-
公开(公告)号:US20070244279A1
公开(公告)日:2007-10-18
申请号:US11628166
申请日:2005-06-20
申请人: Peijun Jiang , John Shutt , Charles Speed , Randall Laird , Kevin Stavens , Robert Hagerty
发明人: Peijun Jiang , John Shutt , Charles Speed , Randall Laird , Kevin Stavens , Robert Hagerty
CPC分类号: C08F210/16 , C08F2/002 , C08F2/06 , C08F210/06 , C08F2500/03 , C08F2500/20
摘要: This invention relates to a process to increase the amount of polymer solute in a polymerization medium or effluent comprising introducing a fluorocarbon into the polymerization medium or effluent in an amount effective to increase the amount of polymer solute in the polymerization medium or effluent by at least 3% without causing precipitation of polymer solute from the polymerization medium or effluent, as compared to the same polymerization medium or effluent without the fluorocarbon present. This invention also relates to a process to reduce the viscosity of a polymerization medium or effluent comprising introducing a fluorocarbon into the polymerization medium or effluent in an amount effective to reduce the viscosity of the polymerization medium or effluent by at least 3% without causing precipitation of polymer solute from the polymerization medium or effluent, as compared to the same polymerization medium or effluent without the fluorocarbon present.
摘要翻译: 本发明涉及一种增加聚合介质或流出物中聚合物溶质量的方法,包括将碳氟化合物引入聚合介质或流出物中,其量有效地将聚合介质或流出物中聚合物溶质的量增加至少3 %,而不会导致聚合物溶质从聚合介质或流出物中沉淀,与不存在碳氟化合物的相同聚合介质或流出物相比。 本发明还涉及降低聚合介质或流出物的粘度的方法,包括将碳氟化合物引入聚合介质或流出物中,其量可有效地降低聚合介质或流出物的粘度至少3%而不引起沉淀 与不存在碳氟化合物的相同聚合介质或流出物相比,来自聚合介质或流出物的聚合物溶质。
-
公开(公告)号:US20070199218A1
公开(公告)日:2007-08-30
申请号:US10561340
申请日:2004-06-17
申请人: Peijun Jiang , John Shutt , Charles Speed , Robert Hagerty , Pradeep Shirodkar
发明人: Peijun Jiang , John Shutt , Charles Speed , Robert Hagerty , Pradeep Shirodkar
IPC分类号: G09F13/18
CPC分类号: G02B6/0033 , G09F13/18 , G09F19/12
摘要: An illuminable sign (1) including a plate (2) of a light-transmitting material, at least one three-dimensional body, such as a convex strip (7), also of a light-transmitting material, in the form of a symbol, lettering, decoration or the like, and positioned on or over a surface of the plate (2), and a light source (4). The light source (4) is positioned along at least part of an edge (3) of the plate (2), such that, when the light source (4) is switched on, light from the source (4) is coupled into the plate (2). The illuminable sign (1) closely resembles a neon sign.
摘要翻译: 一种包括透光材料的板(2)的可照亮标志(1),至少一个三维体,例如凸条(7),也是透光材料,其形式为符号 ,刻字,装饰等,并且位于板(2)的表面上或上方,以及光源(4)。 光源(4)沿着板(2)的边缘(3)的至少一部分定位,使得当光源(4)接通时,来自源(4)的光被耦合到 板(2)。 可照亮的标志(1)非常类似于霓虹灯。
-
公开(公告)号:US20070197753A1
公开(公告)日:2007-08-23
申请号:US11628182
申请日:2005-06-20
申请人: Peijun Jiang , John Shutt , Charles Speed , Robert Hagerty , Pradeep Shirodkar
发明人: Peijun Jiang , John Shutt , Charles Speed , Robert Hagerty , Pradeep Shirodkar
IPC分类号: C08F10/14
CPC分类号: C08F10/00 , C08F4/6592 , C08F4/65927 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2/06 , C08F4/65912 , C08F4/6493 , C08F2/14 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要: This invention relates to a process to polymerize olefins comprising contacting a catalyst or catalyst system with olefin(s) in the presence of a fluorocarbon at a temperature above the onset melting point of the polymer. This invention also relates to a solution process to polymerize olefins comprising contacting a catalyst or catalyst system with olefin(s) in the presence of a fluorocarbon at a temperature above the onset melting point of the polymer.
