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公开(公告)号：US20080260621A1
公开(公告)日：2008-10-23
申请号：US11737942
申请日：2007-04-20
CPC分类号： C01G49/0018 , C01B13/185 , C01B32/60 , C01G45/1221 , C01G49/0036 , C01G49/0072 , C01P2002/50 , C01P2002/72
摘要： The present invention provides a process for making a complex metal oxide comprising the formula AxByOz. The process comprises the steps of: (a) reacting in solution at a temperature of between about 75° C. to about 100° C. at least one water-soluble salt of A, at least one water-soluble salt of B and a stoichiometric amount of a carbonate salt or a bicarbonate salt required to form a mole of a carbonate precipitate represented by the formula AxBy(CO3)n, wherein the reacting is conducted in a substantial absence of carbon dioxide to form the carbonate precipitate and wherein the molar amount of carbonate salt or bicarbonate salt is at least three times the stoichiometric amount of carbonate or bicarbonate salt required to form a mole of the carbonate precipitate; and (b) reacting the carbonate precipitate with an oxygen containing fluid under conditions to form the complex metal oxide.
摘要翻译： 本发明提供一种制备复合金属氧化物的方法，所述复合金属氧化物包括下式：其中R 1，R 2，R 3， 该方法包括以下步骤：（a）在约75℃至约100℃的温度下在溶液中使至少一种A的水溶性盐，至少一种B的水溶性盐和 化学计量量的形成一摩尔由式A表示的碳酸盐沉淀所需的碳酸盐或碳酸氢盐（CO 3/3） 其中反应在基本上不存在二氧化碳的情况下进行以形成碳酸盐沉淀物，并且其中碳酸盐或碳酸氢盐的摩尔量为化学计量量的碳酸盐的至少三倍或 形成一摩尔碳酸盐沉淀物所需的碳酸氢盐; 和（b）在条件下使碳酸盐沉淀物与含氧流体反应以形成复合金属氧化物。
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公开(公告)号：US07897128B2
公开(公告)日：2011-03-01
申请号：US11737942
申请日：2007-04-20
IPC分类号： C01G45/00
CPC分类号： C01G49/0018 , C01B13/185 , C01B32/60 , C01G45/1221 , C01G49/0036 , C01G49/0072 , C01P2002/50 , C01P2002/72
摘要： The present invention provides a process for making a complex metal oxide comprising the formula AxByOz. The process comprises the steps of: (a) reacting in solution at a temperature of between about 75° C. to about 100° C. at least one water-soluble salt of A, at least one water-soluble salt of B and a stoichiometric amount of a carbonate salt or a bicarbonate salt required to form a mole of a carbonate precipitate represented by the formula AxBy(CO3)n, wherein the reacting is conducted in a substantial absence of carbon dioxide to form the carbonate precipitate and wherein the molar amount of carbonate salt or bicarbonate salt is at least three times the stoichiometric amount of carbonate or bicarbonate salt required to form a mole of the carbonate precipitate; and (b) reacting the carbonate precipitate with an oxygen containing fluid under conditions to form the complex metal oxide.
摘要翻译： 本发明提供一种制备复合金属氧化物的方法，该复合金属氧化物包含式AxByOz。 该方法包括以下步骤：（a）在约75℃至约100℃的温度下在溶液中使至少一种A的水溶性盐，至少一种B的水溶性盐和 化学计量的形成式AxBy（CO3）n表示的摩尔碳酸盐沉淀所需的碳酸盐或碳酸氢盐，其中反应在基本上不存在二氧化碳的情况下进行以形成碳酸盐沉淀物，其中摩尔 碳酸盐或碳酸氢盐的量至少为形成一摩尔碳酸盐沉淀物所需的碳酸盐或碳酸氢盐的化学计量量的三倍; 和（b）在条件下使碳酸盐沉淀物与含氧流体反应以形成复合金属氧化物。
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公开(公告)号：US08038981B2
公开(公告)日：2011-10-18
申请号：US12352863
申请日：2009-01-13
申请人： Diwakar Garg , Robert Quinn , Frederick Carl Wilhelm , Gokhan Alptekin , Margarita Dubovik , Matthew Schaefer
发明人： Diwakar Garg , Robert Quinn , Frederick Carl Wilhelm , Gokhan Alptekin , Margarita Dubovik , Matthew Schaefer
CPC分类号： C01B3/56 , B01J20/041 , B01J20/06 , B01J20/28011 , B01J20/2803 , B01J23/002 , B01J23/8892 , B01J23/8986 , B01J23/94 , B01J23/96 , B01J37/0009 , B01J38/12 , B01J2523/00 , C01B3/38 , C01B2203/0233 , C01B2203/0425 , C01B2203/043 , C01B2203/0475 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , G01C21/30 , G01C21/32 , Y02P20/52 , Y02P20/584 , B01J2523/23 , B01J2523/72 , B01J2523/842
摘要： Complex metal oxide-containing pellets and their use for producing hydrogen. The complex metal oxide-containing pellets are suitable for use in a fixed bed reactor due to sufficient crush strength. The complex metal oxide-containing pellets comprise one or more complex metal oxides and at least one of in-situ formed calcium titanate and calcium aluminate. calcium titanate and calcium aluminate are formed by reaction of suitable precursors in a mixture with one or more complex metal carbonates. The complex metal oxide-containing pellets optionally comprise at least one precious metal.
