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公开(公告)号：US5013535A
公开(公告)日：1991-05-07
申请号：US340829
申请日：1989-04-20
CPC分类号： C01B37/08 , C01B37/04 , Y10S423/30
摘要： Aluminophosphate-based molecular sieve compositions having the crystal structure of AlPO.sub.4 -54 are stabilized against framework collapse or conversion to other crystal structures by treatment in their hydrated state with boric acid or salts thereof. The stabiized products are characterized, in addition to their essential AlPO.sub.4 -54 structure, by the presence of at least 6 ppm of extraneous boron.
摘要翻译： 具有AlPO4-54晶体结构的磷酸铝基分子筛组合物通过用硼酸或其盐处理它们的水合状态而稳定，防止骨架塌陷或转化成其它晶体结构。 通过至少6ppm的外来硼的存在，除了其基本的AlPO4-54结构之外，稳定的产物被表征。
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2.发明授权Hydrocarbon conversion process using crystalline microporous metal sulfide compositions 失效使用结晶微孔金属硫化物组合物的烃转化方法
公开(公告)号：US4933068A
公开(公告)日：1990-06-12
申请号：US416170
申请日：1989-10-02
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82
摘要： This invention relates to a hydrocarbon conversion process using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2+0.2 :ZH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. This invention also relates to a composition having the empirical formula expressed in molar ratios: XR:M.sub.1-y M.sup.'y A.sub.2+0.2 :ZH.sub.2 O where M' is a metal such as cobalt, zinc, manganese, iron, nickel, cooper, cadmium and gallium.
摘要翻译： 本发明涉及使用具有MA2单元的三维微孔结构的结晶组合物的烃转化方法，其中A是硫或硒，并且具有以摩尔比表示的经验式：xR：MA2 + 0.2：ZH2O其中R表示至少 存在于晶体内孔体系中的一种有机模板剂，x是R的摩尔数，z是水的摩尔数，M是锗或锡。 本发明还涉及具有以摩尔比表示的经验式的组合物：XR：M1-yM'yA2 + 0.2：ZH2O其中M'是金属如钴，锌，锰，铁，镍，铜，镉和镓 。
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公开(公告)号：US4880761A
公开(公告)日：1989-11-14
申请号：US280757
申请日：1988-12-06
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82
摘要： This invention relates to a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. This invention also relates to a composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium. This invention further relates to a method of preparing the crystalline composition.
摘要翻译： 本发明涉及一种具有MA2单元的三维微孔结构的结晶组合物，其中A是硫或硒并具有以摩尔比表示的经验式：xR：MA2 +/- 0.2：zH2O其中R表示至少一种有机模板剂 存在于晶体内孔体系中，x是R的摩尔数，z是水的摩尔数，M是锗或锡。 本发明还涉及具有以摩尔比表示的经验式的组合物：xR：M1-yM'yA2 +/- 0.2：zH2O，其中M'是诸如钴，锌，锰，铁，镍，铜，镉的金属 和镓。 本发明还涉及一种制备该结晶组合物的方法。
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公开(公告)号：US5122357A
公开(公告)日：1992-06-16
申请号：US670826
申请日：1991-03-18
IPC分类号： B01J29/00 , B01J29/84 , B01J29/85 , C01B17/98 , C01G1/00 , C01G9/00 , C01G15/00 , C01G17/00 , C01G19/00 , C01G37/00
CPC分类号： C01B33/2884 , B01J29/005 , B01J29/85 , B01J29/84
摘要： This invention deals with a crystalline oxysulfide composition, a process for preparing the composition, a catalyst using the composition and processes using the composition. The crystalline oxysulfide composition has a three-dimensional microporous framework structure of at least MO.sub.2, MS.sub.2, and MOS tetrahedral units, having an intracrystalline pore system and an empirical formula expressed in molar ratios:(M.sub.s Al.sub.t P.sub.u Si.sub.v)S.sub.w O.sub.2-wwhere M is at least one metal selected from the group consisting of metals which: 1) can be incorporated into the framework structure of a microporous molecular sieve and 2) form hydrolytically stable sulfides; s, t, u, v and w are the mole fractions of M, Al, P, Si and S respectively. The oxysulfide composition is prepared by contacting a molecular sieve having an empirical formula: (M.sub.s Al.sub.t P.sub.u Si.sub.v)O.sub.2 with a sulfur containing compound such as carbonyl sulfide for a time and a temperature sufficient to sulfide a fraction of the metal. The oxysulfide compositions are useful as catalyst in hydrocarbon conversion processes such as cracking.