摘要翻译: 本发明涉及聚合烯烃的方法,包括在高于聚合物起始熔点的温度下,在碳氟化合物的存在下使催化剂或催化剂体系与烯烃接触。 本发明还涉及使烯烃聚合的溶液方法,其包括在高于聚合物起始熔点的温度下在碳氟化合物的存在下使催化剂或催化剂体系与烯烃接触。
-
公开(公告)号:US20080033127A1
公开(公告)日:2008-02-07
申请号:US11628165
申请日:2005-06-20
申请人: Peijun Jiang , John Shutt , Charles Speed , Robert Hagerty , Pradeep Shirodkar
发明人: Peijun Jiang , John Shutt , Charles Speed , Robert Hagerty , Pradeep Shirodkar
CPC分类号: C08F10/00 , C08F4/65908 , C08F4/65912 , C08F10/06 , C08F210/06 , C08F2/14 , C08F4/65927 , C08F2/06 , C08F210/16 , C08F2500/03 , C08F2500/20 , C08F2500/12
摘要: This invention relates to a multiple phase polymerization process to produce polyolefins comprising contacting olefins and a homogeneous catalyst or catalyst system at a temperature between the melting point of the dry polymer and 80° C. below the melting point of the dry polymer in the presence of a fluorinated hydrocarbon. This invention also relates to a process to produce polyethylene comprising contacting a homogeneous catalyst or catalyst system with ethylene and from 0 to 40 weight % of one or more C3 to C40 olefin comonomer(s) in the presence of a fluorinated hydrocarbon and optionally a hydrocarbon solvent at a temperature below the reaction medium melting point. This invention also relates to a process to produce polypropylene comprising contacting a homogeneous catalyst or catalyst system with propylene and from 0 to 50 weight % of one or more of ethylene and C4 to C40 olefin comonomer(s) in the presence of a fluorinated hydrocarbon and optionally a hydrocarbon solvent at a temperature below the reaction medium melting point.
摘要翻译: 本发明涉及生产聚烯烃的多相聚合方法,包括使烯烃和均相催化剂或催化剂体系在干聚合物的熔点和低于干聚合物熔点的80℃之间的温度下,在存在 氟化烃。 本发明还涉及一种生产聚乙烯的方法,其包括使均相催化剂或催化剂体系与乙烯和0至40重量%的一种或多种C 3至C 40烯烃共聚单体在氟化烃和任选的烃 溶剂在低于反应介质熔点的温度下进行。 本发明还涉及生产聚丙烯的方法,包括在氟化烃存在下使均相催化剂或催化剂体系与丙烯和0至50重量%的一种或多种乙烯和C 4至C 40烯烃共聚单体接触, 任选的烃溶剂在低于反应介质熔点的温度下。
-
公开(公告)号:US20070208146A1
公开(公告)日:2007-09-06
申请号:US11629368
申请日:2005-06-20
申请人: Robert Hagerty , Chia Chee , Randall Laird , Michael Risch , Pradeep Shirodkar , Peijun Jiang
发明人: Robert Hagerty , Chia Chee , Randall Laird , Michael Risch , Pradeep Shirodkar , Peijun Jiang
IPC分类号: C08F2/00
CPC分类号: C08F10/06 , C08F210/06 , C08F2/06 , C08F2/005 , C08F4/6493 , C08F2/14 , C08F4/6543 , C08F210/16 , C08F2500/12 , C08F2500/20 , C08F2500/15 , C08F2500/03 , C08F2500/26
摘要: This invention is directed to processes of making polymer in the presence of a fluorinated hydrocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and allows for the recovery of the fluorinated hydrocarbon and other hydrocarbons such as hydrocarbons for reuse in the process or hydrocarbon by-products from the polymerization process. The invention is particularly beneficial in the production of propylene based polymers using Ziegler Natta catalyst systems.
