公开(公告)号：US4659611A

公开(公告)日：1987-04-21

申请号：US706280

申请日：1985-02-27

申请人： Nobuo Iwase ,  Kazuo Anzai ,  Kazuo Shinozaki ,  Akihiko Tsuge ,  Kazutaka Saitoh ,  Kiyoshi Iyogi ,  Noboru Sato ,  Mitsuo Kasori

发明人： Nobuo Iwase ,  Kazuo Anzai ,  Kazuo Shinozaki ,  Akihiko Tsuge ,  Kazutaka Saitoh ,  Kiyoshi Iyogi ,  Noboru Sato ,  Mitsuo Kasori

IPC分类号： C04B41/51 ,  C04B41/52 ,  C04B41/88 ,  C04B41/89 ,  H01L23/15 ,  H01L23/373 ,  H05K1/03 ,  C04B35/52 ,  B32B5/16 ,  B32B15/04 ,  C04B35/58

CPC分类号： C04B41/009 ,  C04B41/5111 ,  C04B41/52 ,  C04B41/88 ,  C04B41/89 ,  H01L23/15 ,  H01L23/3731 ,  C04B2111/00844 ,  H01L2924/0002 ,  H05K1/0306 ,  Y10S428/901 ,  Y10T428/24917 ,  Y10T428/24926

摘要： A high thermal conductivity circuit substrate is provided comprising a sintered aluminum nitride ceramic substrate consisting essentially of one member selected from the group of yttrium, the rare earth metals and the alkali earth metals and an electrically conductive thick film paste for a conductive layer formed on the substrate.

摘要翻译： 提供了一种高导热性电路基板，其包括基本上由选自钇，稀土金属和碱土金属的一种元素组成的烧结氮化铝陶瓷基板，以及形成在导电层上的导电厚膜糊 基质。

公开(公告)号：US4847221A

公开(公告)日：1989-07-11

申请号：US142818

申请日：1988-01-11

申请人： Akihiro Horiguchi ,  Fumio Ueno ,  Mitsuo Kasori ,  Yoshiko Sato ,  Masaru Hayashi ,  Hiroshi Endo ,  Kazuo Shinozaki ,  Akihiko Tsuge

发明人： Akihiro Horiguchi ,  Fumio Ueno ,  Mitsuo Kasori ,  Yoshiko Sato ,  Masaru Hayashi ,  Hiroshi Endo ,  Kazuo Shinozaki ,  Akihiko Tsuge

IPC分类号： C04B35/581

CPC分类号： C04B35/581

摘要： According to the present invention, there is provided an aluminum nitride sintered body having a high thermal conductivity and essentially consisting of a AlN single-phase, containing 0.01 to 8,000 ppm of rare earth elements and less than 2,000 ppm of oxygen. According to the present invention, there is provided a method of fabricating an aluminum nitride sintered body having a high thermal conductivity and essentially consisting of AlN single-phase, containing 0.01 to 8,000 ppm of rare earth elements and less than 2,000 ppm of oxygen, wherein a molded body prepared by mixing and molding an aluminum nitride power having less than 7 wt % of oxygen and an average particle size of 0.05 to 5 .mu.m and with rare earth compounds of 0.01 to 15 wt % of based on rare earth elements content, or a sintered AlN body containing oxide grain boundary phases of 0.01 to 15 wt % of rare earth elements and 0.01 to 20 wt % of oxygen and (rare earth element)--Al--O compounds phases and/or (rare earth element)--O compounds phases, is fired in a reducing atmosphere at a temperature of 1,550 to 2,050.degree. C. for 4 hours or more.

摘要翻译： 根据本发明，提供了一种具有高导热性且基本上由含有0.01至8,000ppm的稀土元素和小于2,000ppm的氧的AlN单相组成的氮化铝烧结体。 根据本发明，提供一种制造具有高导热性且基本由AlN单相组成的氮化铝烧结体的方法，该AlN单相含有0.01至8,000ppm的稀土元素和小于2,000ppm的氧，其中 通过将少于7重量％的氧和平均粒径为0.05〜5μm的氮化铝粉末和基于稀土元素含量为0.01〜15重量％的稀土类化合物混合成型而制备的成型体， 或含有0.01〜15重量％的稀土元素和0.01〜20重量％的氧和（稀土元素）-Al-O化合物相和/或（稀土元素）-Oi的氧化物晶界相的烧结AlN体 化合物相在1550〜2050℃的温度下在还原气氛中烧成4小时以上。