摘要翻译： 本发明涉及结晶氧硫化物组合物，制备组合物的方法，使用该组合物的催化剂和使用该组合物的方法。 结晶氧硫化物组合物具有至少具有MO2，MS2和MOS四面体单元的三维微孔骨架结构，其具有结晶孔系统和以摩尔比表示的经验式：（MsAltPuSiv）SwO 2 -w，其中M为至少一个 选自以下的金属的金属：1）可以结合到微孔分子筛的骨架结构中，2）形成水解稳定的硫化物; s，t，u，v和w分别是M，Al，P，Si和S的摩尔分数。 通过使经验式为（MsAltPuSiv）O 2的分子筛与含硫化合物如硫化羰接触一段时间和足以硫化金属部分的温度来制备氧硫化物组合物。 氧硫化物组合物可用作烃转化过程如裂解中的催化剂。
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5.发明授权Hydrocarbon conversion processes using a novel crystalline microporous metal oxysulfide composition 失效使用新的结晶微孔金属氧硫化物组合物的烃转化方法
公开(公告)号：US5128025A
公开(公告)日：1992-07-07
申请号：US803936
申请日：1991-12-09
CPC分类号： B01J29/85 , B01J29/005 , C01B33/2884 , B01J29/84
摘要： This invention deals with a hydrocarbon conversion process using a crystalline oxysulfide composition. The crystalline oxysulfide composition has a three-dimensional microporous framework structure of at least MO.sub.2, MS.sub.2, and MOS tetrahedral units, having an intracrystalline pore system and an empirical formula expressed in molar ratios:(M.sub.s Al.sub.t P.sub.u Si.sub.v)S.sub.w O.sub.2-wwhere M is at least one metal selected from the group consisting of metals which: 1) can be incorporated into the framework structure of a microporous molecular sieve and 2) form hydrolytically stable sulfides; s, t, u, v and w are the mole fractions of M, Al, P, Si and S respectively. The values of s, t, u and v are chosen such that when t is greater than zero u is greater than zero, s+t+u+v=1 and when s=1, M is only a combination of gallium and germanium.
摘要翻译： 本发明涉及使用结晶氧硫化物组合物的烃转化方法。 结晶氧硫化物组合物具有至少具有MO2，MS2和MOS四面体单元的三维微孔骨架结构，具有结晶孔系统和以摩尔比表示的经验式：（MsAltPuSiv）SwO 2 -w，其中M为至少一个 选自以下的金属的金属：1）可以结合到微孔分子筛的骨架结构中，2）形成水解稳定的硫化物; s，t，u，v和w分别是M，Al，P，Si和S的摩尔分数。 选择s，t，u和v的值，使得当t大于零时，u大于零，s + t + u + v = 1，当s = 1时，M只是镓和锗的组合 。
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6.发明授权Process for separating a mixture of molecular species using crystalline microporous metal sulfide compositions 失效使用结晶微孔金属硫化物组合物分离分子物质的混合物的方法
公开(公告)号：US5013337A
公开(公告)日：1991-05-07
申请号：US507819
申请日：1990-04-12
CPC分类号： B01J31/0254 , B01J27/04 , B01J31/0239 , C01B17/20 , C01B19/007 , C01G17/00 , C09K11/06 , B01J2231/641 , C01P2002/72 , C01P2002/74 , C01P2006/80 , C01P2006/82 , Y10S95/902
摘要： This invention relates to a process for separating a mixture of molecular species based on the molecular size (kinetic diameter) or on the degree of polarity of the molecular species using a crystalline composition having a three-dimensional microporous structure of MA.sub.2 units where A is sulfur or selenium and having the empirical formula expressed in molar ratios: xR:MA.sub.2.+-.0.2 :zH.sub.2 O where R represents at least one organic templating agent present in the intracrystalline pore system, x is the moles of R, z is the moles of water and M is germanium or tin. A composition having the empirical formula expressed in molar ratios: xR:M.sub.1-y M'.sub.y A.sub.2.+-.0.2 :zH.sub.2 O, where M' is a metal such as cobalt, zinc, manganese, iron, nickel, copper, cadmium and gallium may also be used in the process.
