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公开(公告)号:US20070155848A1
公开(公告)日:2007-07-05
申请号:US11322080
申请日:2005-12-29
Applicant: Douglas Miller , Irwin Lewis , Richard Shao , Terrence Pirro , Orest Andrianowycz
Inventor: Douglas Miller , Irwin Lewis , Richard Shao , Terrence Pirro , Orest Andrianowycz
IPC: C08G63/00
CPC classification number: C04B41/5092 , C04B38/0032 , C04B41/5006 , C04B41/85 , C04B2111/00431 , C04B41/0072 , C04B41/4535 , C04B41/502 , C04B35/52 , C04B38/0054 , C04B38/0061 , C04B38/0074
Abstract: A carbon foam material with an improved oxidation resistance is created by blending formaldehyde with phenol to form a reactive mixture, polymerizing the reactive mixture with a non-oxidation promoting basic catalyst to form a resin article, foaming the resin article to create phenolic foam, and carbonizing the phenolic foam to create the carbon foam with an increased oxidation resistance. Specifically, the oxidation resistant carbon foam has a sodium content of approximately 0%. This inventive foam may also contain one or more oxidization inhibitors to impede the oxidation of the carbon foam when the foam is exposed to an oxidizing environment.
Abstract translation: 通过将甲醛与苯酚混合以形成反应性混合物,使反应混合物与非氧化促进碱性催化剂聚合以形成树脂制品,使树脂制品发泡以产生酚醛泡沫,并产生酚醛泡沫,产生具有改善抗氧化性的碳泡沫材料,以及 碳化酚醛泡沫以产生具有增加的抗氧化性的碳泡沫。 具体地说,抗氧化碳泡沫的钠含量约为0%。 当泡沫暴露于氧化环境时,本发明的泡沫体还可含有一种或多种氧化抑制剂,以阻止碳泡沫的氧化。
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公开(公告)号:US20070154702A1
公开(公告)日:2007-07-05
申请号:US11321693
申请日:2005-12-29
Applicant: Douglas Miller , Irwin Lewis , Richard Shao
Inventor: Douglas Miller , Irwin Lewis , Richard Shao
IPC: B32B9/00
CPC classification number: C04B41/526 , C01B32/00 , C04B38/0032 , C04B41/009 , C04B41/89 , C04B2111/0087 , Y10T428/249987 , Y10T428/249988 , Y10T428/24999 , Y10T428/249991 , C04B35/52 , C04B41/4539 , C04B41/5001 , C04B41/4554
Abstract: A glassy carbon coated carbon foam material is formed by coating carbon foam with a glassy carbon layer. Carbon foam may be produced by carbonizing a phenolic or polyurethane foam at high temperatures in an inert atmosphere. The carbon foam is then machined to a desired shape and treated with a fine carbon or graphite powder to the surface. Subsequently a resin is applied to the surface of the carbon foam, and the coated carbon foam block is fired to carbonize the resin coating into a glassy carbon coating. The firing and coating are repeated until the desired coating thickness and surface properties are achieved.
Abstract translation: 通过用碳玻璃碳层涂覆碳泡沫形成玻璃碳涂覆的碳泡沫材料。 可以通过在惰性气氛中高温下将酚醛或聚氨酯泡沫碳化来生产碳泡沫。 然后将碳泡沫机加工成所需的形状,并将细碳或石墨粉末处理到表面。 随后将树脂施加到碳泡沫的表面上,并且将涂覆的碳泡沫块烧制以将树脂涂层碳化成玻璃碳涂层。 重复烧制和涂覆,直到达到所需的涂层厚度和表面性能。
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公开(公告)号:US20060159905A1
公开(公告)日:2006-07-20
申请号:US11137111
申请日:2005-05-25
Applicant: Richard Shao , Douglas Miller , Irwin Lewis , Robert Mercuri
Inventor: Richard Shao , Douglas Miller , Irwin Lewis , Robert Mercuri
CPC classification number: B32B27/18 , C04B38/0032 , C04B41/009 , C04B41/4823 , C04B41/83 , C09K3/10 , C09K2200/02 , Y10T428/249953 , Y10T428/249982 , Y10T428/249983 , Y10T428/249991 , Y10T428/28 , C04B41/4535 , C04B41/4547 , C04B41/5001 , C04B35/52 , C04B38/0074 , C04B38/00 , C04B35/524 , C04B38/0054 , C04B38/0067
Abstract: A sealant useful for sealing the surfaces of carbon foams to provide a surface useful for, inter alia, composite tooling or other high temperature applications or for bonding of carbon foams together to form larger blocks.
