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    Method of hydroisomerizing paraffins emanating from the Fischer-Tropsch process using catalysts based on H-Y zeolite
    1.
    发明授权
    Method of hydroisomerizing paraffins emanating from the Fischer-Tropsch process using catalysts based on H-Y zeolite 失效
    使用基于H-Y沸石的催化剂从费 - 托方法发出的烷烃加氢异构化方法

    公开(公告)号：US5306860A

    公开(公告)日：1994-04-26

    申请号：US886224

    申请日：1992-05-21

    申请人： Pierre-Henri Bigeard ,  Alain Billon ,  Pierre Dufresne ,  Samuel Mignard

    发明人： Pierre-Henri Bigeard ,  Alain Billon ,  Pierre Dufresne ,  Samuel Mignard

    IPC分类号： C10G65/04 ,  C07C5/13 ,  C07C5/22

    CPC分类号： C10G65/043 ,  Y10S208/95 ,  Y10S585/946

    摘要： For Hydroisomerizering charges emanating from the Fischer-Tropsch process:a) hydrogen is reacted with the charge in contact with a catalyst 1 in a first reaction zone, the catalyst 1 comprising at least one alumina-based matrix and at least one hydro-dehydrogenation component andb) the effluent from the first reaction zone is put into contact with a catalyst 2 in a second reaction zone, the catalyst 2 comprising:20 to 97% by weight of at least one matrix,3 to 80% by weight of at least one Y zeolite in hydrogen form, the zeolite being characterized by an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of over 4.5; a sodium content of less than 1% by weight determined at 1100.degree. C. under calcining conditions; an a.sub.o crystal parameter of the elemental mesh of less than 24.70.times.10.sup.-10 m; and a specific surface area determined by the BET method of over 400 m.sup.2.g.sup.-1, andat least one hydro-dehydrogenation component.

    摘要翻译： 对于从费 - 托方法产生的加氢异构化电荷：a）氢与在第一反应区中与催化剂1接触的电荷反应，催化剂1包含至少一种基于氧化铝的基体和至少一个氢脱氢组分 和b）来自第一反应区的流出物与第二反应区中的催化剂2接触，催化剂2包含：至少一种基质20至97重量％，至少3至80重量％ 一种Y型沸石为氢形式，沸石的特征在于SiO 2 / Al 2 O 3摩尔比超过4.5; 在1100℃下在煅烧条件下测定的钠含量小于1重量％ 元素网的ao晶体参数小于24.70×10-10 m; 并且通过BET法测定的比表面积超过400m 2·g -1，和至少一种加氢脱氢组分。

    Method of hydrocracking paraffins emanating from the Fischer-Tropsch process using catalysts based on H-Y zeolite
    2.
    发明授权
    Method of hydrocracking paraffins emanating from the Fischer-Tropsch process using catalysts based on H-Y zeolite 失效
    使用基于H-Y沸石的催化剂从费 - 托方法发出的链烷烃的加氢裂化方法

    公开(公告)号：US5345019A

    公开(公告)日：1994-09-06

    申请号：US886225

    申请日：1992-05-21

    申请人： Pierre-Henri Bigeard ,  Alain Billon ,  Pierre Dufresne ,  Samuel Mignard

    发明人： Pierre-Henri Bigeard ,  Alain Billon ,  Pierre Dufresne ,  Samuel Mignard

    IPC分类号： C10G65/10 ,  C07C5/00 ,  C07C5/42

    CPC分类号： C10G65/10 ,  Y10S585/946

    摘要： A method of hydrocracking charges emanating from the Fischer-Tropsch process, in which:(a) hydrogen is reacted with the charge in contact with a catalyst 1 in a first reaction zone, the said catalyst 1 comprising at least one alumina-based matrix and at least one hydro-dehydrogenation component;(b) the effluent from the first reaction zone is put into contact with a catalyst 2 in a second reaction zone, the said catalyst 2 comprising:20 to 97% by weight of at least one matrix;3 to 80% by weight of at least one Y zeolite in hydrogen form,the said zeolite being characterized by an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of over 4.5:1, a sodium content of less than 1% by weight determined on a zeolite calcined at 1100.degree. C.; an a.sub.o crystal parameter of the elemental mesh of less than 24.70.times.10.sup.-10 m; and a specific surface area determined by the BET method of over 400 m.sup.2.g.sup.-1 ;and at least one hydro-dehydrogenation component.