摘要翻译： 本发明涉及使用具有MA2单元的三维微孔结构的结晶组合物，基于分子大小（动力学直径）或分子物质的极性的程度来分离分子种类的混合物的方法，其中A是硫 或硒，并具有以摩尔比表示的经验式：xR：MA2 +/- 0.2：zH2O其中R表示晶体内孔体系中存在的至少一种有机模板剂，x是R的摩尔数，z是水的摩尔数， M是锗或锡。 具有以摩尔比表示的经验式的组合物：xR：M1-yM'yA2 +/- 0.2：zH2O，其中M'是诸如钴，锌，锰，铁，镍，铜，镉和镓的金属也可以是 在过程中使用。
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公开(公告)号：US5478787A
公开(公告)日：1995-12-26
申请号：US174092
申请日：1994-02-28
申请人： Hemant W. Dandekar , David A. Lesch , Thomas M. Reynolds , Robert L. Patton , Stephen T. Wilson , Gregory J. Gajda
发明人： Hemant W. Dandekar , David A. Lesch , Thomas M. Reynolds , Robert L. Patton , Stephen T. Wilson , Gregory J. Gajda
CPC分类号： B01J29/85 , C01B37/08 , C07C5/2724 , B01J2229/26 , B01J2229/42
摘要： This invention presents a novel MgAPSO molecular sieve, containing a critical range of magnesium: in the sieve framework and having a small crystallite size, which is particularly active for hydrocarbon conversion. The sieve advantageously is incorporated, along with a platinum-group metal, into a catalyst formulation which is useful for isomerization. When utilized in a process for isomerizing a non-equilibrium mixture of xylenes containing ethylbenzene, a greater yield of para-xylene is obtained compared to prior-art processes.
摘要翻译： 本发明提出了一种新颖的MgAPSO分子筛，其含有临界范围的镁：在筛骨架中并具有小的微晶尺寸，其对烃转化特别有活性。 筛有利地与铂族金属一起掺入可用于异构化的催化剂制剂中。 当用于异构化含有乙苯的二甲苯的非平衡混合物的方法中时，与现有技术方法相比，获得更高的对二甲苯产率。
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8.发明授权
公开(公告)号：US4781814A
公开(公告)日：1988-11-01
申请号：US46396
申请日：1987-05-06
IPC分类号： B01J29/84 , C01B37/06 , C01B39/54 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/05 , C10G47/02 , C10G11/04 , C10G45/12 , C10G47/04
CPC分类号： C07C5/41 , B01J29/84 , C01B37/06 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structure of MO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis are expressed by the formula:mR: (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; "M" represents at least two elements capable of forming framework tetrahedral oxides and selected from the group consisting of arsenic, beryllium, boron, chromium, gallium, germanium, lithium and vanadium; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed. The catalyst is useful in the cracking and hydrocracking of various hydrocarbonaceous feeds.
摘要翻译： 公开了具有MO2，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基的经验化学组成由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; “M”表示能够形成骨架四面体氧化物并选自砷，铍，硼，铬，镓，锗，锂和钒的至少两种元素; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 公开了它们作为吸附剂，催化剂等的用途。 该催化剂可用于各种烃类进料的裂化和加氢裂化。
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公开(公告)号：US5516957A
公开(公告)日：1996-05-14
申请号：US442741
申请日：1995-05-17
申请人： Hermant W. Dandekar , David A. Lesch , Thomas M. Reynolds , Robert L. Patton , Stephen T. Wilson , Gregory J. Gajda
发明人： Hermant W. Dandekar , David A. Lesch , Thomas M. Reynolds , Robert L. Patton , Stephen T. Wilson , Gregory J. Gajda
CPC分类号： B01J29/85 , C01B37/08 , C07C5/2724 , B01J2229/26 , B01J2229/42
摘要： This invention presents a novel MgAPSO molecular sieve, containing a critical range of magnesium in the sieve framework and having a small crystallite size, which is particularly active for hydrocarbon conversion. The sieve advantageously is incorporated, along with a platinum-group metal, into a catalyst formulation which is useful for isomerization. When utilized in a process for isomerizing a non-equilibrium mixture of xylenes containing ethylbenzene, a greater yield of para-xylene is obtained compared to prior-art processes.
摘要翻译： 本发明提出了一种新型的MgAPSO分子筛，其在筛骨架中含有镁的临界范围并且具有小的微晶尺寸，其对烃转化特别有活性。 筛有利地与铂族金属一起掺入可用于异构化的催化剂制剂中。 当用于异构化含有乙苯的二甲苯的非平衡混合物的方法中时，与现有技术方法相比，获得更高的对二甲苯产率。
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10.发明授权
公开(公告)号：US4973460A
公开(公告)日：1990-11-27
申请号：US218494
申请日：1988-07-06
IPC分类号： B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41
CPC分类号： C07C5/41 , B01J29/85 , C01B37/06 , C01B37/08 , C07C2/12 , C07C2/54 , C07C4/06 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2527/173 , C07C2529/84 , Y10S423/30
摘要： Molecular sieve compositions having three-dimensional microporous framework structures of LiO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Li.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of lithium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
摘要翻译： 公开了具有LiO 2，AlO 2，PO 2和SiO 2四面体氧化物单元的三维微孔骨架结构的分子筛组合物。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（LiwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（LiwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锂，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。
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