Abstract translation: 用于密封碳泡沫表面以提供用于尤其是复合模具或其它高温应用或用于将碳泡沫粘合在一起以形成更大块的表面的密封剂。
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公开(公告)号:US20070154381A1
公开(公告)日:2007-07-05
申请号:US11321714
申请日:2005-12-29
Applicant: Douglas Miller , Irwin Lewis , Richard Shao , Terrence Pirro
Inventor: Douglas Miller , Irwin Lewis , Richard Shao , Terrence Pirro
CPC classification number: C04B38/0032 , C04B35/524 , C04B2111/00258 , C04B2111/00431 , C04B2111/763 , C04B2111/94 , C04B2201/32 , C04B2235/3409 , C04B2235/3821 , C04B2235/421 , C04B2235/48 , C04B35/52 , C04B38/0051 , C04B38/0054 , C04B38/0067 , C04B38/0074
Abstract: A carbon foam material with improved graphitizability is formed by including a graphitization promoting additive into the carbon foam. The graphitization promoting additive greatly improves the graphitic structure of the carbon foam resulting in a carbon foam with much greater thermal and electrical conductivities. This inventive foam may be created by introducing the graphitization promoting additive during the catalysis of a phenol-aldehyde mixture to a form phenolic resin or during the conversion of the phenolic resin to a phenolic foam. Alternatively, the graphitization promoting additive can be fixed onto a preformed carbon foam.
Abstract translation: 通过在碳泡沫中包含石墨化促进添加剂来形成具有改善的石墨化性质的碳泡沫材料。 石墨化促进添加剂大大改善了碳泡沫的石墨结构,导致碳泡沫具有更高的热和电导率。 本发明的泡沫可以通过在苯酚 - 醛混合物催化成酚醛树脂或将酚醛树脂转化成酚醛泡沫体期间引入石墨化促进添加剂来产生。 或者,可将石墨化促进添加剂固定在预先形成的碳泡沫上。
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公开(公告)号:US20070218272A1
公开(公告)日:2007-09-20
申请号:US11677613
申请日:2007-02-22
Applicant: Richard Shao , Irwin Lewis
Inventor: Richard Shao , Irwin Lewis
IPC: B32B7/12
CPC classification number: B32B27/18 , C04B38/0032 , C04B41/009 , C04B41/4823 , C04B41/83 , C09K3/10 , C09K2200/02 , Y10T428/249953 , Y10T428/249982 , Y10T428/249983 , Y10T428/249991 , Y10T428/28 , C04B41/4535 , C04B41/4547 , C04B41/5001 , C04B35/52 , C04B38/0074 , C04B38/00 , C04B35/524 , C04B38/0054 , C04B38/0067
Abstract: A cement useful for bonding carbon articles or sealing the surfaces of carbon articles to provide a surface useful for, inter alia, composite tooling or other high temperature applications or for bonding of carbon articles together to form larger blocks.
