Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    2.
    发明授权
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N,O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号:US07932303B2

    公开(公告)日:2011-04-26

    申请号:US11898338

    申请日:2007-09-11

    摘要: A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    摘要翻译: 材料至少包含式(I)的可聚合的N,O-官能化的丙烯酸羟基酰胺,其中A是n + m价的直链或支链脂族C1至C50基团,其中碳链可以被O ,S,-CO-O-,CO-NH,O-CO-NH或NH-CO-NH,n + m价芳族C6至C18基或n + m价环脂族或杂环C3至C18基 其中基团可以携带一个或多个取代基,Y不存在,或者是O,S,酯,酰胺或氨基甲酸酯基,R 1是氢,可以携带一个的脂族C1至C20烷基或C3至C8环烷基 或更多的取代基,R 2是H或C 1至C 10烷基,R 3不存在或是可被O,HG不存在的C 1至C 16亚烷基,是-COOH,-P = O(OH) 2; -POO(OH)(OR4); -O-P = O(OH)2,-SO 2 OH或-O-P = O(OH)(OR 4),R 4为C 1至C 15烷基,苯基或苄基,n为1至5的数, ma号从0到3。

    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides
    6.
    发明申请
    Materials based on radically polymerizable N,O-functionalized acrylic acid hydroxamides 有权
    基于可自由基聚合的N,O-官能化丙烯酸羟基酰胺的材料

    公开(公告)号:US20080234405A1

    公开(公告)日:2008-09-25

    申请号:US11898338

    申请日:2007-09-11

    摘要: A material contains at least a polymerizable N,O-functionalized acrylic acid hydroxyamide of the Formula (I) in which A is an n+m-valent linear or branched aliphatic C1 to C50 radical, in which the carbon chain can be interrupted by O, S, —CO—O—, CO—NH, O—CO—NH or NH—CO—NH, an n+m-valent aromatic C6 to C18 radical or an n+m-valent cycloaliphatic or heterocyclic C3 to C18 radical, wherein the radicals can carry one or more substituents, Y is not present, or is O, S, an ester, amide or urethane group, R1 is hydrogen, an aliphatic C1 to C20 alkyl or C3 to C8 cycloalkyl radical which can carry one or more substituents, R2 is H or a C1 to C10 alkyl radical, R3 is not present or is a C1 to C16 alkylene radical which can be interrupted by O, HG is not present, is —COOH, —P═O(OH)2; —P═O(OH)(OR4); —O—P═O(OH)2, —SO2OH or —O—P═O(OH)(OR4), R4 is a C1 to C15 alkyl radical, phenyl or benzyl radical and n is a number from 1 to 5 and m a number from 0 to 3.

    摘要翻译: 材料至少含有式(I)的可聚合的N,O-官能化丙烯酸羟基酰胺,其中A是n + m价的直链或支链脂肪族C 1至C 50 其中碳链可被O,S,-CO-O-,CO-NH,O-CO-NH或NH-CO-NH中断,n + m价芳族C < C 6至C 18或C 14环烷基或杂环C 3〜C 18 - 基团,其中 基团可以携带一个或多个取代基,Y不存在,或者是O,S,酯,酰胺或氨基甲酸酯基,R 1是氢,脂族C 1 C 20 -C 20烷基或C 3至C 8环烷基,其可以携带一个或多个取代基R 2 O / 是H或C 1至C 10烷基,R 3不存在或者是C 1〜 可以被O,HG中断的C 16 -C 16亚烷基,不存在,是-COOH,-PO(OH)2。 -P-O(OH)(OR 4); -OPO(OH)2,-SO 2 OH或-OPO(OH)(OR 4),R 4, SUP>是C 15 -C 15烷基,苯基或苄基,n是1至5的数和0至3的数。

    Self-etching dental materials based on (METH) acrylamide phosphates
    7.
    发明授权
    Self-etching dental materials based on (METH) acrylamide phosphates 有权
    基于(METH)丙烯酰胺磷酸盐的自蚀牙科材料

    公开(公告)号:US07622538B2

    公开(公告)日:2009-11-24

    申请号:US11211938

    申请日:2005-08-25

    IPC分类号: C08F20/58 C08F20/60

    摘要: Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-10 aralkyl or a bicylic C4-C12 radial; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p ≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.

    摘要翻译: 可聚合牙科材料,其特征在于其含有至少一种下列通式(I)的(甲基)丙烯酰胺磷酸酯:其中R1是H或CH3; R2是H或C1-C4烷基或与其键合的氮原子一起形成一个或多个属于R3或R3'杂原子的原子; R 3,R 3'彼此独立地为具有m + n或p + n价的直链或支链脂族C 1 -C 50基团,价数为m + n或p + n的芳族C 6 -C 18基团或 脂环族,芳脂族或杂环C 3 -C 18基,其价态为m + n或p + n,其中基团或基团的碳链可被O,S,CONR 4,OCONH中断,或与一个或多个原子一起形成 属于R2和氮原子,R 2与杂环结合,如果p = 0,则R3'为H,R4为H,C1-C10烷基,C6-C12芳基,C6-10芳烷基或双 C4-C12径向; 如果p = 0,则n为1,2,3或4,如果p为0,则为1或2; m为1,2,3或4; p是0,1,2,3或4; x是0或S.

    DENTAL MATERIALS BASED ON MONOMERS HAVING DEBONDING-ON-DEMAND PROPERTIES

    公开(公告)号:US20140329929A1

    公开(公告)日:2014-11-06

    申请号:US14343297

    申请日:2012-09-10

    IPC分类号: A61K6/083

    摘要: The invention relates to a dental restorative material which comprises a thermolabile or photolabile polymerizable compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]1  Formula I, in which T represents a thermolabile or photolabile group, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, wherein at least one Z1 or Z2 is a polymerizable group, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical and k, l, m and n in each case independently are 1, 2 or 3.