公开(公告)号：US20150158024A1

公开(公告)日：2015-06-11

申请号：US14621792

申请日：2015-02-13

Applicant: Reliance Industries Limited

Inventor： Sharad Vasudeorao Lande ,  Veera Venkata Satya Bhaskara Sita Rama Murthy Katravulapalli ,  Sreedharan Unnikrishnan ,  Nagesh Sharma ,  Shashank Vaidya ,  Raksh Vir Jasra

IPC: B01J37/18 ,  B01J21/04 ,  B01J37/02 ,  B01J27/135 ,  B01J37/00 ,  B01J35/10 ,  B01J35/02 ,  B01J23/02 ,  C07C5/333 ,  B01J37/08

CPC classification number: B01J37/18 ,  B01J21/04 ,  B01J23/02 ,  B01J23/58 ,  B01J23/626 ,  B01J27/13 ,  B01J27/135 ,  B01J35/0066 ,  B01J35/008 ,  B01J35/023 ,  B01J35/026 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0018 ,  B01J37/0203 ,  B01J37/0205 ,  B01J37/0223 ,  B01J37/0242 ,  B01J37/08 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2521/10 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/62 ,  C07C2527/10 ,  C10G11/00 ,  C10G11/02 ,  C10G2400/20 ,  C10G2400/22 ,  C07C11/02

Abstract: The present disclosure relates to a dehydrogenation catalyst composite comprising at least one alumina support impregnated with at least one layer of at least one alkaline earth metal element and at least one layer comprising at least one catalytic metal element, at least one group VIA element and optionally, at least one halogen element. The present disclosure also relates to a process for preparation of the dehydrogenation catalyst composite.

Abstract translation: 本公开内容涉及一种脱氢催化剂复合材料，其包含至少一个浸渍有至少一层至少一种碱土金属元素的氧化铝载体和至少一层包含至少一种催化金属元素，至少一种VIA族元素和任选地 ，至少一种卤素元素。 本公开还涉及一种制备脱氢催化剂复合材料的方法。

公开(公告)号：US09511356B2

公开(公告)日：2016-12-06

申请号：US14577495

申请日：2014-12-19

Applicant: Reliance Industries Limited

Inventor： Shashank Dattatraya Vaidya ,  Sharad Vasudeorao Lande ,  Sreedharan Unnikrishnan ,  Kalpana Gopalakrishnan ,  Raksh Vir Jasra

IPC: B01J23/96 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/18 ,  B01J38/20 ,  B01J38/44 ,  B01J21/04 ,  B01J23/62 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10 ,  B01J21/12 ,  B01J21/20

CPC classification number: B01J23/96 ,  B01J21/04 ,  B01J21/12 ,  B01J21/20 ,  B01J23/626 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/18 ,  B01J38/20 ,  B01J38/44

Abstract: There is provided a method for regenerating a spent dehydrogenation catalyst used in the conversion of n-paraffin to olefin. The method comprises method steps for removing the coke by treating the catalyst with an ozone-oxygen stream followed by an oxygen stream. The catalyst is stabilized by passing a nitrogen stream and the stabilized catalyst is rejuvenated by passing an air-nitrogen stream containing a halogenated hydrocarbon. This is followed by reducing the metal oxide in the catalyst by passing hydrogen-nitrogen stream.

Abstract translation: 提供了用于将正链烷烃转化为烯烃的用过的脱氢催化剂的再生方法。 该方法包括通过用臭氧 - 氧气流跟随氧气流处理催化剂来除去焦炭的方法步骤。 通过使氮气流通过使稳定的催化剂通过含有卤代烃的空气 - 氮气流来使催化剂恢复活力来稳定催化剂。 然后通过使氢 - 氮流通过还原催化剂中的金属氧化物。

公开(公告)号：US20150111720A1

公开(公告)日：2015-04-23

申请号：US14577495

申请日：2014-12-19

Applicant: Reliance Industries Limited

Inventor： Shashank Dattatraya Vaidya ,  Sharad Vasudeorao Lande ,  Sreedharan Unnikrishnan ,  Kalpana Gopalakrishnan ,  Raksh Vir Jasra

IPC: B01J23/96 ,  B01J23/62 ,  B01J21/12 ,  B01J21/20 ,  B01J21/04

CPC classification number: B01J23/96 ,  B01J21/04 ,  B01J21/12 ,  B01J21/20 ,  B01J23/626 ,  B01J35/002 ,  B01J35/006 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J38/02 ,  B01J38/10 ,  B01J38/12 ,  B01J38/18 ,  B01J38/20 ,  B01J38/44

Abstract: There is provided a method for regenerating a spent dehydrogenation catalyst used in the conversion of n-paraffin to olefin. The method comprises method steps for removing the coke by treating the catalyst with an ozone-oxygen stream followed by an oxygen stream. The catalyst is stabilized by passing a nitrogen stream and the stabilized catalyst is rejuvenated by passing an air-nitrogen stream containing a halogenated hydrocarbon. This is followed by reducing the metal oxide in the catalyst by passing hydrogen-nitrogen stream.

Abstract translation: 提供了用于将正链烷烃转化为烯烃的用过的脱氢催化剂的再生方法。 该方法包括通过用臭氧 - 氧气流跟随氧气流处理催化剂来除去焦炭的方法步骤。 通过使氮气流通过使稳定的催化剂通过含有卤代烃的空气 - 氮气流来使催化剂恢复活力来稳定催化剂。 然后通过使氢 - 氮流通过还原催化剂中的金属氧化物。

公开(公告)号：US20140323785A1

公开(公告)日：2014-10-30

申请号：US14359226

申请日：2012-11-20

Applicant: Reliance Industries Limited

Inventor： Sharad Vasuderao Lande ,  Venkata Satya Bhaskara Sita Rama Murthy Katravulapalli Veera ,  Sreedharan Unnikrishnan ,  Nagesh Sharma ,  Shashank Vaidya ,  Rajeshwer Dongara ,  Krishnamurthy Ramaswamy Konda

IPC: B01J31/26 ,  C07C5/32

CPC classification number: B01J31/26 ,  B01J21/04 ,  B01J23/42 ,  B01J23/468 ,  B01J23/626 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/006 ,  B01J35/008 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0205 ,  B01J37/0207 ,  B01J37/16 ,  C07C5/325 ,  C07C5/3337 ,  C07C2521/04 ,  C07C2523/04 ,  C07C2523/14 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2523/62 ,  C07C11/02

Abstract: The present invention provides a dehydrogenation catalyst composite that is capable of providing a dehydrogenated hydrocarbon product characterized by a bromine number of at least 19. for hydrocarbons. The dehydrogenation catalyst of the present invention comprises a nano-sized complex containing a Group VIII component; a group IVA component and a sulfur containing capping agent; an alkali component; a halogen component; and a support with an inner core of alpha alumina and an outer layer comprising a mixture of gamma alumina and delta alumina.

Abstract translation: 本发明提供一种脱氢催化剂复合材料，其能够提供特征在于烃的至少为19的溴值的脱氢烃产物。 本发明的脱氢催化剂包含含有VIII族成分的纳米级复合物; IVA组分和含硫封端剂; 碱组分; 卤素组分; 以及具有α氧化铝内核和包含γ氧化铝和δ氧化铝的混合物的外层的载体。