Abstract translation: 用于粘结碳制品或密封碳制品表面的水泥,以提供用于尤其是复合模具或其它高温应用或用于将碳制品粘合在一起以形成更大块的表面。
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公开(公告)号:US20070155849A1
公开(公告)日:2007-07-05
申请号:US11321739
申请日:2005-12-29
Applicant: Douglas Miller , Irwin Lewis , Richard Shao , Mehmet Yazici
Inventor: Douglas Miller , Irwin Lewis , Richard Shao , Mehmet Yazici
CPC classification number: C08G8/10 , C04B35/83 , C04B38/0022 , C04B2111/00431 , C04B2111/00853 , C04B2111/00939 , C04B2111/2046 , C04B2111/52 , C04B2235/48 , C04B2235/483 , C04B2235/5248 , C04B2235/787 , C08J9/0085 , C08J2203/06 , C08J2361/06 , Y10S521/919 , Y10T428/30 , C04B38/0064 , C04B38/0074 , C04B38/08
Abstract: A reinforced carbon foam material is formed from carbon fibers incorporated within a carbon foam's structure. First, carbon fiber bundles are combined with a liquid resol resin. The carbon fiber bundles separate into individual carbon fiber filaments and disperse throughout the liquid resol resin. Second, the carbon fiber resin mixture is foamed thus fixing the carbon fibers in a permanent spatial arrangement within the phenolic foam. The foam is then carbonized to create a carbon fiber reinforced foam with improved graphitic characteristics as well as increased strength. Optionally, various additives can be introduced simultaneously with the addition of the carbon fiber bundles into the liquid resol, which can improve the graphitic nature of the final carbon foam material and/or increase the foam's resistance to oxidation.
Abstract translation: 增强碳泡沫材料由掺入碳泡沫结构中的碳纤维形成。 首先,将碳纤维束与液体甲醛树脂组合。 碳纤维束分成单独的碳纤维长丝,并分散在整个液体甲醛树脂中。 第二,将碳纤维树脂混合物发泡,从而将酚醛泡沫塑料中的永久性空间布置的碳纤维固定。 然后将泡沫碳化以产生具有改善的石墨特性以及增加的强度的碳纤维增强泡沫。 任选地,可以将各种添加剂同时引入,将碳纤维束加入到液体甲醇溶胶中,这可以改善最终的碳泡沫材料的石墨性质和/或增加泡沫的抗氧化性。
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公开(公告)号:US20070155847A1
公开(公告)日:2007-07-05
申请号:US11321757
申请日:2005-12-29
Applicant: Douglas Miller , Irwin Lewis , Richard Shao , Terrence Pirro
Inventor: Douglas Miller , Irwin Lewis , Richard Shao , Terrence Pirro
IPC: C08G63/00
CPC classification number: C04B38/0032 , C04B2111/00793 , C04B35/52
Abstract: An activated carbon foam material with improved graphitizability is formed by including an oxidation promoting metal-containing additive into the carbon foam and subsequently heat treating the foam in a reactive atmosphere. The oxidation promoting metal-containing additive greatly improves the development of the carbon foam's ramified pore system resulting in a carbon foam with a much greater surface area. This inventive foam may be created by introducing the oxidation promoting metal by way of an oxidation catalyst during the polymerization of the phenolic resin or as a inorganic chemical activating agent to the formed phenolic resin. The foam is then heated in a reactive atmosphere to produce an activated foam with a surface area of from about 200 m2/g to about 3000 m2/g.
