚性泡沫的方法，包括使多异氰酸酯组分与发泡剂中的异氰酸酯反应性组分反应。 用于本发明要求保护的发明的合适的异氰酸酯反应性组分包含OH数为200至800并包含3至8个羟基的聚醚多元醇，其中存在于聚醚多元醇中的碱度水平等于氢氧根离子水平为约 0.006重量％至约0.21重量％。
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9.发明授权Composition and process for preparation of thermoplastic polyurethanes (TPU based on a polybutadiene soft segment) 失效用于制备热塑性聚氨酯的组合物和方法（基于聚丁二烯软链段的TPU）
公开(公告)号：US06166166A
公开(公告)日：2000-12-26
申请号：US140208
申请日：1998-08-26
申请人： Ronald P. Taylor , Jack C. Chan , Karl W. Haider , E. Haakan Jonsson , Uli W. Franz , Mark A. Peters
发明人： Ronald P. Taylor , Jack C. Chan , Karl W. Haider , E. Haakan Jonsson , Uli W. Franz , Mark A. Peters
CPC分类号： C08G18/6204 , C08G18/0895 , C08G18/10 , C08G18/3206
摘要： A process for making a thermoplastic polyurethane material comprising the steps of casting an NCO-terminated prepolymer with 1,4-butanediol to form a casting composition; extruding the casting composition to form at least one strand of a polyurethane elastomer; pelletizing the at least one strand of said polyurethane elastomer to form at least one pellet; and processing the at least one pellet to form a thermoplastic article.
摘要翻译： 一种制备热塑性聚氨酯材料的方法，包括以下步骤：用1,4-丁二醇浇铸NCO封端的预聚物以形成铸塑组合物; 挤出所述浇铸组合物以形成至少一股聚氨酯弹性体链; 造粒所述聚氨酯弹性体的至少一股，形成至少一个丸粒; 以及处理所述至少一个颗粒以形成热塑性制品。
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公开(公告)号：US20160347900A1
公开(公告)日：2016-12-01
申请号：US15166948
申请日：2016-05-27
申请人： Matthew BECKER , Robert A. Weiss , Zachary Kurtiss Zander , Don S. Wardius , Karl W. Haider , Bruce D. Lawrey
发明人： Matthew BECKER , Robert A. Weiss , Zachary Kurtiss Zander , Don S. Wardius , Karl W. Haider , Bruce D. Lawrey
CPC分类号： C08G18/10 , C08G18/0814 , C08G18/0828 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/603 , C08G18/7671 , C08G18/3206 , C08G18/3857 , C08G18/3855
摘要： In one or more embodiments, the present invention provides a novel approach to the addition of plasticizers for softening TPUs, i.e., lowering the durometer and the melt viscosity. This approach involves incorporating bonded sulfonate groups with quaternary ammonium counterions into the TPU. In one or more embodiments of the present invention, the softening of TPU is achieved by incorporating an ionic diol, such as N,N-bis (2-hydoxyethyl)-2-aminoethane-sulfonic acid (BES), coupled with various bulky alkyl ammonium cations, during the chain extension step of the TPU synthesis. It is believed that that steric hindrance of the bulky quaternary ammonium groups weakens the dipole-dipole interactions of the sulfonate groups and/or lowers the crystallinity of the hard block, thereby creating additional free volume that softens the polymer and lowers the melt viscosity.
摘要翻译： 在一个或多个实施方案中，本发明提供了添加用于软化TPU的增塑剂的新方法，即降低硬度和熔融粘度。 这种方法包括将键合的磺酸盐基团与季铵抗衡离子结合到TPU中。 在本发明的一个或多个实施方案中，TPU的软化通过加入离子二醇，例如N，N-双（2-羟乙基）-2-氨基乙磺酸（BES），与各种大体积烷基 在TPU合成的扩链步骤期间，铵阳离子。 据信大体积季铵基团的空间位阻削弱了磺酸盐基团的偶极 - 偶极相互作用和/或降低了硬块的结晶度，从而产生了使聚合物软化并降低了熔体粘度的额外的自由体积。
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