摘要翻译: 本发明涉及在氟化烃存在下制备聚合物并回收聚合物的方法。 所提供的方法使聚合方法能够在反应体系中以最小的结垢进行聚合,并允许回收氟化烃和其它烃类,例如在该方法中重新使用的烃或来自聚合方法的烃副产物。 本发明特别有益于使用齐格勒纳塔催化剂体系生产基于丙烯的聚合物。
-
公开(公告)号:US20070255017A1
公开(公告)日:2007-11-01
申请号:US11629369
申请日:2005-06-20
CPC分类号: C08F10/06 , C08F210/06 , C08F210/16 , Y10S526/912 , C08F2/06 , C08F2/00 , C08F2/14 , C08F2500/04 , C08F2500/20
摘要: This invention is directed to processes of making polymer in, the presence of a fluorinated hydrocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and allows for the recovery of the fluorinated hydrocarbon and other hydrocarbons such as hydrocarbons for re-use in the process or hydrocarbon by-products from the polymerization process. The invention is particularly beneficial in the production of propylene-ethylene based copolymers using Ziegler-Natta catalyst systems.
摘要翻译: 本发明涉及使聚合物在氟化烃存在下回收聚合物的方法。 所提供的方法使得聚合方法能够在反应体系中以最小的结垢进行聚合,并允许回收氟化烃和其它烃,例如在该方法中重复使用的烃或聚合方法中的烃副产物。 本发明特别有利于使用齐格勒 - 纳塔催化剂体系生产丙烯 - 乙烯基共聚物。
-
公开(公告)号:US20070225455A1
公开(公告)日:2007-09-27
申请号:US11628183
申请日:2005-06-20
申请人: Peijun Jiang , John Shutt , Charles Speed , Pradeep Shirodkar , Hagerty Olds , Larry Iaccino
发明人: Peijun Jiang , John Shutt , Charles Speed , Pradeep Shirodkar , Hagerty Olds , Larry Iaccino
IPC分类号: C08F2/00
CPC分类号: C08F10/06 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F210/06 , C08F4/651 , C08F4/654 , C08F2/14 , C08F2/01 , C08F2/06 , C08F2/001 , C08F2500/20 , C08F210/16
摘要: This invention relates to a continuous process to prepare olefin impact copolymers comprising producing a semi-crystalline olefin polymer in a first reactor and then transferring the reactor contents to a second reactor where a low crystallinity olefin polymer is produced in the presence of the semi-crystalline polymer, where a fluorinated hydrocarbon is present in the polymerization medium of the first reactor, the second reactor or both reactors.
摘要翻译: 本发明涉及制备烯烃抗冲共聚物的连续方法,其包括在第一反应器中制备半结晶烯烃聚合物,然后将反应器内容物转移到第二反应器中,在第二反应器中,在半结晶存在下制备低结晶度烯烃聚合物 聚合物,其中氟化烃存在于第一反应器,第二反应器或两个反应器的聚合介质中。
-
公开(公告)号:US20080033124A1
公开(公告)日:2008-02-07
申请号:US11628875
申请日:2005-06-20
申请人: Peijun Jiang , Charles Speed
发明人: Peijun Jiang , Charles Speed
CPC分类号: C08F210/06 , C08F4/659 , C08F2/14 , C08F2/06 , C08F210/16 , C08F2500/03 , C08F2500/20 , C08F4/64144
摘要: This invention relates to processes for preparing polyolefins in the presence of a perfluorocarbon or hydrofluorocarbon with an activated, nonmetallocene, metal-centered, heteroaryl ligand catalyst.
