-
公开(公告)号:US4962256A
公开(公告)日:1990-10-09
申请号:US469999
申请日:1990-01-25
申请人: Quang N. Le , David O. Marler , John P. McWilliams , Mae K. Rubin , Joosup Shim , Stephen S. Wong
发明人: Quang N. Le , David O. Marler , John P. McWilliams , Mae K. Rubin , Joosup Shim , Stephen S. Wong
CPC分类号: B01J29/04 , C07C2/12 , C07C2529/06 , C07C2529/70
摘要: Long chain alkyl aromatic compounds are prepared by alkylating an alkylatable aromatic compound with a long chain alkylating agent in the presence of catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms.
摘要翻译: 长链烷基芳族化合物是通过在催化剂存在下用长链烷基化剂烷基化可烷基化芳族化合物制备的,所述催化剂包含合成多孔结晶材料,其特征在于X射线衍射图包括12.36 +/- 0.4的面间d-间距, 11.03 +/- 0.2,8.33 +/- 0.14,6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃。
-
公开(公告)号:US4986894A
公开(公告)日:1991-01-22
申请号:US495545
申请日:1990-03-19
摘要: A process for dewaxing waxy hydrocarbon feedstocks to produce distillate fuels or lubricant stocks having improved pour point properties. The process comprises catalytic hydroisomerization of the feedstock over catalyst comprising a synthetic porous crystalline material characterized in its calcined form by an X-ray diffraction pattern including interplanar d-spacings at 12.36.+-.0.4, 11.03.+-.0.2, 8.83.+-.0.14, 6.18.+-.0.12, 6.00.+-.0.10, 4.06.+-.0.07, 3.91.+-.0.07 and 3.42.+-.0.06 Angstroms, and an Alpha Value of 10 or less.
摘要翻译: 用于脱蜡蜡质原料以生产具有改进的倾点性质的馏出燃料或润滑剂原料的方法。 该方法包括催化剂的催化加氢异构化,其包括合成多孔结晶材料,其特征在于其煅烧形式的X射线衍射图,其包括在12.36 +/- 0.4,11.03 +/- 0.2,8.83 +/-的平面d间距 0.14,6.18 +/- 0.12,6.00 +/- 0.10,4.06 +/- 0.07,3.91 +/- 0.07和3.42 +/- 0.06埃,Alpha值为10以下。
-
公开(公告)号:US4894212A
公开(公告)日:1990-01-16
申请号:US075496
申请日:1987-07-20
申请人: John P. McWilliams , Mae K. Rubin
发明人: John P. McWilliams , Mae K. Rubin
CPC分类号: C01B39/365 , C01B37/02
摘要: This invention relates to a new form of crystalline silicate identified as zeolite ZSM-11, to a new and useful improvement in synthesizing said crystalline silicate and to use of said crystalline silicate prepared in accordance herewith as a catalyst for organic compound, e.g. hydrocarbon compound, conversion.
-
公开(公告)号:US4983275A
公开(公告)日:1991-01-08
申请号:US426837
申请日:1989-10-26
申请人: John P. McWilliams , Mae K. Rubin
发明人: John P. McWilliams , Mae K. Rubin
CPC分类号: C01B37/02 , C01B33/185 , C01B39/365
摘要: This invention relates to use of a new improved form of crystalline silicate identified as zeolite ZSM-11 as a catalyst component for organic compound, e.g. hydrocarbon compound, conversion.
