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公开(公告)号:US5853681A
公开(公告)日:1998-12-29
申请号:US704639
申请日:1996-09-04
申请人: Patrick John Denny , Peter John Herbert Carnell , Brian Peter Williams , Cathy Anne Woodroffe , Peter Wood
发明人: Patrick John Denny , Peter John Herbert Carnell , Brian Peter Williams , Cathy Anne Woodroffe , Peter Wood
CPC分类号: B01D53/34 , B01D15/00 , B01J20/0237 , B01J20/0277 , B01J20/06 , B01J20/08 , B01J20/3028
摘要: Absorbents, suitable for absorbing sulphur compounds such as hydrogen sulphide from gases and liquids, in the form of shaped units having an average size within the range 1-10 mm and containing at least 75% by weight of an absorbent material comprising copper carbonate, basic copper carbonate, and/or copper hydroxide. The units preferably have a bulk density of at least 0.9 kg/l, especially at least 1.2 kg/l. The units are preferably agglomerates containing a small amount of a binder such as a cement and may also contain a proportion of alumina to catalyse hydrolysis of carbon-containing sulphur compounds such as carbonyl sulphide or carbon disulphide.
摘要翻译: PCT No.PCT / GB95 / 00448 Sec。 371日期1996年9月4日 102(e)日期1996年9月4日PCT 1995年3月2日PCT公布。 公开号WO95 / 24962 日期1995年9月21日适用于从气体和液体中吸收硫化物如硫化氢的吸附剂,其形式为平均尺寸在1-10mm范围内并且含有至少75重量%的吸收材料 包括碳酸铜,碱式碳酸铜和/或氢氧化铜。 单元优选具有至少0.9kg / l,特别是至少1.2kg / l的堆积密度。 这些单元优选是含有少量粘合剂如水泥的附聚物,并且还可以含有一定比例的氧化铝以催化含碳硫化合物如硫化羰或二硫化碳的水解。
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公开(公告)号:US5897845A
公开(公告)日:1999-04-27
申请号:US693202
申请日:1996-10-08
CPC分类号: B01D53/68 , B01J20/041 , B01J20/043 , B01J20/08 , B01J20/28004 , B01J20/28014 , B01J20/2803 , B01J20/28057 , B01J20/3028 , B01J20/3078
摘要: Absorbent granules comprising an intimate mixture of particles of alumina trihydrate, 0.5 to 2 parts by weight of particles of a sodium component selected from the group consisting of sodium carbonate, sodium bicarbonate and mixtures thereof per part by weight of said alumina trihydrate and from 5 to 20% by weight of a binder, said alumina trihydrate, sodium component and binder being present in such proportions that, after ignition of a sample of the granules at 900.degree. C., the sample has a sodium oxide, Na.sub.2 O, content of at least 20% by weight. Processes for manufacturing such absorbent granules and for using such absorbent granules for the removal of acidic gases are also disclosed.
摘要翻译: PCT No.PCT / GB95 / 00303 Sec。 371日期1996年10月8日第 102(e)日期1996年10月8日PCT提交1995年2月14日PCT公布。 WO95 / 22403 PCT出版物 日期1995年8月24日吸收剂颗粒包含三水合氧化铝颗粒的紧密混合物,0.5至2重量份选自碳酸钠,碳酸氢钠的钠组分的颗粒及其混合物,每重量份所述氧化铝 三水合物和5至20重量%的粘合剂,所述三水合氧化铝,钠组分和粘合剂以如下比例存在,使得在900℃下将颗粒样品点燃后,样品具有氧化钠,Na 2 O ,含量至少为20重量%。 还公开了制造这种吸收性颗粒和使用这种吸收性颗粒去除酸性气体的方法。
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公开(公告)号:US07591944B2
公开(公告)日:2009-09-22
申请号:US10502236
申请日:2003-01-17
摘要: A method of making a sulphided ion exchange resin from an ion exchange resin containing primary or secondary amino group comprises passing a non-aqueous liquid, e.g. a hydrocarbon, feedstock containing elemental sulphur or organic, or inorganic, di-or poly-sulphides through a bed of an ion exchange resin containing primary or secondary amino groups, and so unsulphided ion exchange resins containing primary or secondary amine groups may be used to remove such elemental sulphur or sulphur compounds from liquid, e.g. hydrocarbon, feedstocks. The sulphided ion exchange resins may be used to remove elemental mercury or organic mercury compounds from liquid, e.g. hydrocarbon, streams.