公开(公告)号：US4766097A

公开(公告)日：1988-08-23

申请号：US51237

申请日：1987-05-14

申请人： Kazuo Shinozaki ,  Kazuo Anzai ,  Takeshi Takano ,  Akihiko Tsuge

发明人： Kazuo Shinozaki ,  Kazuo Anzai ,  Takeshi Takano ,  Akihiko Tsuge

IPC分类号： C04B35/581 ,  C04B35/58

CPC分类号： C04B35/581

摘要： An aluminum nitride-based sintered body having a high thermal conductivity and a total oxygen content of 0.01 to 20% by weight which is prepared by mixing a main component of aluminum nitride powder containing 0.001 to 7% by weight of oxygen with 0.01 to 15% by weight of at least one of the group consisting of a powder of a rare earth element and/or a powder of a material containing the rare earth element (said 0.01 to 15% by weight being counted on the basis of the content of the rare earth element), and sintering said powder mixture.

摘要翻译： 通过将含有0.001〜7重量％的氧的氮化铝粉末的主成分与0.01〜15重量％的氧混合而制备的具有高导热性和总氧含量为0.01〜20重量％的氮化铝系烧结体， 的稀土元素粉末和/或含有稀土元素的材料的粉末中的至少一种（0.01〜15重量％，以稀有元素的含量为基准计算） 土元素），并烧结所述粉末混合物。

公开(公告)号：US5001089A

公开(公告)日：1991-03-19

申请号：US402844

申请日：1989-09-06

申请人： Mituo Kasori ,  Kazuo Shinozaki ,  Kazuo Anzai ,  Akihiko Tsuge ,  Hiroshi Imagawa ,  Takeshi Takano ,  Fumio Ueno ,  Akihiro Horiguchi ,  Hiroshi Inoue

发明人： Mituo Kasori ,  Kazuo Shinozaki ,  Kazuo Anzai ,  Akihiko Tsuge ,  Hiroshi Imagawa ,  Takeshi Takano ,  Fumio Ueno ,  Akihiro Horiguchi ,  Hiroshi Inoue

IPC分类号： C04B35/581

CPC分类号： C04B35/581

摘要： There is disclosed an aluminum sintered body prepared by sintering aluminum nitride and additives, which consists essentially of(a) aluminum nitride,(b) at least one compound selected from the group consisting of an aluminum compound of a rare earth metal, an aluminum compound of an alkaline earth metal, and an aluminum compound of a rare earth metal and an alkaline earth metal, and(c) at least one element selected from the transition elements consisting of Groups IVa, Va, VIa, VIIa and VIII of the periodic table, and/or at least one compound comprising the element, and the rare earth element, alkaline earth element and transition element are supplied by the additives.

摘要翻译： 公开了通过烧结氮化铝和添加剂制备的铝烧结体，其主要由（a）氮化铝，（b）至少一种选自由稀土金属的铝化合物，铝化合物 碱土金属的铝化合物和稀土金属和碱土金属的铝化合物，和（c）选自周期表第Ⅳa，Ⅴa，Ⅵa，Ⅶa和Ⅷ族的过渡元素中的至少一种元素 ，和/或至少一种包含元素的化合物，稀土元素，碱土金属元素和过渡元素由添加剂提供。

公开(公告)号：US4883780A

公开(公告)日：1989-11-28

申请号：US157150

申请日：1988-02-11

申请人： Mituo Kasori ,  Kazuo Shinozaki ,  Kazuo Anzai ,  Akihiko Tsuge ,  Hiroshi Imagawa ,  Takeshi Takano ,  Fumio Ueno ,  Akihiro Horiguchi ,  Hiroshi Inoue

发明人： Mituo Kasori ,  Kazuo Shinozaki ,  Kazuo Anzai ,  Akihiko Tsuge ,  Hiroshi Imagawa ,  Takeshi Takano ,  Fumio Ueno ,  Akihiro Horiguchi ,  Hiroshi Inoue

IPC分类号： C04B35/58 ,  C04B35/581

CPC分类号： C04B35/581

摘要： There are disclosed an aluminum sintered body comprising(a) aluminum nitride,(b) at least one compound selected from the group consisting of an aluminum compound of a rare earth metal, an aluminum compound of an alkaline earth metal, and an aluminum compound of a rare earth metal and an alkaline earth metal, and(c) at least one element selected from the transition elements consisting of Groups IVa, Va, VIa, VIIa and VIII of the periodic table, and/or at least one compound containing said element,and a process for preparing the same comprising mixing aluminum nitride with(i) at least one of compound selected from the group consisting of a rare earth metal and/or an alkaline earth metal; and(ii) at least one of element selected from the group consisting of a transition element of Groups IVa, Va, VIa, VIIa and VIII of the periodic table, and/or at least one of a compound containing said element;and then molding and sintering the mixture.