摘要翻译: 本发明涉及鉴定为ZSM-11沸石的新型结晶硅酸盐形式用作有机化合物的催化剂组分的用途, 烃化合物,转化。
-
公开(公告)号:US5063037A
公开(公告)日:1991-11-05
申请号:US913541
申请日:1986-09-24
申请人: Mae K. Rubin
发明人: Mae K. Rubin
IPC分类号: C07C1/20 , B01J29/00 , B01J29/70 , B01J29/86 , C01B35/12 , C01B39/04 , C01B39/10 , C01B39/12 , C07B61/00 , C07C1/00 , C07C2/66 , C07C2/86 , C07C5/333 , C07C6/12 , C07C11/02 , C07C15/02 , C07C15/08 , C07C67/00
CPC分类号: B01J29/70 , B01J29/86 , C01B35/1009 , B01J2229/20 , B01J2229/36
摘要: There is provided a boron-containing aluminosilicate zeolite corresponding to the substantially aluminum and boron free silicate zeolite described in the Hinnenkamp et al. U.S. Pat. No. 4,376,757. Also provided are methods for making this borosilicate zeolite and methods for the catalytic conversion of organic charges to desired products with this borosilicate zeolite.
摘要翻译: 提供了相应于Hinnenkamp等人描述的基本上不含铝和无硼的硅酸盐沸石的含硼硅铝酸盐沸石。 美国专利 4,376,757。 还提供了制备该硼硅酸盐沸石的方法以及用该硼硅酸盐沸石将有机电荷催化转化为所需产物的方法。
-
公开(公告)号:US4209499A
公开(公告)日:1980-06-24
申请号:US844168
申请日:1977-10-21
IPC分类号: C08F4/00 , B01J29/00 , B01J29/70 , C01B39/04 , C01B39/48 , C07B61/00 , C07C1/00 , C07C1/20 , C07C2/00 , C07C2/12 , C07C4/06 , C07C7/167 , C07C9/14 , C07C11/02 , C07C67/00 , C01B33/28
摘要: A new crystalline zeolite, designated ZSM-43, a method of making same and the use thereof in catalytic conversion of organic compounds is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides, as follows:(0.6 to 2.1)M.sub.2/n O : Al.sub.2 O.sub.3 : xSiO.sub.2wherein M is at least one cation having a valence n and x is at least 5, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译: 一种名为ZSM-43的新型结晶沸石,其制备方法及其在有机化合物的催化转化中的应用是本申请的主题。 新沸石具有无水状态的氧化物摩尔比表示的组成:(0.6-2.1)M2 / nO:Al2O3:xSiO2其中M是至少一个价数为n的阳离子,x是 至少5个,其特征在于指定的X射线粉末衍射图。
-
公开(公告)号:US4199556A
公开(公告)日:1980-04-22
申请号:US23856
申请日:1979-03-26
CPC分类号: B01J29/40 , C01B39/365 , C01B39/38 , Y10S423/22 , Y10S423/29
摘要: As synthesized by previous methods, ZSM-5 or ZSM-11 zeolites are crystallized in the presence of substantial amounts of a nitrogen-containing compound. When synthesized in this way, they contain an organic ammonium cation as well as a metal cation such as sodium. To obtain a more active form, the sodium ion must be exchanged out. Such exchange, especially with ZSM-5 and ZSM-11, is difficult unless there is calcination of the zeolite to remove the obstructing organo compounds. By making these zeolites in the presence of (1) seeds of the desired zeolite, (2) mixtures of them with ammonium hydroxide and/or alcohol, (3) the alcohol per se or (4) mixtures of the alcohol with ammonium hydroxide, a product substantially deficient in organic ammonium cation is obtained. These products can be exchanged directly without any calcination.