摘要翻译: 从含有伯或仲氨基的离子交换树脂制备硫化离子交换树脂的方法包括使非水性液体例如 通过含有伯或仲氨基的离子交换树脂的床,含有元素硫或有机或无机,二 - 或多硫化物的烃类原料,因此可以使用含有伯胺或仲胺基团的未硫化离子交换树脂 从液体中除去这些元素硫或硫化合物,例如 碳氢化合物,原料。 硫化离子交换树脂可用于从液体中除去元素汞或有机汞化合物,例如, 碳氢化合物,溪流。
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公开(公告)号:US08956428B2
公开(公告)日:2015-02-17
申请号:US13003421
申请日:2009-06-15
IPC分类号: C10J3/46 , C01B3/24 , F25J3/00 , C07C27/06 , F25J1/00 , C01B3/38 , C10L3/08 , C10L3/10 , F25J1/02
CPC分类号: F25J1/0022 , C01B3/38 , C01B2203/0233 , C01B2203/0405 , C01B2203/0415 , C01B2203/042 , C01B2203/0445 , C01B2203/0475 , C01B2203/0495 , C01B2203/1052 , C01B2203/1058 , C01B2203/1064 , C01B2203/1247 , C01B2203/1252 , C01B2203/1258 , C01B2203/127 , C01B2203/1288 , C01B2203/1294 , C01B2203/146 , C01B2203/148 , C10L3/08 , C10L3/102 , F25J1/0229 , F25J1/0278 , F25J2210/06 , F25J2220/64
摘要: A process for treating offshore natural gas includes processing the natural gas on an off-shore processing facility by, (i) liquefying and fractionating the natural gas to generate a liquefied natural gas stream and a higher hydrocarbon stream, (ii) vaporizing at least a portion of the higher hydrocarbon stream, (iii) passing the vaporized higher hydrocarbon stream and steam over a steam reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon oxides and hydrogen, (iv) passing the reformed gas mixture over a methanation catalyst to generate a methane rich gas, and (v) combining the methane-rich gas with the natural gas prior to the liquefaction step.
摘要翻译: 一种用于处理海上天然气的方法包括:(i)液化和分馏天然气以产生液化天然气流和较高烃流,在离岸加工设备处理天然气,(ii)将至少一种 较高烃流的一部分,(iii)使蒸发的较高烃流和蒸汽通过蒸汽重整催化剂以产生包含甲烷,蒸汽,碳氧化物和氢的重整气体混合物,(iv)使重整气体混合物通过甲烷化 催化剂以产生富含甲烷的气体,和(v)在液化步骤之前将富含甲烷的气体与天然气组合。
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公开(公告)号:US20100155297A1
公开(公告)日:2010-06-24
申请号:US11993292
申请日:2006-06-07
IPC分类号: C10G25/00
CPC分类号: B01D15/00 , C10G25/003 , C10G67/06
摘要: A process for the removal of one or more nitrogen compounds, e.g. basic nitrogen compound from a fluid stream is described in which the fluid is contacted with a functionalized polymer fibre material having functional groups capable of reacting with the nitrogen compounds.