    摘要翻译： 一种从费 - 托法生产的加氢裂化装料的方法，其中：（a）在第一反应区中使氢气与与催化剂1接触的电荷反应，所述催化剂1包含至少一种基于氧化铝的基体和 至少一种氢脱氢组分; （b）来自第一反应区的流出物与第二反应区中的催化剂2接触，所述催化剂2包含：至少一种基质的20至97重量％; 3至80重量％的至少一种氢形式的Y沸石，所述沸石的特征在于SiO 2 / Al 2 O 3摩尔比超过4.5:1，钠含量小于1重量％，在沸石上煅烧 1100℃。 元素网的ao晶体参数小于24.70x10-10 m; 并且通过BET法测定的比表面积超过400m 2·g -1; 和至少一种氢脱氢组分。

    Hydroisomerization treatment process for feeds from the fisher-tropsch process
    4.
    发明授权
    Hydroisomerization treatment process for feeds from the fisher-tropsch process 失效
    来自渔草过程的饲料的加氢异构化处理过程

    公开(公告)号：US5834522A

    公开(公告)日：1998-11-10

    申请号：US553654

    申请日：1996-07-05

    申请人： Samuel Mignard ,  Nathalie Marchal ,  Slavik Kasztelan ,  Pierre-Henri Bigeard ,  Alain Billon

    发明人： Samuel Mignard ,  Nathalie Marchal ,  Slavik Kasztelan ,  Pierre-Henri Bigeard ,  Alain Billon

    IPC分类号： B01J21/08 ,  B01J21/12 ,  B01J23/40 ,  B01J35/10 ,  C10G45/40 ,  C10G45/62 ,  C07C27/00

    CPC分类号： C10G45/62 ,  B01J21/12 ,  B01J23/40 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108

    摘要： The invention concerns a process for the hydroisomerisation treatment for feeds from the Fischer-Tropsch process. The catalyst is essentially constituted by 0.05% to 10% by weight of a precious metal and a silica (5-70%)/alumina support with a specific surface area of 100-500 m.sup.2 /g. The catalyst has an average pore diameter of 1-12 nm, the pore volume of pores with diameters between the average diameter .+-.3 nm being more than 40% of the total pore volume. The dispersion of the precious metal is 20-100% and the distribution coefficient for the precious metal is greater than 0.1. The process is operated at 200.degree.-450.degree. C. at a partial pressure of hydrogen of 2 to 25 MPa with a VVH of 0.1-10 h.sup.-1 and a hydrogen/feed volume ratio of 100-2000.

    摘要翻译： PCT No.PCT / FR95 / 00353 Sec。 371日期：1996年7月5日第 102（e）日期1996年7月5日PCT 1995年3月22日PCT公布。 出版物WO95 / 27020 PCT 日期1995年10月12日本发明涉及从费 - 托方法进料的加氢异构化处理方法。 催化剂基本上由0.05％至10％重量的贵金属和二氧化硅（5-70％）/比表面积为100-500m2 / g的氧化铝载体构成。 催化剂的平均孔径为1-12nm，直径在±3nm之间的孔的孔体积大于总孔体积的40％。 贵金属的分散度为20-100％，贵金属的分布系数大于0.1。 该工艺在200〜-450℃，氢气分压为2〜25MPa，VVH为0.1-10h-1，氢/进料体积比为100〜2000。

    Catalyst containing phosphorous and a process hydrotreatment of petroleum feeds using the catalyst
    5.
    发明授权
    Catalyst containing phosphorous and a process hydrotreatment of petroleum feeds using the catalyst 有权
    含有磷的催化剂和使用催化剂的石油进料的工艺加氢处理