摘要翻译： 公开了一种铝烧结体，其包含（a）氮化铝，（b）至少一种选自稀土金属的铝化合物，碱土金属的铝化合物和铝化合物的化合物 稀土金属和碱土金属，和（c）选自元素周期表第Ⅳa，Ⅴa，Ⅵa，Ⅶa和Ⅷ族的过渡元素中的至少一种元素，和/或含有所述元素的至少一种化合物 和其制备方法包括将氮化铝与（i）选自稀土金属和/或碱土金属的化合物中的至少一种化合物混合; 和（ii）选自元素周期表第Ⅳa，Ⅴa，Ⅵa，Ⅶa和Ⅷ族的过渡元素的元素中的至少一种，和/或含有所述元素的化合物中的至少一种; 然后成型和烧结混合物。

公开(公告)号：US4746637A

公开(公告)日：1988-05-24

申请号：US760772

申请日：1985-07-31

申请人： Mituo Kasori ,  Kazuo Shinozaki ,  Kazuo Anzai ,  Akihiko Tsuge

发明人： Mituo Kasori ,  Kazuo Shinozaki ,  Kazuo Anzai ,  Akihiko Tsuge

IPC分类号： C04B35/581 ,  C04B35/58

CPC分类号： C04B35/581

摘要： Disclosed are an aluminum nitride sintered body comprising aluminum nitride, rare earth element-aluminum compounds and alkaline earth metal-aluminum compounds, and a process for producing an aluminum nitride sintered body, which comprises adding to aluminum nitride powder:(a) powder of at least one compound selected from the group consisting of rare earth element oxides, rare earth element fluorides and compounds capable of being converted into these oxides or fluorides by calcination, and(b) powder of at least one compound selected from the group consisting of alkaline earth metal oxides, alkali earth metal fluorides and compounds capable of being converted into these oxides or fluorides by calcination, in a total amount of 0.01 to 20 wt % as calculated on the weight of the oxides or the fluorides, and then molding and sintering the resultant mixture.

摘要翻译： 公开了一种包含氮化铝，稀土元素 - 铝化合物和碱土金属 - 铝化合物的氮化铝烧结体，以及一种制造氮化铝烧结体的方法，其包括向氮化铝粉末中加入：（a） 选自稀土元素氧化物，稀土元素氟化物和能够通过煅烧转化为这些氧化物或氟化物的化合物中的至少一种化合物，和（b）至少一种选自碱土金属的化合物的粉末 金属氧化物，碱土金属氟化物和能够通过煅烧转化为这些氧化物或氟化物的化合物，其总量按照氧化物或氟化物的重量计算为0.01〜20重量％，然后成型和烧结所得物 混合物。

公开(公告)号：US5112780A

公开(公告)日：1992-05-12

申请号：US521548

申请日：1990-05-10

申请人： Yasuhiro Goto ,  Takeyuki Yonezawa ,  Akihiko Tsuge ,  Michiyasu Komatsu

发明人： Yasuhiro Goto ,  Takeyuki Yonezawa ,  Akihiko Tsuge ,  Michiyasu Komatsu

IPC分类号： C04B35/597 ,  C04B35/80

CPC分类号： C04B35/597 ,  C04B35/806

摘要： A sialon based composite composite essentially consists of 5 wt % to 40 wt % of SiC fibers, 0.3 wt % to 10 wt % of an Hf component which is calculated in terms of Hf oxide, and the balance of sialon as a major constituent. In this case, the sialon is .alpha.-sialon or .beta.-sialon.

公开(公告)号：US4853299A

公开(公告)日：1989-08-01

申请号：US903141

申请日：1986-09-03

申请人： Toshiaki Mizutani ,  Takeyuki Yonezawa ,  Hiroshi Inoue ,  Akihiko Tsuge ,  Yoshiyuki Ohnuma

发明人： Toshiaki Mizutani ,  Takeyuki Yonezawa ,  Hiroshi Inoue ,  Akihiko Tsuge ,  Yoshiyuki Ohnuma

IPC分类号： C04B35/565

CPC分类号： C04B35/565 ,  Y10S264/36

摘要： A silicon carbide sintered body containing not less than 0.03% by weight of boron, a total of not more than 0.3% by weight of metallic element impurities including the boron, not more than 1.0% by weight of free carbon, a total of not more than 0.15% by weight of non-metal impurities other than the free carbon, and the balance essentially consisting of silicon carbide, and having a density of not less 3.10 g/cm.sup.3. The sintered body is manufactured by heating a molding of a mixture containing a silicon carbide powder, a boron-containing sintering assistant, and a carbon-containing oxygen scavenger to a sintering temperature. The molded body is maintained at a temperature lower than the sintering temperature during the heating process until an oxide film covering the silicon carbide powder is substantially removed by the oxygen scavenger, and the molded body is then sintered at the sintering temperature under a non-pressurized condition.

