公开(公告)号：US4684598A

公开(公告)日：1987-08-04

申请号：US674129

申请日：1984-11-23

申请人： Richard S. Potember ,  Theodore O. Poehler

发明人： Richard S. Potember ,  Theodore O. Poehler

IPC分类号： G11B7/26 ,  G03C1/73 ,  G11B7/241 ,  G11B7/244 ,  G11B7/249 ,  G11B7/254 ,  G03C5/00

CPC分类号： G11B7/245 ,  G11B7/244 ,  G11B7/249 ,  G11B7/254 ,  Y10S430/10 ,  Y10S430/102

摘要： An enhanced optically sensitive medium is disclosed which uses an organic charge transfer complex as the switching material. The organic charge transfer complex includes at least one moiety in an oxidized state. An enhancement mechanism is taught which provides a secondary source of neutral molecules of said at least one constituent moiety in the neutral or altered oxidation state. For example, with CuTCNQ used as the switching material, the erasing characteristics can be improved by using a covering dispersion having a matrix polymer interspersed with neutral molecules of TCNQ.degree..

摘要翻译： 公开了一种使用有机电荷转移络合物作为开关材料的增强型光敏介质。 有机电荷转移络合物包括至少一个氧化状态的部分。 提出了增强机制，其提供了处于中性或改变的氧化态的所述至少一个构成部分的中性分子的次级来源。 例如，通过使用CuTCNQ作为开关材料，通过使用具有散布有TCNQ DEG的中性分子的基质聚合物的覆盖分散体，可以提高擦除特性。

公开(公告)号：US4825408A

公开(公告)日：1989-04-25

申请号：US35327

申请日：1987-04-07

申请人： Richard S. Potember ,  Theodore O. Poehler

发明人： Richard S. Potember ,  Theodore O. Poehler

IPC分类号： G03C1/73 ,  G11B7/244 ,  G11C11/56 ,  G11C13/02 ,  G11C13/04 ,  G11C13/00 ,  G03C1/00 ,  G03C3/00 ,  G11B3/70

CPC分类号： G11C13/0014 ,  B82Y10/00 ,  G03C1/73 ,  G11B7/244 ,  G11C11/5664 ,  G11C13/04

摘要： The charge transfer apparatus of the present invention comprises an optical storage medium of either a mixture of several charge transfer compounds of varying redox potential or a single amphoteric organic charge transfer compound capable of undergoing a multistage charge transfer reaction, and a source of optical energy, typically a laser. When the optical energy illuminates a spot on the optical storage medium, the spot switches to one of a plurality of optically detectable states.

摘要翻译： 本发明的电荷转移装置包括可以进行多级电荷转移反应的几种不同氧化还原电位的电荷转移化合物或单一两性有机电荷转移化合物的混合物的光学存储介质，以及光能源， 通常是激光。 当光能照射光学存储介质上的光点时，光斑切换到多个光学可检测状态之一。

公开(公告)号：US4663270A

公开(公告)日：1987-05-05

申请号：US603717

申请日：1984-04-25

申请人： Richard S. Potember ,  Theodore O. Poehler

发明人： Richard S. Potember ,  Theodore O. Poehler

IPC分类号： B41M5/26 ,  G03C1/73 ,  G03C5/00 ,  G03C5/56 ,  G11B7/00 ,  G11B7/004 ,  G11B7/24 ,  G11B7/244 ,  G11C11/56 ,  G11C13/02 ,  G11C13/04 ,  G03C1/00 ,  G03C3/00

CPC分类号： G11C13/0014 ,  B82Y10/00 ,  G03C1/73 ,  G11B7/244 ,  G11C11/5664 ,  G11C13/04 ,  Y10S430/10

摘要： A multistate organic optical storage medium is disclosed, wherein an optical beam can switch any "data storage spot" on said optical storage medium into three or more memory states. The optical storage medium may consist of a mixture of bistate switching modules, or it may consist of large delocalized amphoteric molecules. The illuminated area of said optical storage medium will undergo an electrochemical topactic redox reaction which will cause certain moieties in the illuminated area to change oxidation state. By changing the intensity of the optical "write" beam the illuminated area can be switched to a plurality of specific states each state having a unique set of oxidation species. An optical/spectroscopic means is used to identify the presence of oxidation species and to "read" the data stored.