摘要翻译: 通过以前的方法合成,ZSM-5或ZSM-11沸石在大量含氮化合物的存在下结晶。 当以这种方式合成时,它们含有有机铵阳离子以及诸如钠的金属阳离子。 要获得更活跃的形式,必须将钠离子交换出来。 这种交换,尤其是与ZSM-5和ZSM-11的交换是困难的,除非有煅烧沸石去除阻碍的有机化合物。 在(1)所需沸石的种子存在下制备这些沸石,(2)它们与氢氧化铵和/或醇的混合物,(3)醇本身或(4)醇与氢氧化铵的混合物, 获得了有机铵阳离子基本上不足的产物。 这些产品可直接进行交换而无需任何煅烧。
-
公开(公告)号:US4081490A
公开(公告)日:1978-03-28
申请号:US739413
申请日:1976-11-08
CPC分类号: C07C5/41 , B01J29/65 , C01B39/445
摘要: Catalytic conversion of hydrocarbon compounds in the presence of crystalline zeolite ZSM-35, or a thermal decomposition product thereof, is provided. Zeolite ZSM-35 has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides as follows:(0.3-2.5)R.sub.2 O:(0-0.8)M.sub.2 O : Al.sub.2 O.sub.3 : (x) SiO.sub.2wherein R is an organic nitrogen-containing cation derived from ethylenediamine or pyrrolidine, M is an alkali metal cation and x is greater than 8, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译: 提供了在结晶沸石ZSM-35或其热分解产物存在下烃化合物的催化转化。 沸石ZSM-35具有无水状态的组成,以氧化物的摩尔比表示如下:
-
公开(公告)号:US4076842A
公开(公告)日:1978-02-28
申请号:US739414
申请日:1976-11-08
IPC分类号: C10G57/02 , B01J29/00 , B01J29/70 , C01B33/40 , C01B39/04 , C01B39/48 , C07B61/00 , C07C1/00 , C07C1/20 , C07C2/00 , C07C2/12 , C07C2/42 , C07C4/06 , C07C67/00 , C10G50/00 , C01B33/28
CPC分类号: C07C2/12 , B01J29/70 , C01B39/48 , C07C1/20 , C07C2/00 , B01J2229/36 , C07C2529/70 , Y10S423/36
摘要: A new crystalline zeolite, designated ZSM-23, a method of making same and the use thereof in catalytic conversion of organic compounds is the subject of this application. The new zeolite has a composition, in the anhydrous state, expressed in terms of mole ratios of oxides, as follows;(0.58-3.4)M.sub.2/n O : Al.sub.2 O.sub.3 : (40-250)SiO.sub.2wherein M is at least one cation having a valence n, and is characterized by a specified X-ray powder diffraction pattern.
摘要翻译: 一种名为ZSM-23的新型结晶沸石,其制备方法及其在有机化合物催化转化中的应用是本申请的主题。 新沸石具有以无水状态以氧化物的摩尔比表示的组成,如下所述: (0.58-3.4)M2 / nO:Al2O3:(40-250)SiO2,其中M是至少一种价数为n的阳离子,其特征在于规定的X射线粉末衍射图。
-
公开(公告)号:US5236575A
公开(公告)日:1993-08-17
申请号:US802938
申请日:1991-12-06
申请人: J. Michael Bennett , Clarence D. Chang , Stephen L. Lawton , Michael E. Leonowicz , Daria N. Lissy , Mae K. Rubin
发明人: J. Michael Bennett , Clarence D. Chang , Stephen L. Lawton , Michael E. Leonowicz , Daria N. Lissy , Mae K. Rubin
IPC分类号: B01J29/06 , B01J29/70 , C01B39/04 , C01B39/06 , C01B39/48 , C07B61/00 , C07C2/02 , C07C2/66 , C07C15/02 , C07C37/14 , C07C37/16 , C07C39/06 , C10G11/05 , C10G35/095
CPC分类号: B01J29/7038 , B01J29/70 , B01J29/7049 , B01J29/87 , C01B39/065 , C01B39/48 , B01J2229/26 , B01J2229/36 , B01J2229/42
摘要: This invention relates to a new synthetic porous crystalline material, a method for its preparation and use thereof in catalytic conversion of organic compounds. The new crystalline material exhibits a distinctive X-ray diffraction pattern.
摘要翻译: 本发明涉及一种新的合成多孔结晶材料,其制备方法和用于有机化合物的催化转化。 新的结晶材料表现出独特的X射线衍射图。
-
-
-
-
-
-
-
-
-