摘要翻译: 一种除去一种或多种氮化合物的方法,例如, 描述了来自流体物流的碱性氮化合物,其中流体与具有能够与氮化合物反应的官能团的官能化聚合物纤维材料接触。
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公开(公告)号:US07435338B2
公开(公告)日:2008-10-14
申请号:US10575555
申请日:2004-10-29
IPC分类号: C10G29/04
CPC分类号: B01D15/00 , B01J20/02 , B01J20/0225 , B01J20/0229 , B01J20/0237 , B01J20/0244 , B01J20/0277 , B01J20/0285 , B01J20/06 , B01J20/08 , B01J20/20 , B01J20/2803 , B01J20/3204 , B01J20/3236 , B01J2220/42 , B01J2220/56 , C07C7/11 , C07C29/76 , C07C31/202
摘要: The invention is a process for removing mercury compounds from a glycol- or alcohol-containing liquid absorbent stream which contains mercury compounds, especially a glycol stream which has been used in a glycol drying plant for removing water from natural gas streams. The process comprises contacting the mercury-laden liquid absorbent stream with a bed of solid absorbent particles, comprising a sulphided metal, optionally supported on support material, or sulphur supported on carbon.
摘要翻译: 本发明是一种从含乙二醇或醇的液体吸收剂流中除去汞化合物的方法,其中含有汞化合物,特别是已经用于二醇干燥设备中的用于从天然气流中除去水的二醇物流。 该方法包括将含汞的液体吸收剂流与固体吸收剂颗粒床接触,所述固体吸收剂颗粒包含任选负载在载体材料上的硫化金属或负载在碳上的硫。
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公开(公告)号:US6007706A
公开(公告)日:1999-12-28
申请号:US145165
申请日:1998-09-02
摘要: A process for the purification of a fluid stream containing a sulphur contaminant, such as hydrogen sulphide, and mercury, phosphine, stibine, and/or arsenic compounds as a second contaminant wherein said fluid stream is passed through a bed of a particulate absorbent containing a sulphide of a variable valency metal, especially copper, that is more electropositive than mercury, to remove said second contaminant and then the sulphur contaminant is removed from at least part of the effluent from that bed by passing that part of the effluent through a bed of a particulate sulphur absorbent comprising a compound selected from oxides, hydroxides, carbonates and basic carbonates of said variable valency metal is disclosed. The removal of the sulphur contaminant converts said variable valency metal compound to the corresponding sulphide. The resulting bed of variable valency metal sulphide is subsequently used for the removal of the second contaminant.
摘要翻译: 一种用于净化含硫硫化物的流体物流(例如硫化氢)和作为第二污染物的汞,磷化氢,锑和/或砷化合物的流程,其中所述流体流通过含有 通过将该部分流出物通过床的一部分,将来自该床的流出物的至少一部分从至少部分来自该床的流出物中除去所述第二污染物,然后除去硫污染物,其中比汞更具有正电性的可变价金属,特别是铜的硫化物, 公开了一种包含选自所述可变价金属的氧化物,氢氧化物,碳酸盐和碱性碳酸盐的化合物的颗粒状硫吸收剂。 去除硫污染物将所述可变价金属化合物转化为相应的硫化物。 所得到的可变价金属硫化物床随后用于除去第二污染物。
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公开(公告)号:US09017642B2
公开(公告)日:2015-04-28
申请号:US12293175
申请日:2007-03-05
CPC分类号: B01J8/02 , B01J8/04 , B01J8/0457 , B01J2208/00203 , B01J2208/00504 , B01J2219/00006 , B01J2219/00038 , B01J2219/0004 , C01B3/382 , C01B3/48 , C01B2203/0244 , C01B2203/0261 , C01B2203/0283 , C01B2203/1241 , C01B2203/127 , C01B2203/1276 , C01B2203/142
摘要: A process for reducing free oxygen in a hydrocarbon gas stream comprises the steps of (i) forming a gas mixture containing hydrogen from a hydrocarbon, (ii) mixing the hydrogen gas mixture with a gaseous hydrocarbon stream containing free oxygen, and (iii) passing the resulting hydrocarbon gas mixture over a conversion catalyst that converts at least a portion of the free oxygen present in the gaseous hydrocarbon to steam.