    公开(公告)号：US06332976B1

    公开(公告)日：2001-12-25

    申请号：US09310105

    申请日：1999-05-12

    申请人： Samuel Mignard ,  Nathalie George-Marchal ,  Virginie Harle ,  Slavik Kasztelan

    发明人： Samuel Mignard ,  Nathalie George-Marchal ,  Virginie Harle ,  Slavik Kasztelan

    IPC分类号： C10G4508

    CPC分类号： B01J27/188 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/108 ,  C10G45/08 ,  C10G49/04

    摘要： The invention concerns an alumina based catalyst containing, expressed as the oxide content by weight, 2-10% by weight of cobalt oxide CoO, 10-30% by weight of molybdenum oxide MoO3 and 4-10% of phosphorous oxide P2O5, with a BET surface area in the range 100-300 m2/g, a crushing strength CSH of more than 1.4 MPa, and an average pore diameter in the range 8-11 nm, the pore volume of pores with diameter of more than 14 nm being less than 0.08 ml/g, or less than 22% of total pore volume, the volume of pores with a diameter of less than 8 nm being at most 0.05 ml/g, or less than 10% of total pore volume, the volume of pores with diameter less than 10 nm being in the range of 20%-70%, the volume of pores with diameter between 10 nm and 13 nm being in the range of 20%-60%, and the volume of pores with a diameter which is in the range 8 to 14 nm being in the range 0.20 ml/g to 0.8 ml/g. The invention also concerns a hydrotreatment process using the catalyst, in particular hydrodesulphuration.

    摘要翻译： 本发明涉及一种氧化铝基催化剂，其含有氧化物含量为2-10重量％的氧化钴CoO，10-30重量％的氧化钼MoO 3和4-10重量％的氧化磷P2O5，其中a BET表面积在100-300m2 / g范围内，抗碎强度CSH大于1.4MPa，平均孔径在8-11nm范围内，孔径大于14nm的孔体积较小 直径小于8nm的孔的体积至少为0.05ml / g，或小于总孔体积的10％，孔的体积小于0.08ml / g，或小于总细孔容积的22％ 直径小于10nm的范围在20％-70％的范围内，直径在10nm和13nm之间的孔的体积在20％-60％的范围内，直径的孔的体积是 在8至14nm的范围内在0.20ml / g至0.8ml / g的范围内。本发明还涉及使用该催化剂，特别是加氢脱硫的加氢处理方法。

    Process for activation of catalysts with a nitrogenous compound and excess thionic compound the catalysts that is obtained and it use in hydroconversion
    6.
    发明授权
    Process for activation of catalysts with a nitrogenous compound and excess thionic compound the catalysts that is obtained and it use in hydroconversion 有权
    用含氮化合物和过量的硫辛酸化合物活化催化剂的方法，所得催化剂及其在加氢转化中的应用

    公开(公告)号：US06187708B1

    公开(公告)日：2001-02-13

    申请号：US09305285

    申请日：1999-05-05

    申请人： Samuel Mignard ,  Virginie Harle ,  Slavik Kasztelan ,  Nathalie Marchal-George

    发明人： Samuel Mignard ,  Virginie Harle ,  Slavik Kasztelan ,  Nathalie Marchal-George

    IPC分类号： B01J3720

    CPC分类号： B01J37/20 ,  C10G47/12

    摘要： The invention relates to a process for the sulfurization of hydroconversion catalysts, whereby said catalyst contains at least one element of group VIII of the periodic table and optionally an element of group VI, whereby said metal is present in the oxide state. Said process comprises at least one stage that is carried out in a hydrotreatment zone in the presence of at least one thionic compound and at least one nitrogenous compound. This process is carried out in such a way that before the final sulfurization temperature is reached, at least 130% of the stoichiometric amount of sulfur that is necessary for complete sulfurization of the catalyst is injected in said catalyst.

