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    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    2.
    发明授权
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N，O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号：US07932303B2

    公开(公告)日：2011-04-26

    申请号：US11898338

    申请日：2007-09-11

    申请人： Norbert Moszner ,  Iris Lamparth ,  Urs Karl Fischer ,  Frank Zeuner ,  Armin de Meijere ,  Volker M. Rheinberger

    发明人： Norbert Moszner ,  Iris Lamparth ,  Urs Karl Fischer ,  Frank Zeuner ,  Armin de Meijere ,  Volker M. Rheinberger

    IPC分类号： A61K6/083 ,  A61K6/08 ,  A61C5/00 ,  C08F2/44 ,  C08F20/58 ,  C08F20/54 ,  C07C233/09 ,  C07C233/16 ,  C07C233/27

    CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C08L33/26 ,  C08L33/14

    摘要： A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    摘要翻译： 材料至少包含式（I）的可聚合的N，O-官能化的丙烯酸羟基酰胺，其中A是n + m价的直链或支链脂族C1至C50基团，其中碳链可以被O ，S，-CO-O-，CO-NH，O-CO-NH或NH-CO-NH，n + m价芳族C6至C18基或n + m价环脂族或杂环C3至C18基 其中基团可以携带一个或多个取代基，Y不存在，或者是O，S，酯，酰胺或氨基甲酸酯基，R 1是氢，可以携带一个的脂族C1至C20烷基或C3至C8环烷基 或更多的取代基，R 2是H或C 1至C 10烷基，R 3不存在或是可被O，HG不存在的C 1至C 16亚烷基，是-COOH，-P = O（OH） 2; -POO（OH）（OR4）; -O-P = O（OH）2，-SO 2 OH或-O-P = O（OH）（OR 4），R 4为C 1至C 15烷基，苯基或苄基，n为1至5的数， ma号从0到3。

    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    6.
    发明申请
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N，O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号：US20080234405A1

    公开(公告)日：2008-09-25

    申请号：US11898338

    申请日：2007-09-11

    申请人： Norbert Moszner ,  Iris Lamparth ,  Urs Karl Fischer ,  Frank Zeuner ,  Armin de Meijere ,  Volker M. Rheinberger

    发明人： Norbert Moszner ,  Iris Lamparth ,  Urs Karl Fischer ,  Frank Zeuner ,  Armin de Meijere ,  Volker M. Rheinberger

    IPC分类号： A61K6/083 ,  C07C233/02 ,  C08F20/58 ,  A61L27/16 ,  A61L27/34 ,  C07F9/08 ,  C07F9/38

    CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C08L33/26 ,  C08L33/14

    摘要： A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    摘要翻译： 材料至少含有式（I）的可聚合的N，O-官能化丙烯酸羟基酰胺，其中A是n + m价的直链或支链脂肪族C 1至C 50 其中碳链可被O，S，-CO-O-，CO-NH，O-CO-NH或NH-CO-NH中断，n + m价芳族C < C 6至C 18或C 14环烷基或杂环C 3〜C 18 - 基团，其中 基团可以携带一个或多个取代基，Y不存在，或者是O，S，酯，酰胺或氨基甲酸酯基，R 1是氢，脂族C 1 C 20 -C 20烷基或C 3至C 8环烷基，其可以携带一个或多个取代基R 2 O / 是H或C 1至C 10烷基，R 3不存在或者是C 1〜 可以被O，HG中断的C 16 -C 16亚烷基，不存在，是-COOH，-PO（OH）2。 -P-O（OH）（OR 4）; -OPO（OH）2，-SO 2 OH或-OPO（OH）（OR 4），R 4， SUP>是C 15 -C 15烷基，苯基或苄基，n是1至5的数和0至3的数。

    DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES
    8.
    发明申请
    DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES 有权

    公开(公告)号：US20140329929A1

    公开(公告)日：2014-11-06

    申请号：US14343297

    申请日：2012-09-10

    申请人： Norbert Moszner ,  Iris Lamparth ,  Thorsten Bock ,  Urs Karl Fischer ,  Ulrich Salz ,  Volker Rheinberger ,  Robert Liska

    发明人： Norbert Moszner ,  Iris Lamparth ,  Thorsten Bock ,  Urs Karl Fischer ,  Ulrich Salz ,  Volker Rheinberger ,  Robert Liska

    IPC分类号： A61K6/083

    CPC分类号： A61K6/0835 ,  A61K6/0002 ,  A61K6/0023 ,  A61K6/083 ,  C07D239/47 ,  C07F3/06 ,  C08F122/22 ,  C08L33/00

    摘要： The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1  Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.

    Dental materials with improved hydrolysis stability based on phthalic acid monomers
    9.
    发明授权
    Dental materials with improved hydrolysis stability based on phthalic acid monomers 有权
    具有改善的基于邻苯二甲酸单体的水解稳定性的牙科材料

    公开(公告)号：US09393181B2

    公开(公告)日：2016-07-19

    申请号：US13630491

    申请日：2012-09-28

    申请人： Thorsten Bock ,  Urs Karl Fischer ,  Iris Lamparth ,  Norbert Moszner ,  Volker Rheinberger

    发明人： Thorsten Bock ,  Urs Karl Fischer ,  Iris Lamparth ,  Norbert Moszner ,  Volker Rheinberger