摘要翻译: 一种用于减少烃气流中的游离氧的方法包括以下步骤:(i)从烃形成含有氢的气体混合物,(ii)将氢气混合物与含有游离氧的气态烃流混合,和(iii)通过 所得烃混合物在转化催化剂上,将至少一部分气态烃中存在的游离氧转化为蒸汽。
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公开(公告)号:US08574328B2
公开(公告)日:2013-11-05
申请号:US12305699
申请日:2007-05-14
CPC分类号: C01B21/04 , B01D53/8671 , B01D2257/104 , C01B3/36 , C01B3/382 , C01B3/386 , C01B3/48 , C01B21/0422 , C01B2203/0244 , C01B2203/0255 , C01B2203/0283 , C01B2203/04 , C01B2203/0405 , C01B2203/0485 , C01B2203/1023 , C01B2203/1041 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1076 , C01B2203/1082 , C01B2203/1241 , C01B2203/127 , C01B2210/0045 , C02F1/20 , C02F2103/023 , C02F2103/08
摘要: A process for reducing free oxygen in a gaseous nitrogen stream comprises the steps of (i) reforming a hydrocarbon to generate a gas mixture containing hydrogen and carbon oxides, (ii) mixing the gas mixture with a nitrogen stream containing free oxygen, and (iii) passing the resulting nitrogen gas mixture over a conversion catalyst that converts at least a portion of the free oxygen present in the nitrogen to steam wherein the hydrocarbon reforming step includes oxidation of a hydrocarbon using an oxygen-containing gas.
摘要翻译: 一种用于减少气态氮气流中的游离氧的方法包括以下步骤:(i)重整烃以产生含有氢和碳氧化物的气体混合物,(ii)将气体混合物与含有游离氧的氮气流混合,和(iii )将所得氮气混合物通过转化催化剂,所述转化催化剂将存在于氮气中的至少一部分游离氧转化为蒸汽,其中烃重整步骤包括使用含氧气体氧化烃。
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公开(公告)号:US6139605A
公开(公告)日:2000-10-31
申请号:US371292
申请日:1999-08-10
申请人: Peter John Herbert Carnell , Hiren Krishnakant Shethna , Gavin Paul Towler , Edwin Stephen Willis
发明人: Peter John Herbert Carnell , Hiren Krishnakant Shethna , Gavin Paul Towler , Edwin Stephen Willis
IPC分类号: B01D53/14
CPC分类号: B01D53/1425 , B01D53/1456
摘要: A double-loop process for the removal of specified gas or gases from a process gas by absorption with a liquid absorbent for said specified gas or gases wherein the process gas is contacted counter-currently in a first absorption stage with semi-lean absorbent liquid and then in a second absorption stage with lean absorbent liquid to give a sweet process gas and the absorbed gases are stripped from the laden absorbent liquid in a first stage giving a semi-lean absorbent liquid. Part of the semi-lean absorbent is recycled to the first absorption stage while the remainder is subjected to further stripping by counter-current contact with an auxiliary gas that has a concentration of the specified gas or gases that is lower than the concentration of the specified gas or gases in the process gas to give the lean absorbent liquid which is recycled to the second absorption stage. The auxiliary gas, which is especially a part stream of the sweet process gas, may be recycled, after use for stripping, to the process gas upstream of the first absorption stage. The process may be integrated with a glycol drying stage with regeneration of the wet glycol by stripping with the part stream of the sweet process gas before the latter is used for stripping the semi-lean absorbent liquid.
摘要翻译: 一种用于通过用用于所述特定气体或气体的液体吸收剂吸收从工艺气体中除去特定气体或气体的双循环方法,其中工艺气体在第一吸收阶段与半贫吸收液体反向接触, 然后在具有贫吸收液体的第二吸收阶段中产生甜味工艺气体,并且在第一阶段中从吸收液体中吸收吸收的气体,得到半贫吸收液体。 半贫吸收剂的一部分被再循环到第一吸收阶段,而其余部分通过与特定气体或气体的浓度低于规定浓度的辅助气体的逆流接触进行进一步的汽提 气体或气体,以产生再循环到第二吸收级的贫吸收液体。 特别是甜加工气体的一部分流的辅助气体可以在用于汽提之后再循环到第一吸收级上游的工艺气体。 该方法可以与二醇干燥阶段整合,通过用甜味工艺气体的一部分流汽提湿二醇,然后将其用于汽提半贫吸收液体。
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