摘要翻译： 公开了一种多状态有机光学存储介质，其中光束可以将所述光学存储介质上的任何“数据存储点”切换成三个或更多个存储器状态。 光学存储介质可以由双稳态切换模块的混合物组成，或者它可以由大的离域两性分子组成。 所述光学存储介质的照明区域将经历电化学顶部氧化还原反应，这将引起照明区域中的某些部分改变氧化态。 通过改变光学“写入”光束的强度，照明区域可以切换到多个特定状态，每个状态具有独特的一组氧化物质。 使用光学/光谱手段来识别氧化物质的存在并“读取”存储的数据。

公开(公告)号：US4731756A

公开(公告)日：1988-03-15

申请号：US770443

申请日：1985-08-29

申请人： Richard S. Potember ,  Theodore O. Poehler ,  Richard C. Benson

发明人： Richard S. Potember ,  Theodore O. Poehler ,  Richard C. Benson

IPC分类号： G03C1/73 ,  G11C13/02 ,  G11C13/04 ,  H03K3/40 ,  H03K17/78 ,  G11C11/00

CPC分类号： G11C13/0014 ,  B82Y10/00 ,  G03C1/73 ,  G11C13/047 ,  H03K17/78 ,  H03K3/40 ,  G11C13/04

摘要： Optical devices using an organic charge transfer salt as the switching and storage media are disclosed. Generally, a light beam of a given intensity directed to a film of certain organic charge transfer salts causes the illuminated area to change from a first to a second state. This electrochemical process is reversible with heat energy transforming the illuminated area back into the first state. The first and second states have identifiably different optical and electrical properties. The organic charge transfer salt is used to fabricate an erasable or permanent optical memory and a threshold on bistable optoelectronic switch.

摘要翻译： 公开了使用有机电荷转移盐作为开关和存储介质的光学器件。 通常，指向某些有机电荷转移盐的膜的给定强度的光束导致照明区域从第一状态变为第二状态。 该电化学过程是可逆的，热能将照明区域转换回第一状态。 第一和第二状态具有可识别的不同的光学和电气特性。 有机电荷转移盐用于制造可擦除或永久的光学存储器和双稳态光电开关的阈值。

公开(公告)号：US4574366A

公开(公告)日：1986-03-04

申请号：US464771

申请日：1983-02-07

申请人： Richard S. Potember ,  Theodore O. Poehler ,  Richard C. Benson

发明人： Richard S. Potember ,  Theodore O. Poehler ,  Richard C. Benson

IPC分类号： G03C5/00 ,  B41M5/26 ,  G02F1/01 ,  G03C1/72 ,  G03C1/73 ,  G11B7/24 ,  G11C11/42 ,  G11C13/02 ,  G11C13/04 ,  H03K3/40 ,  H03K17/78 ,  G11C11/00

CPC分类号： G11C13/0014 ,  B82Y10/00 ,  G03C1/73 ,  G11C13/047 ,  H03K17/78 ,  H03K3/40 ,  G11C13/04

摘要： Optical devices using an organic charge transfer salt as the switching and storage media are disclosed. Generally, a light beam of a given intensity directed to a film of certain organic charge transfer salts causes the illuminated area to change from a first to a second state. This electrochemical process is reversible with heat energy transforming the illuminated area back into the first state. The first and second states have identifiably different optical and electrical properties. The organic charge transfer salt is used to fabricate an erasable or permanent optical memory and a threshold on bistable optoelectronic switch.

公开(公告)号：US4507672A

公开(公告)日：1985-03-26

申请号：US385523

申请日：1982-06-07

申请人： Richard S. Potember ,  Theodore O. Poehler ,  Dwaine O. Cowan

发明人： Richard S. Potember ,  Theodore O. Poehler ,  Dwaine O. Cowan

IPC分类号： G11C13/02 ,  H01L45/00 ,  H01L51/00 ,  H01L51/30 ,  H01L51/40 ,  H01L29/28

CPC分类号： H01L51/05 ,  B82Y10/00 ,  G11C13/0014 ,  H01L51/0051

摘要： A current-controlled, bistable threshold or memory switch comprises a polycrystalline metal-organic semiconductor sandwiched between metallic electrodes. Films of either copper or silver complexed with TNAP, DDQ, TCNE, TCNQ, derivative TCNQ molecules, or other such electron acceptors provides switching between high and low impedance states with combined delay and switching times on the order of 1 nanosecond. Switching behavior of a complex of the present invention is related to the reduction potential of the acceptor molecule.Various other modifications, adaptations and alterations are of course possible in light of the above teachings. Therefore, it should be understood at this time that within the scope of the appended claims the invention may be practiced otherwise than as specifically described.