    IPC分类号： A61K6/00 ,  A61K6/083 ,  C08F2/50

    CPC分类号： A61K6/0023 ,  A61K6/083 ,  C08L33/24

    摘要： Dental material which contains a polymerizable phthalic acid derivative of the general Formula I: with R1=H, methyl or a C1-C5 alkyl residue; R2=H, a phenyl, benzyl or C1-C8 alkyl residue; Q1=is absent or is a C1-C15 alkylene residue, wherein the carbon chain can be interrupted by O or S; Q2=is absent or a (n+1)-valent aliphatic C1-C20 residue, wherein the carbon chain can be interrupted by O or S and wherein Q1 and Q2 cannot be absent simultaneously; X=is absent, is O, S or (—CO—NR4—)—, wherein R4 is H, CH3 or C2H5; Y=is absent, is O, S or (—CO—NR5—)—, wherein R5 is H, CH3 or C2H5; n, m=independently of one another in each case mean 1, 2 or 3; R3=H, CH3, C2H5, Cl, Br or OCH3, and wherein the two carboxyl groups of the benzene ring can together form an anhydride group.

    摘要翻译： 含有通式I的可聚合邻苯二甲酸衍生物的牙科材料：其中R1 = H，甲基或C1-C5烷基残基; R2 = H，苯基，苄基或C1-C8烷基残基; Q1 =不存在或是C1-C15亚烷基残基，其中碳链可被O或S间隔; Q2 =不存在或（n + 1）价的脂族C1-C20残基，其中碳链可以被O或S中断，并且其中Q1和Q2不能同时存在; X =不存在，为O，S或（-CO-NR 4 - ） - ，其中R 4为H，CH 3或C 2 H 5; Y =不存在，是O，S或（-CO-NR 5 - ） - ，其中R 5是H，CH 3或C 2 H 5; 在每种情况下，n，m =彼此独立，意指1,2或3; R3 = H，CH3，C2H5，Cl，Br或OCH3，其中苯环的两个羧基可以一起形成酸酐基团。

    Dental materials with unusual fluorine distribution
    10.
    发明授权
    Dental materials with unusual fluorine distribution 有权
    具有不寻常氟分布的牙科材料

    公开(公告)号：US07595354B2

    公开(公告)日：2009-09-29

    申请号：US11338034

    申请日：2006-01-24

    申请人： Norbert Moszner ,  Urs Karl Fischer ,  Volker M Rheinberger ,  Giancarlo Galli ,  Marina Ragnoli ,  Emo Chiellini

    发明人： Norbert Moszner ,  Urs Karl Fischer ,  Volker M Rheinberger ,  Giancarlo Galli ,  Marina Ragnoli ,  Emo Chiellini

    IPC分类号： A61C5/04 ,  A61K6/083 ,  C08F12/20 ,  C08F232/04

    CPC分类号： A61K6/083 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00 ,  C08L25/00

    摘要： A composition comprising (A) at least one fluorinated vinylcyclopropane according to Formula (I) wherein R1 is H or —CO—O—(CH2CH2)p—R7; R2 is H or forms together with R6 a —CH2—C(R9)(R10)—CH2— residue; R3 is H; R4 is H or forms together with R5—CH2—C(R9)(R10)—CH2— residue; R5 is H, —CO—O—R8, —CO—O—(CH2CH2)p—R7 or forms together with R4—CH2—C(R9)(R10)—CH2— residue; R6 is H, —CO—O—R8, —CO—O—(CH2CH2)p—R7 or forms together with R2 a —CH2—C(R9)(R10)—CH2— residue; R7 is perfluorinated C2-C20 aliphatic or alicyclic group; R8 is H, phenyl, benzyl, or a linear or branched C1-C12 aliphatic or alicyclic group; R9 is a H, benzoyl, acetyl or a C1-C5-alkyl group; R10H or a —CO—O—R8; p is 1, 2, 3, or 4, provided that the compound of Formula (I) comprises at least one —CO—O—(CH2CH2)p—R7 residue; (B) at least one non-fluorinated vinylcyclopropane derivative; (C) a bisphenol-A-ether di(meth)acrylate according to Formula (II) wherein R18 is H or CH3, R19 is CH3 or CF3, Y is a C2-C5-alkylen residue which can be substituted by an OH group or is preferably unsubstituted.

    摘要翻译： 一种组合物，其包含（A）至少一种根据式（I）的氟化乙烯基环丙烷，其中R 1是H或-CO-O-（CH 2 CH 2）p -R 7; R2是H或与R6一起形成-CH 2 -C（R 9）（R 10）-CH 2 - 残基; R3为H; R4是H或与R5-CH2-C（R9）（R10）-CH2-残基一起形成; R5是H，-CO-O-R8，-CO-O-（CH2CH2）p-R7或与R4-CH2-C（R9）（R10）-CH2-残基一起形成; R6是H，-CO-O-R8，-CO-O-（CH2CH2）p-R7或与R2一起形成-CH2-C（R9）（R10）-CH2-残基; R7是全氟化C 2 -C 20脂族或脂环基; R8是H，苯基，苄基或直链或支链C 1 -C 12脂族或脂环基; R9是H，苯甲酰基，乙酰基或C1-C5-烷基; R10H或-CO-O-R8; p为1,2,3或4，条件是式（I）化合物包含至少一个-CO-O-（CH 2 CH 2）p-R 7残基; （B）至少一种非氟化乙烯基环丙烷衍生物; （C）式（II）的双酚A - 醚二（甲基）丙烯酸酯，其中R18为H或CH3，R19为CH3或CF3，Y为可被OH基取代的C2-C5-亚烷基基团 或优选未被取代。