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1.发明授权F-T process using an iron on mixed zirconia-titania supported catalyst 失效在混合的氧化锆 - 二氧化钛载体催化剂上使用铁的F-T方法
公开(公告)号：US4652587A
公开(公告)日：1987-03-24
申请号：US875803
申请日：1986-06-18
CPC分类号： C07C1/0445 , B01J23/78 , C07C1/044 , B01J37/16 , B01J37/18 , C07C2521/06 , C07C2523/04 , C07C2523/745 , C07C2523/78
摘要： A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.
摘要翻译： 一种费 - 托催化剂，其包含与包含氧化锆和二氧化钛的混合物的颗粒共沉积或沉积的铁，优选通过共转化为可转化为氧化锆的化合物和二氧化钛如锆和钛醇盐形成。 本发明还包括制备该催化剂的方法和利用催化剂的改进的费 - 托反应方法。
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2.发明授权Iron on mixed zirconia-titania substrate Fischer-Tropsch catalyst and method of making same 失效混合氧化锆 - 二氧化钛基材上的铁 - 费 - 托催化剂及其制备方法
公开(公告)号：US4624942A
公开(公告)日：1986-11-25
申请号：US752203
申请日：1985-07-03
CPC分类号： B01J23/78 , C07C1/044 , C07C1/0445 , B01J21/063 , B01J21/066 , C07C2521/06 , C07C2523/04 , C07C2523/745 , C07C2523/78
摘要： A Fischer-Tropsch catalyst comprising iron co-deposited with or deposited on particles comprising a mixture of zirconia and titania, preferably formed by co-precipitation of compounds convertible to zirconia and titania, such as zirconium and titanium alkoxide. The invention also comprises the method of making this catalyst and an improved Fischer-Tropsch reaction process in which the catalyst is utilized.
摘要翻译： 一种费 - 托催化剂，其包含与包含氧化锆和二氧化钛的混合物的颗粒共沉积或沉积的铁，优选通过共转化为可转化为氧化锆的化合物和二氧化钛如锆和钛醇盐形成。 本发明还包括制备该催化剂的方法和利用催化剂的改进的费 - 托反应方法。
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公开(公告)号：US4801751A
公开(公告)日：1989-01-31
申请号：US913826
申请日：1986-09-30
IPC分类号： C07C209/68
CPC分类号： C07C209/68
摘要： Alkylated aromatic primary amines undergo disproportionation and transalkylation in the presence of a carbon-containing catalyst at a temperature between 200.degree. C. and 500.degree. C. The carbon-containing catalyst may have carbon as the only active component, or optionally, may also contain a Group VIIIA metal, such as platimum, palladium, nickel, cobalt or mixtures thereof.
摘要翻译： 烷基化芳族伯胺在含碳催化剂存在下，在200℃至500℃的温度下进行歧化和烷基转移。含碳催化剂可以具有碳作为唯一的活性组分，或任选还可含有 ⅦA族金属，如铂，钯，镍，钴或其混合物。
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公开(公告)号：US5270379A
公开(公告)日：1993-12-14
申请号：US938930
申请日：1992-08-31
IPC分类号： A61K8/81 , A61K47/32 , A61Q5/02 , A61Q5/12 , A61Q19/00 , C08F8/28 , C09D7/00 , C08L29/04 , C08L39/02
CPC分类号： A61Q19/00 , A61K47/32 , A61K8/817 , C08F8/28 , C08F8/44 , C09D7/002 , A61Q5/02 , A61Q5/12 , C08L39/02
摘要： Fluid coating materials such as paints, ink pastes, personal care creams and the like having a water-base are thickened with an associative thickener which is a vinylamine polymer having a weight average molecular weight above 10.sup.5 and which has been modified by reaction with at least 0.2 mer percent of a linear monoaldehyde having 8 to 30 carbon atoms. A hydrolyzed polymer of N-vinylformamide which has been hydrophobically modified with an aldehyde such as dodecaldehyde, exhibits associative thickening characteristics and is useful in thickening water-based formulations.
摘要翻译： 具有水基的涂料，油墨膏，个人护理霜等流体涂料通过缔合增稠剂增稠，该缔合增稠剂是重均分子量大于105的乙烯基胺聚合物，并且至少与 具有8至30个碳原子的直链单醛的0.2个百分比。 已经用醛如十二醛疏水改性的N-乙烯基甲酰胺的水解聚合物显示出缔合的增稠特性，并且可用于增稠水性制剂。
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5.发明授权Separation of solids from aqueous suspensions using modified amine functional polymers 失效使用改性胺官能聚合物从固体悬浮液中分离固体
公开(公告)号：US5185083A
公开(公告)日：1993-02-09
申请号：US803256
申请日：1991-12-05
CPC分类号： G21F9/10 , C02F1/54 , C08F8/12 , C08F8/48 , C08F2800/10
摘要： Polyvinylaminals, optionally as the formed copolymer with polyvinylhemiaminals and polyvinylacetals are useful as separating agents and are provided by reacting a poly(vinylamine) or a copolymer containing vinyl alcohol and vinylamine units with a monoaldehyde. The aldehyde, such as butyraldehyde, can be introduced into the polymer aminalization as a liquid or gas, generally in a proportion of about 0.02 to 0.5 mol per mol of alcohol and amine units in the polymer chain. These polymers, especially as the cationic salt, perform very well in the flocculation, settling, clarification and dewatering of wastewater.