摘要翻译： 电流控制的双稳态阈值或存储器开关包括夹在金属电极之间的多晶金属 - 有机半导体。 与TNAP，DDQ，TCNE，TCNQ，衍生物TCNQ分子或其他这样的电子受体络合的铜或银的膜提供高阻抗状态和低阻抗状态之间的切换，其组合的延迟和切换时间为1纳秒级。 本发明的复合物的开关行为与受体分子的还原电位有关。 根据上述教导，当然可以进行各种其它修改，改编和改变。 因此，此时应当理解，在所附权利要求的范围内，本发明可以以不同于具体描述的方式实施。

公开(公告)号：US6120940A

公开(公告)日：2000-09-19

申请号：US961100

申请日：1997-10-30

申请人： Theodore O. Poehler ,  Peter Searson ,  Jeffrey Gilbert Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yosef Gofer

发明人： Theodore O. Poehler ,  Peter Searson ,  Jeffrey Gilbert Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yosef Gofer

IPC分类号： C08G61/12 ,  H01B1/12 ,  H01M4/04 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/60 ,  H01M10/052 ,  H01M10/0565 ,  H01M6/14

CPC分类号： H01M4/137 ,  C08G61/126 ,  H01B1/127 ,  H01M10/052 ,  H01M10/0565 ,  H01M4/0466 ,  H01M4/1399 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608 ,  Y10T29/49108

摘要： An electrochemical storage cell or battery including as at least one electrode at least one electrically conductive polymer, the polymer being poly(1,4-bis(2-thienyl)-3-fluorophenylene), poly(1,4-bis(2-thienyl)-2,5-difluorophenylene), poly(1,4-bis(2-thienyl)-2,3,5,6-tetrafluorophenylene), or poly(1,4-bis(2-thienyl)-benzene). These polymeric electrodes have remarkably high charge capacities, and excellent cycling efficiency. The provision of these polymeric electrodes further permits the electrochemical storage cell to be substantially free of metal components, thereby improving handling of the storage cell and obviating safety and environmental concerns associated with alternative secondary battery technology.

摘要翻译： 一种电化学存储单元或电池，其包括作为至少一个电极的至少一种导电聚合物，所述聚合物是聚（1,4-双（2-噻吩基）-3-氟亚苯基），聚（1,4-双（2- 噻吩基）-2,5-二氟亚苯基），聚（1,4-双（2-噻吩基）-2,3,5,6-四氟亚苯基）或聚（1,4-双（2-噻吩基） - 苯） 。 这些聚合物电极具有非常高的充电容量，并具有优异的循环效率。 提供这些聚合物电极进一步允许电化学存储电池基本上不含金属组分，从而改善存储电池的处理并避免与替代二次电池技术相关的安全和环境问题。

公开(公告)号：US06699621B2

公开(公告)日：2004-03-02

申请号：US09227214

申请日：1999-01-08

申请人： Theodore O. Poehler ,  Peter Searson ,  Jeffrey G. Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yosef Gofer ,  Walkiria S. Schlindwein

发明人： Theodore O. Poehler ,  Peter Searson ,  Jeffrey G. Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yosef Gofer ,  Walkiria S. Schlindwein

IPC分类号： H01M614

CPC分类号： H01M4/60 ,  H01B1/122 ,  H01M4/0438 ,  H01M4/0466 ,  H01M4/137 ,  H01M4/606 ,  H01M4/608 ,  H01M10/04 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0565 ,  H01M2300/0085 ,  Y10T29/49108

摘要： A method of manufacture of an electrode formed from at least one electrically conductive polymer having a lower, polymerization potential than p-doping peak. The method of manufacture of the electrode including a conditioning step which results in remarkably high charge capacities and excellent cycling efficiency. The provision of these polymeric electrodes further permits the manufacture of an electrochemical storage cell which is substantially free of metal components, thereby improving handling of the storage cell and obviating safety and environmental concerns associated with alternative secondary battery technology.