    摘要翻译： 本发明涉及一种加氢转化催化剂硫化方法，其中所述催化剂含有至少一种元素周期表第Ⅷ族元素和任选的第Ⅵ族元素，其中所述金属以氧化态存在。 所述方法包括在至少一种硫辛酸化合物和至少一种含氮化合物的存在下在加氢处理区中进行的至少一个阶段。 该方法是在达到最终硫化温度之前进行的，在催化剂中注入催化剂完全硫化所需的化学计量量的至少130％的硫。

    Catalyst comprising a dioctahedral 2:1 phyllosilicate prepared in a fluoride medium and a process for the hydroconversion of petroleum feeds
    7.
    发明授权
    Catalyst comprising a dioctahedral 2:1 phyllosilicate prepared in a fluoride medium and a process for the hydroconversion of petroleum feeds 失效
    包含在氟化物介质中制备的二八面体2：1页硅酸盐的催化剂和用于石油进料加氢转化的方法

    公开(公告)号：US5997725A

    公开(公告)日：1999-12-07

    申请号：US806672

    申请日：1997-02-26

    申请人： Eric Benazzi ,  Samuel Mignard

    发明人： Eric Benazzi ,  Samuel Mignard

    IPC分类号： B01J29/08 ,  C10G47/18

    CPC分类号： B01J29/084

    摘要： The invention concerns a catalyst comprising at least one catalytic element, and a support comprising 20-99% by weight of at least one matrix, 1-80% by weight of at least one 2:1 dioctahedral phyllosilicate containing fluorine and 0-30% by weight of at least one Y zeolite. The catalytic element is from groups VI and/or VIII. Phosphorous can be present. The invention also concerns a process for the hydroconversion of said catalyst.

    摘要翻译： 本发明涉及包含至少一种催化元素的催化剂和包含20-99重量％的至少一种基质，1-80重量％至少一种含氟二异丁基二甲硅烷基硅酸盐和0-30重量％ 的至少一种Y沸石。 催化元素来自VI族和/或VIII族。 可以存在磷。 本发明还涉及所述催化剂的加氢转化方法。

    Catalyst and process for hydrocracking fractions that contain hydrocarbon
    10.
    发明授权
    Catalyst and process for hydrocracking fractions that contain hydrocarbon 有权
    含有烃的加氢裂化馏分的催化剂和方法

    公开(公告)号：US06174429B1

    公开(公告)日：2001-01-16

    申请号：US09175468

    申请日：1998-10-20

    申请人： Nathalie George-Marchal ,  Samuel Mignard ,  Slavik Kasztelan

    发明人： Nathalie George-Marchal ,  Samuel Mignard ,  Slavik Kasztelan

    IPC分类号： C10G4700

    CPC分类号： C10G47/20 ,  B01J29/166 ,  B01J35/108 ,  B01J2229/42

    摘要： The invention relates to a hydrocracking catalyst that contains at least one metal of group VIB, and/or at least one metal of group VIII of the periodic table, an alumina matrix, phosphorus, optionally at least one element from group VIIA (fluorine), and a zeolite Y that is not fully dealuminificated, with a crystalline parameter that is greater than 2,438 nm, an overall SiO2/Al2O3 ratio that is less than 8, and a framework SiO2/Al2O3 ratio that is less than 21 and greater than the overall SiO2/Al2O3 ratio. The invention also relates to a process for hydrocracking with this catalyst, in particular at low pressure of 7.5 to 11 MPa.

    摘要翻译： 本发明涉及加氢裂化催化剂，其含有至少一种VIB族金属和/或至少一种周期表第VIII族金属，氧化铝基质，磷，任选地至少一种来自VIIA族（氟）的元素， 和未完全脱沥青的沸石Y，其结晶参数大于2,438nm，SiO 2 / Al 2 O 3的总体比小于8，骨架SiO 2 / Al 2 O 3比小于21且大于总体 SiO2 / Al2O3比例。 本发明还涉及一种用该催化剂进行加氢裂化的方法，特别是在7.5至11MPa的低压下。