摘要:
A fabrication process for conformal coating of a thin polymer electrolyte layer on nanostructured electrode materials for three-dimensional micro/nanobattery applications, compositions thereof, and devices incorporating such compositions. In embodiments, conformal coatings (such as uniform thickness of around 20-30 nanometer) of polymer Polymethylmethacralate (PMMA) electrolyte layers around individual Ni—Sn nanowires were used as anodes for Li ion battery. This configuration showed high discharge capacity and excellent capacity retention even at high rates over extended cycling, allowing for scalable increase in areal capacity with electrode thickness. Such conformal nanoscale anode-electrolyte architectures were shown to be efficient Li-ion battery system.
摘要:
A fabrication process for conformal coating of a thin polymer electrolyte layer on nanostructured electrode materials for three-dimensional micro/nanobattery applications, compositions thereof, and devices incorporating such compositions. In embodiments, conformal coatings (such as uniform thickness of around 20-30 nanometer) of polymer Polymethylmethacralate (PMMA) electrolyte layers around individual Ni—Sn nanowires were used as anodes for Li ion battery. This configuration showed high discharge capacity and excellent capacity retention even at high rates over extended cycling, allowing for scalable increase in areal capacity with electrode thickness. Such conformal nanoscale anode-electrolyte architectures were shown to be efficient Li-ion battery system.
摘要:
Aligned carbon nanotube-polymer composite materials, systems and methods include a substrate that carries an adhesive coating thereon. A plurality of carbon nanostructures are adhered to the substrate by the adhesive coating, such that the nanostructures are formed into a predetermined architecture, such that the architecture of the nanostructures defines at least one orientation for a plurality of nanostructures, and defies the approximate spacing between the nanostructures and/or groups of nanostructures. The adherence of the carbon nanostructures in the adhesive coating stabilizes the predetermined architecture of the nanostructures, such that the architecture renders the composite material superhydrophobic.
摘要:
The invention is directed to carbon nanostructure composite systems which may be useful for various applications, including as dry adhesives, self-cleaning applications, electronics and display technologies, or in a wide variety of other areas where organized nanostructures may be formed and integrated into a flexible substrate. The present invention provides systems and methods wherein organized nanotube structures or other nanostructures are embedded within an adhesive, with the properties and characteristics of the nanotubes or other nanostructures exploited for use in various applications. In one aspect, the invention is directed to a self-cleaning carbon nanotube composite material that includes a substrate, an adhesive coating on at least a portion of the substrate, a plurality of carbon nanostructures formed into a predetermined architecture, each of the plurality of nanostructures having a substantially predetermined width and length, and the architecture of the plurality of nanostructures defining at least one orientation for a plurality of nanostructures, and defining the approximate spacing between nanostructures and/or groups of nanostructures, the carbon nanostructures architecture being at least partially adhered to the adhesive coating on the substrate in a manner that the architecture is stabilized in the predetermined architecture, wherein the carbon nanostructures architecture renders the composite material superhydrophobic.
摘要:
An optical absorber includes vertically aligned carbon nanotubes with an ultra-low reflectance less than 0.16% and an absorption efficiency greater than 99.84%. The index of refraction and the absorption constant are controlled by independently varying the nanotube diameter and nanotube spacing. The nanotubes are mostly double-walled. The density of the nanotube arrays is very low, around 0.015 g/cm3.
摘要翻译:光吸收器包括垂直排列的碳纳米管,超低反射率小于0.16%,吸收效率大于99.84%。 通过独立地改变纳米管直径和纳米管间距来控制折射率和吸收常数。 纳米管主要是双壁的。 纳米管阵列的密度非常低,约为0.015g / cm 3。
摘要:
A flash CVD process can be employed to grow micron- and nano-sized tree-like structures, particularly carbon structures on graphite electrodes. This process involves fast cyclic resistive heating of electrodes in an atmosphere of inert gas and hydrocarbons at below atmospheric pressure.
摘要:
The invention is directed to carbon nanostructure composite systems which may be useful for various applications, including as dry adhesives, electronics and display technologies, or in a wide variety of other areas where organized nanostructures may be formed and integrated into a flexible substrate. The present invention provides systems and methods wherein organized nanotube structures or other nanostructures are embedded within polymers or other flexible materials to provide a flexible skin-like material, with the properties and characteristics of the nanotubes or other nanostructures exploited for use in various applications. In one aspect, the invention is directed to a carbon nanotube/polymer composite material having a plurality of carbon nanotubes formed into a predetermined architecture, with each of the plurality of nanotubes having a desired width and length. The architecture of the plurality of nanotubes defines at least one orientation for a plurality of nanotubes, and also defines the approximate spacing between nanotubes and/or groups of nanotubes. The carbon nanotube architecture is at least partially embedded with a polymer matrix in a manner that the architecture is stabilized in the predetermined architecture. The polymer matrix may also be formed to have a desired predetermined thickness.
摘要:
Embodiments of the invention relate to energy storage devices, e.g., capacitors and batteries, that may include a composite article of elongated conductive structures embedded in a polymer matrix. In some embodiments, a liquid containing ionic species may be dispersed within the polymer matrix of the article. The liquid may contact the elongated conductive structures within the polymer matrix. When the composite article is used as an energy storage device, the large surface area at the interface between the elongated conductive structures and the liquid can provide high energy storage. Embodiments of the invention enable storing energy using a composite article that exhibits both high and low temperature stability, high cyclic repeatability, and mechanical flexibility. The composite article can also be non-toxic, biocompatible and environmentally friendly. Thus, the composite article may be useful for a variety of energy storage applications, such as in the automotive, RFID, MEMS and medical fields.
摘要:
A method of controllably aligning carbon nanotubes to a template structure to fabricate a variety of carbon nanotube containing structures and devices having desired characteristics is provided. The method allows simultaneous, selective growth of both vertically and horizontally controllably aligned nanotubes on the template structure but not on a substrate in a single process step.
摘要:
Methods for synthesizing macroscale 3D heteroatom-doped carbon nanotube materials (such as boron doped carbon nanotube materials) and compositions thereof. Macroscopic quantities of three-dimensionally networked heteroatom-doped carbon nanotube materials are directly grown using an aerosol-assisted chemical vapor deposition method. The porous heteroatom-doped carbon nanotube material is created by doping of heteroatoms (such as boron) in the nanotube lattice during growth, which influences the creation of elbow joints and branching of nanotubes leading, to the three dimensional super-structure. The super-hydrophobic heteroatom-doped carbon nanotube sponge is strongly oleophilic and can soak up large quantities of organic solvents and oil. The trapped oil can be burnt off and the heteroatom-doped carbon nanotube material can be used repeatedly as an oil removal scaffold. Optionally, the heteroatom-doped carbon nanotubes in the heteroatom-doped carbon nanotube materials can be welded to form one or more macroscale 3D carbon nanotubes.