摘要翻译: 本发明涉及在全氟化碳或氢氟烃与活化的非金属茂金属中心的杂芳基配体催化剂的存在下制备聚烯烃的方法。
-
公开(公告)号:US20130158307A1
公开(公告)日:2013-06-20
申请号:US13476686
申请日:2012-05-21
CPC分类号: C07C11/02 , C07C2/02 , C07C2/34 , C07C5/05 , C08F4/65908 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/14 , C08F110/14 , C08F210/04 , C08F210/14 , C10M107/10 , C10M143/08 , C10M2205/026 , C10M2205/0265 , C10M2205/028 , C10M2205/0285 , C10N2220/021 , C10N2220/022 , C10N2220/023 , C10N2220/024 , C10N2220/025 , C10N2220/026 , C10N2220/028 , C10N2220/033 , C10N2270/00 , C08F2500/03 , C08F2500/17 , C08F2500/20 , C08F2500/02
摘要: A low viscosity poly(apha-olefin) (PAO) is produced by contacting one or more C3 to C24 alpha-olefins with an unbridged, substituted bis cyclopentadienyl transition metal compound, a non-coordinating anion activator, and an alkyl-aluminum compound. The molar ratio of transition metal compound to activator is 10:1 to 0.1:1, and the molar ratio of alkyl aluminum compound to transition metal compound is 1:4 to 4000:1. The transition metal compound has either (a) at least one non-isoolefin substitution on both cyclopentadienyl rings, or (b) at least two substitutions on at least one cyclopentadienyl ring. The PAO is comprised of at least 50 mole % of C3 to C24 alpha-olefins and has a kinematic viscosity at 100° C. of 20 cSt or less.
摘要翻译: 通过使一个或多个C 3至C 24α-烯烃与未桥连的取代的双环戊二烯基过渡金属化合物,非配位阴离子活化剂和烷基铝化合物接触来制备低粘度聚(对苯二甲酸烯丙酯)(PAO)。 过渡金属化合物与活化剂的摩尔比为10:1至0.1:1,烷基铝化合物与过渡金属化合物的摩尔比为1:4至4000:1。 过渡金属化合物具有(a)在两个环戊二烯基环上至少一个非异构烯烃取代,或(b)至少一个环戊二烯基环上的至少两个取代基。 PAO由至少50摩尔%的C3至C24α-烯烃组成,并且在100℃下的运动粘度为20cSt或更低。
-
公开(公告)号:US08242198B2
公开(公告)日:2012-08-14
申请号:US12616637
申请日:2009-11-11
申请人: Peijun Jiang , George Rodriguez , Fran A. Shipley , Aspy K. Mehta
发明人: Peijun Jiang , George Rodriguez , Fran A. Shipley , Aspy K. Mehta
IPC分类号: D21H19/18
CPC分类号: C09J5/06 , C08L23/02 , C08L23/06 , C08L51/003 , C08L51/06 , C08L91/06 , C08L2666/02 , C09J123/142
摘要: An adhesive and method for hot melt application. The adhesive comprises polyolefin base polymer, from 1 to 10 wt % of at least one functionalized polyolefin, and from 1 to 15 wt % of a wax, based on the total weight of the polyolefin base polymer, functionalized polyolefin and wax, wherein the wax has a weight average molecular weight at least 8% of the weight average molecular weight of the polyolefin base polymer, viscosity at 190° C. of 60 mPa·s or more, and a crystallization temperature greater than the polyolefin base polymer and greater than 100° C., and wherein the adhesive has at least 5% fiber tear at 2° C., at least 50% fiber tear at 25° C., and a characteristic set time of less than 3 seconds.
摘要翻译: 一种用于热熔胶应用的粘合剂和方法。 基于聚烯烃基础聚合物,官能化聚烯烃和蜡的总重量,粘合剂包括聚烯烃基聚合物,1至10重量%的至少一种官能化聚烯烃和1至15重量%的蜡,其中蜡 重均分子量为聚烯烃基聚合物的重均分子量的至少8%,190℃下的粘度为60mPa·s以上,结晶温度大于聚烯烃基聚合物,大于100 ℃,并且其中粘合剂在2℃下具有至少5%的纤维撕裂,在25℃下至少50%的纤维撕裂,以及小于3秒的特征设定时间。
-
-
-
-
-
-
-
-
-