Process for the disproportionation of alkylated aromatic primary amines
    3.
    发明授权
    Process for the disproportionation of alkylated aromatic primary amines 失效
    烷基化芳族伯胺歧化的方法

    公开(公告)号:US4801751A

    公开(公告)日:1989-01-31

    申请号:US913826

    申请日:1986-09-30

    IPC分类号: C07C209/68

    CPC分类号: C07C209/68

    摘要: Alkylated aromatic primary amines undergo disproportionation and transalkylation in the presence of a carbon-containing catalyst at a temperature between 200.degree. C. and 500.degree. C. The carbon-containing catalyst may have carbon as the only active component, or optionally, may also contain a Group VIIIA metal, such as platimum, palladium, nickel, cobalt or mixtures thereof.

    摘要翻译: 烷基化芳族伯胺在含碳催化剂存在下,在200℃至500℃的温度下进行歧化和烷基转移。含碳催化剂可以具有碳作为唯一的活性组分,或任选还可含有 ⅦA族金属,如铂,钯,镍,钴或其混合物。

    Fischer-Tropsch process
    4.
    发明授权
    Fischer-Tropsch process 失效
    费 - 托法

    公开(公告)号:US4670472A

    公开(公告)日:1987-06-02

    申请号:US862744

    申请日:1986-05-13

    摘要: A Fischer-Tropsch process utilizing a product selective and stable catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

    摘要翻译: 公开了一种利用产物选择性和稳定催化剂的费 - 托方法,其中合成气,特别是一氧化碳浓度合成气选择性地转化为相对较窄碳数范围的较高级烃。 通常,选择性和显着稳定的催化剂由首先用ⅣB族金属化合物(例如锆或钛),优选醇盐化合物处理的惰性载体组成,随后用费 - 托金属的有机化合物 催化剂,如钴,铁或羰基钌。 在催化剂制备过程中特别避免了与空气和水的反应和煅烧。

    Supported fischer-tropsch catalyst and method of making the catalyst
    5.
    发明授权
    Supported fischer-tropsch catalyst and method of making the catalyst 失效
    支持的费 - 托催化剂和催化剂的制备方法

    公开(公告)号:US4681867A

    公开(公告)日:1987-07-21

    申请号:US862844

    申请日:1986-05-13

    摘要: A Fischer-Tropsch catalyst and a method of making the catalyst for a Fischer-Tropsch process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas, is selectively converted to higher hydrocarbons of relatively narrow carbon number range is disclosed. In general, the selective and notably stable catalyst, consist of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of a Fischer-Tropsch metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

    摘要翻译: 公开了一种费 - 托催化剂和利用催化剂制备用于费 - 托催化剂的催化剂的方法,通过该催化剂合成气,特别是一氧化碳浓度的合成气被选择性地转化为相对较窄的碳数范围的高级烃。 通常,选择性和显着稳定的催化剂由首先用ⅣB族金属化合物(例如锆或钛),优选醇盐化合物处理的惰性载体组成,随后用费 - 托金属的有机化合物 催化剂,如钴,铁或羰基钌。 在催化剂制备过程中特别避免了与空气和水的反应和煅烧。

    Catalyst for selective conversion of synthesis gas and method of making
the catalyst
    6.
    发明授权
    Catalyst for selective conversion of synthesis gas and method of making the catalyst 失效
    用于选择性转化合成气的催化剂和制备催化剂的方法

    公开(公告)号:US4619910A

    公开(公告)日:1986-10-28

    申请号:US741403

    申请日:1985-06-05

    摘要: A Fischer-Tropsch (F-T) catalyst, a method of making the catalyst and an F-T process utilizing the catalyst by which synthesis gas, particularly carbon-monoxide rich synthesis gas is selectively converted to higher hydrocarbons of relatively narrow carbon number range. In general, the selective and notably stable catalyst, consists of an inert carrier first treated with a Group IV B metal compound (such as zirconium or titanium), preferably an alkoxide compound, and subsequently treated with an organic compound of an F-T metal catalyst, such as cobalt, iron or ruthenium carbonyl. Reactions with air and water and calcination are specifically avoided in the catalyst preparation procedure.

    摘要翻译: 费 - 托(F-T)催化剂,制备催化剂的方法和利用催化剂的F-T方法,其中合成气,特别是一氧化碳浓度合成气选择性地转化为碳数范围相对较窄的高级烃。 通常,选择性和特别稳定的催化剂由首先用ⅣB族金属化合物(例如锆或钛),优选醇盐化合物处理的惰性载体组成,随后用FT金属催化剂的有机化合物处理, 例如钴,铁或羰基钌。 在催化剂制备过程中特别避免了与空气和水的反应和煅烧。