摘要翻译： 聚乙烯基胺，任选地作为与聚乙烯基缩聚物和聚乙烯醇缩甲醛形成的共聚物可用作分离剂，并且通过使聚（乙烯基胺）或含有乙烯醇和乙烯胺单元的共聚物与单醛反应来提供。 醛，如丁醛，可以作为液体或气体引入聚合物中间化，通常在聚合物链中每摩尔醇和胺单元约0.02至0.5摩尔的比例。 这些聚合物，特别是作为阳离子盐，在废水的絮凝，沉降，澄清和脱水方面表现非常好。
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公开(公告)号：US5569725A
公开(公告)日：1996-10-29
申请号：US323210
申请日：1994-10-14
IPC分类号： C08F290/06 , C08G18/48 , C08G18/67 , C08G18/75 , C08F283/04 , C08G71/04
CPC分类号： C08G18/4833 , C08F290/06 , C08G18/6705 , C08G18/755
摘要： A class of unsaturated resins which are suitable for use in radiation curable coatings has been developed. The resins comprise N-vinyl-N-acyl oligomers made by reacting a secondary N-vinylamide with a polyisocyanate monomer which is reacted with at least one mono- or polyhydric alcohol to form a urethane linkage.
摘要翻译： 已经开发了适用于可辐射固化涂料的一类不饱和树脂。 该树脂包括通过使次级N-乙烯基酰胺与多异氰酸酯单体反应制备的N-乙烯基-N-酰基低聚物，其与至少一种一元醇或多元醇反应形成氨基甲酸酯键。
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公开(公告)号：US4906777A
公开(公告)日：1990-03-06
申请号：US260090
申请日：1988-10-19
IPC分类号： C07C231/08
CPC分类号： C07C231/08
摘要： Ethylidene bis-formamide, a precursor for the monomer N-vinylformamide, is made in high yield by heating together formamide and acetaldehyde in a mol ratio of at least 3:1 and in a reaction mixture which is at least 20 weight percent formic acid. In a preferred procedure the acetaldehyde is added after the formamide has been preheated and formic acid is present. Yields of ethylidene bis-formamide of over 50%, based on the acetaldehyde, are obtained in relatively short reaction times, before loss of substantial amounts of recoverable formamide through hydrolysis.
摘要翻译： 亚乙基双甲酰胺是单体N-乙烯基甲酰胺的前体，通过以至少3:1的摩尔比和在至少20重量％甲酸的反应混合物中加热甲酰胺和乙醛一起高产率地制备。 在优选的方法中，在甲酰胺已被预热并存在甲酸之后加入乙醛。 在相对较短的反应时间内，在通过水解失去大量可回收的甲酰胺之前，以乙醛为基础，获得超过50％的亚乙基双甲酰胺的产率。
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公开(公告)号：US5324787A
公开(公告)日：1994-06-28
申请号：US977973
申请日：1992-11-18
IPC分类号： C08F8/00 , C08F26/00 , C08F126/02 , C08F226/02
CPC分类号： C08F8/00
摘要： Poly(vinylamine) homopolymers and copolymers are hydrophobically modified by reaction of amine units present in the polymer with a saturated aliphatic or aromatic glycidyl ether compound. The resulting polymers are useful as flocculants in separating water from suspended solids and are especially effective in improving fines retention in papermaking. Poly(vinylamine hydrochloride) modified in this manner with butyl glycidyl ether is shown to be very efficient in retaining the paper product fines present in recycle paper pulps.
摘要翻译： 通过聚合物中存在的胺单元与饱和脂族或芳族缩水甘油醚化合物的反应，聚（乙烯基胺）均聚物和共聚物被疏水改性。 所得聚合物可用作从悬浮固体中分离水中的絮凝剂，并且特别有效地改善造纸中的细粉保留。 以这种方式用丁基缩水甘油醚改性的聚（乙烯胺盐酸盐）显示出非常有效地保留存在于回收纸浆中的纸制品细粉。
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公开(公告)号：US5232553A
公开(公告)日：1993-08-03
申请号：US826330
申请日：1992-01-24
摘要： Polyvinylaminals, optionally as the formed copolymer with polyvinyl hemiaminals, and polyvinyl acetals are added to a papermaking pulp slurry to improve the retention of fines in the final paper product. This polymer is provided by reacting a poly(vinylamine) which can be a homopolymer or a copolymer containing vinyl alcohol and vinyl amine units with a monoaldehyde. The aldehyde, such as butyraldehyde, modifies the structure of the polymer and increases its hydrophobicity. The use of these polymers in papermaking involving the recycle of waste papers provides notable advantages in fines retention because of the high level of fines which normally accompany such recycle paper waste.
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公开(公告)号：US4935545A
公开(公告)日：1990-06-19
申请号：US231751
申请日：1988-08-12
IPC分类号： C07C209/68
CPC分类号： C07C209/68
摘要： Alkylated aromatic primary amines undergo disproportionation and transalkylation in the presence of a catalyst comprising activated carbon or unmodified graphite and a Group VIIIA metal at a temperature between 200.degree. C. and 500.degree. C. Suitable Group VIIIA metals are selected from the group consisting of platinum, palladium, nickel, cobalt or mixtures thereof.
摘要翻译： 烷基化芳族伯胺在200℃至500℃之间的温度下，在包含活性炭或未改性石墨和ⅦA族金属的催化剂存在下，进行歧化和烷基转移。合适的Ⅷ族金属选自铂 ，钯，镍，钴或其混合物。
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