Abstract translation: 通过在碳泡沫中包含含氧化促进金属的添加剂并随后在反应性气氛中对泡沫进行热处理,形成具有改善的石墨化性的活性炭泡沫材料。 含氧化促进金属的添加剂大大改善了碳泡沫的分枝孔体系的发展,导致具有更大表面积的碳泡沫。 本发明的泡沫体可以通过在酚醛树脂的聚合过程中通过氧化催化剂引入氧化促进金属或作为无机化学活化剂引入所形成的酚醛树脂中来产生。 然后将泡沫在反应性气氛中加热以产生表面积为约200m 2 / g至约3000m 2 / g的活化泡沫。
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公开(公告)号:US20070141344A1
公开(公告)日:2007-06-21
申请号:US11367776
申请日:2006-03-03
Applicant: Douglas Miller , Irwin Lewis , Richard Shao
Inventor: Douglas Miller , Irwin Lewis , Richard Shao
IPC: B32B9/00
CPC classification number: B32B5/18 , B32B5/245 , B32B15/046 , B32B2250/40 , B32B2262/0269 , B32B2262/101 , B32B2262/106 , B32B2266/0278 , B32B2266/0285 , B32B2307/54 , B32B2307/542 , B32B2307/552 , B32B2307/718 , B32B2307/72 , B32B2605/12 , B63B3/48 , B63B3/68 , C04B38/0032 , Y10T428/30 , C04B35/524 , C04B38/0054 , C04B38/0067 , C04B38/0074
Abstract: A laminate sandwich structure useful for, inter alia, decking for naval vessels, which includes a core formed of carbon foam having a ratio of compressive strength to density of at least about 7000 psi/g/cc.
Abstract translation: 一种层压夹层结构,尤其用于海军船只的甲板,其包括由碳泡沫形成的芯,其压缩强度与密度之比至少为约7000psi / g / cc。
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公开(公告)号:US20060192311A1
公开(公告)日:2006-08-31
申请号:US11148155
申请日:2005-06-08
Applicant: James Kortovich , Richard Shao , Irwin Lewis , Richard Lewis , Dai Huang
Inventor: James Kortovich , Richard Shao , Irwin Lewis , Richard Lewis , Dai Huang
CPC classification number: C04B35/522 , B29C47/0016 , B29C47/788 , B29C47/822 , B29C47/8805 , C04B35/532 , C04B35/83 , C04B2235/3272 , C04B2235/526 , C04B2235/5264 , C04B2235/5272 , C04B2235/5436 , C04B2235/6021 , C04B2235/77 , C04B2235/96 , C04B2235/9607
Abstract: A process for preparing graphite articles is presented. In particular, the process includes employing a particulate fraction comprising at least about 35 weight percent coke, coal or combinations thereof having a diameter such that a major fraction of it passes through a 0.25 mm to 25 mm mesh screen. The particulate fraction is mixed with a liquid or solid pitch binder, to form a stock blend; the stock blend is extruded to form a green stock; the green stock is baked to form a carbonized stock; and the carbonized stock is graphitized. The stock blend further includes carbon fibers added after mixing of the particulate fraction and pitch has begun.
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公开(公告)号:US20070172659A1
公开(公告)日:2007-07-26
申请号:US11340370
申请日:2006-01-26
Applicant: Richard Shao
Inventor: Richard Shao
CPC classification number: C04B41/5059 , C04B35/5615 , C04B41/009 , C04B41/87 , C04B2111/00362 , C04B2111/00982 , C04B2235/3826 , C04B2235/3843 , C04B2235/3891 , C04B2235/422 , C04B2235/656 , C04B2235/727 , C04B2235/80 , F16D69/023 , F16D2200/0047 , Y10T428/30 , C04B41/4539 , C04B41/4556 , C04B41/5061 , C04B41/5071 , C04B35/83
Abstract: An oxidation-resistant carbon composite is formed from a protective coating applied over the surface of the carbon composite. The coating, itself, is formed through the application of a metal silicide containing medium to a carbon composite and subsequently heated to convert a portion of the metal silicide into silicon carbide and a metal carbide. The invention exhibits improved oxidation resistance especially in high temperature applications in the presence of oxidizing gases. Of particular interest is the application of the present invention for high friction disc brake systems for vehicles including aircraft.
Abstract translation: 通过涂覆在碳复合材料表面上的保护涂层形成抗氧化碳复合材料。 涂层本身通过将含金属硅化物的介质施加到碳复合材料上形成,随后被加热以将一部分金属硅化物转化为碳化硅和金属碳化物。 本发明表现出改善的抗氧化性,特别是在氧化气体存在下的高温应用中。 特别感兴趣的是本发明用于包括飞行器的车辆的高摩擦盘式制动系统。
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