摘要翻译： 含有不少于0.03重量％的硼，总计不超过0.3重量％的包含硼的金属元素杂质，不超过1.0重量％游离碳的碳化硅烧结体，总计不超过 超过0.15重量％的除游离碳以外的非金属杂质，余量基本上由碳化硅组成，密度不小于3.10g / cm 3。 通过将含有碳化硅粉末，含硼烧结助剂和含碳氧清除剂的混合物的成型加热至烧结温度来制造烧结体。 成型体在加热过程中保持在低于烧结温度的温度，直到氧清除剂基本上除去覆盖碳化硅粉末的氧化膜，然后在未加压的烧结温度下将成型体烧结 条件。

公开(公告)号：US4296065A

公开(公告)日：1981-10-20

申请号：US685980

申请日：1976-05-13

申请人： Takashi Ishii ,  Katsutoshi Nishida ,  Michiyasu Komatsu ,  Akihiko Tsuge

发明人： Takashi Ishii ,  Katsutoshi Nishida ,  Michiyasu Komatsu ,  Akihiko Tsuge

IPC分类号： B22F3/14 ,  B22F3/15 ,  C04B35/593 ,  C04B35/597 ,  C04B35/645 ,  C04B35/58

CPC分类号： B22F3/15 ,  C04B35/593 ,  C04B35/597 ,  C04B35/645 ,  C04B35/6455

摘要： A method of producing ceramic articles having a density substantially equal to the theoretical density comprises heating a highly porous preliminary molding made of a ceramic powder to obtain a preliminarily sintered molding of a porosity below 30%, followed by sintering the preliminarily sintered molding under a uniform pressure by the use of a powder acting as a pressure transmitting medium. This method permits producing a ceramic article having a desired shape, and no deformation in it.

摘要翻译： 制造密度基本等于理论密度的陶瓷制品的方法包括加热由陶瓷粉末制成的高度多孔的预成型模具，以获得孔隙率低于30％的预先烧结的模制品，然后在均匀的条件下烧结预先烧结的模制品 通过使用作为压力传递介质的粉末的压力。 该方法允许制造具有所需形状的陶瓷制品，并且其中没有变形。

公开(公告)号：US4264565A

公开(公告)日：1981-04-28

申请号：US121095

申请日：1980-02-13

申请人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge

发明人： Hiroshi Inoue ,  Katsutoshi Komeya ,  Akihiko Tsuge

IPC分类号： C01B21/068 ,  C04B35/584 ,  C01B21/06

CPC分类号： C04B35/584 ,  C01B21/0685 ,  C01P2004/61 ,  C01P2006/80

摘要： A method for producing powder of .alpha.-silicon nitride which comprises the steps of:adding 0.3 to 2 parts by weight of powder of carbon and 0.005 to 1 paret by weight of at least one silicon compound selected from the group consisting of Si.sub.3 N.sub.4, SiC and silicon oxide nitride series compounds to one part by weight (as converted to SiO.sub.2) to a liquid silane derivative which produces a precipitate and HCl by hydrolysis and further causes SiO.sub.2 to be grown by the baking of said precipitate, or the precipitate produced by hydrolysis of the liquid silane derivatives;hydrolyzing the resultant mixture, if necessary;washing the mixture to separate a solid component, if necessary; andbaking the solid component for reduction and nitrogenization at a temperature of 1300.degree. to 1500.degree. C. in an atmosphere mainly consisting of a nitrogen gas or a gas of a nitrogen compound.

摘要翻译： 一种生产α-氮化硅粉末的方法，包括以下步骤：将0.3至2重量份的碳粉和0.005至1重量份的至少一种选自Si 3 N 4，SiC的硅化合物和 氧化硅氮化物系列化合物与1重量份（转化为SiO 2）相对于通过水解产生沉淀物和HCl的液体硅烷衍生物，并且进一步通过焙烧所述沉淀生成SiO 2或通过水解生成的沉淀 液体硅烷衍生物; 如果需要，水解所得混合物; 如果需要，洗涤混合物以分离固体组分; 在1300〜1500℃的温度下，在氮气或氮化合物气体的气氛中焙烧固体成分。