摘要翻译： 由至少一种具有比p掺杂峰值低的聚合电位的导电聚合物形成的电极的制造方法。 电极的制造方法包括调节步骤，其导致显着高的充电容量和优异的循环效率。 提供这些聚合物电极还允许制造基本上不含金属成分的电化学储存电池，从而改善存储电池的处理并消除与替代二次电池技术相关的安全和环境问题。

公开(公告)号：US5733683A

公开(公告)日：1998-03-31

申请号：US741015

申请日：1996-10-30

申请人： Peter Searson ,  Jeffrey Gilbert Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yossef Gofer ,  Theodore O. Poehler

发明人： Peter Searson ,  Jeffrey Gilbert Killian ,  Haripada Sarker ,  Jennifer Giaccai ,  Yossef Gofer ,  Theodore O. Poehler

IPC分类号： C08G61/12 ,  H01B1/12 ,  H01M4/137 ,  H01M4/1399 ,  H01M4/60 ,  H01M10/0565

CPC分类号： H01M4/137 ,  C08G61/126 ,  H01B1/127 ,  H01M10/0565 ,  H01M4/0466 ,  H01M4/1399 ,  H01M4/60 ,  H01M4/606 ,  H01M4/608

摘要： An electrochemical storage cell or battery including as at least one electrode at least one electrically conductive polymer, the polymer being poly (3(2-fluorophenyl)thiophene), poly(3(3-fluorophenyl) thiophene), poly(3(2,4-fluorophenyl) thiophene), poly(3(3,4-difluorophenyl) thiophene), poly(3(3,5-difluorophenyl) thiophene), or poly(3(3,4,5-trifluorophenyl)thiophene). These polymeric electrodes have remarkably high charge capacities, and excellent cycling efficiency. The provision of these polymeric electrode further permits the electrochemical storage cell to be substantially free of metal components, thereby improving handling of the storage cell and obviating safety and environmental concerns associated with alternative secondary battery technology.

摘要翻译： 一种电化学蓄电池或电池，包括至少一个电极至少一种导电聚合物，聚合物是聚（3（2-氟苯基）噻吩），聚（3（3-氟苯基）噻吩），聚（3（2- 4-氟苯基）噻吩），聚（3（3,4-二氟苯基）噻吩），聚（3（3,5-二氟苯基）噻吩）或聚（3（3,4,5-三氟苯基）噻吩）。 这些聚合物电极具有非常高的充电容量，并具有优异的循环效率。 提供这些聚合物电极还允许电化学存储电池基本上不含金属组分，从而改善存储电池的处理并避免与替代二次电池技术相关的安全和环境问题。

公开(公告)号：US5637421A

公开(公告)日：1997-06-10

申请号：US527598

申请日：1995-09-13

申请人： Theodore O. Poehler ,  Brendan M. Coffey ,  Robert R. Oberle ,  Jeffrey G. Killian ,  Peter C. Searson

发明人： Theodore O. Poehler ,  Brendan M. Coffey ,  Robert R. Oberle ,  Jeffrey G. Killian ,  Peter C. Searson

IPC分类号： H01M4/60 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/40

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M4/60 ,  Y02P70/54 ,  Y10T29/49115

摘要： This invention provides a method for producing a quasi-solid state charge storage device capable of being repeatedly charged and discharged, having one or more electrochemical cells with a structure capable of being stacked or combined to form primary or secondary battery devices, each cell composed entirely of an ionically conducting gel polymer electrolyte layer separating opposing surfaces of electronically conducting conjugated polymeric anode and cathode electrodes supported on lightweight porous substrates; a method of forming conjugated polymers into large area composite electrode structures with practical levels of charge storage capacity; and a quasi-solid state charge storage device produced by the above methods.

摘要翻译： 本发明提供了一种能够重复充电和放电的准固体电荷存储装置的制造方法，其具有一个或多个电化学电池，该电化学电池具有能堆叠或组合以形成一次或二次电池装置的结构，每个电池完全组成 离子导电的凝胶聚合物电解质层，其分离支撑在轻质多孔基材上的电子导电共轭聚合阳极和阴极的相对表面; 将共轭聚合物形成大面积复合电极结构的方法，具有实际的电荷存储容量; 以及通过上述方法制造的准固态电荷存储装置。