摘要翻译： 含复合金属氧化物的颗粒及其用于生产氢的用途。 复合金属氧化物颗粒由于足够的压碎强度适合用于固定床反应器。 含复合金属氧化物的颗粒包含一种或多种复合金属氧化物和至少一种原位形成的钛酸钙和铝酸钙。 通过合适的前体与一种或多种复合金属碳酸盐的混合物的反应形成钛酸钙和铝酸钙。 含复合金属氧化物的颗粒任选地包含至少一种贵金属。
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公开(公告)号：US20090196822A1
公开(公告)日：2009-08-06
申请号：US12352863
申请日：2009-01-13
申请人： Diwakar Garg , Robert Quinn , Frederick Carl Wilhelm , Gokhan Alptekin , Margarita Dubovik , Matthew Schaefer
发明人： Diwakar Garg , Robert Quinn , Frederick Carl Wilhelm , Gokhan Alptekin , Margarita Dubovik , Matthew Schaefer
CPC分类号： C01B3/56 , B01J20/041 , B01J20/06 , B01J20/28011 , B01J20/2803 , B01J23/002 , B01J23/8892 , B01J23/8986 , B01J23/94 , B01J23/96 , B01J37/0009 , B01J38/12 , B01J2523/00 , C01B3/38 , C01B2203/0233 , C01B2203/0425 , C01B2203/043 , C01B2203/0475 , C01B2203/1047 , C01B2203/1064 , C01B2203/107 , G01C21/30 , G01C21/32 , Y02P20/52 , Y02P20/584 , B01J2523/23 , B01J2523/72 , B01J2523/842
摘要： Complex metal oxide-containing pellets and their use for producing hydrogen. The complex metal oxide-containing pellets are suitable for use in a fixed bed reactor due to sufficient crush strength. The complex metal oxide-containing pellets comprise one or more complex metal oxides and at least one of in-situ formed calcium titanate and calcium aluminate. calcium titanate and calcium aluminate are formed by reaction of suitable precursors in a mixture with one or more complex metal carbonates. The complex metal oxide-containing pellets optionally comprise at least one precious metal.
摘要翻译： 含复合金属氧化物的颗粒及其用于生产氢的用途。 复合金属氧化物颗粒由于足够的压碎强度适合用于固定床反应器。 含复合金属氧化物的颗粒包含一种或多种复合金属氧化物和至少一种原位形成的钛酸钙和铝酸钙。 通过合适的前体与一种或多种复合金属碳酸盐的混合物的反应形成钛酸钙和铝酸钙。 含复合金属氧化物的颗粒任选地包含至少一种贵金属。
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公开(公告)号：US07824655B2
公开(公告)日：2010-11-02
申请号：US11339060
申请日：2006-01-25
CPC分类号： C01B3/38 , C01B3/46 , C01B2203/0233 , C01B2203/0425 , C01B2203/0475 , Y02P20/52
摘要： In a process for producing a hydrogen-containing gas, a hydrocarbon feed gas and steam are introduced into a reaction vessel containing a complex metal oxide and steam-hydrocarbon reforming catalyst thereby forming a combustible gas mixture comprising hydrogen. A regeneration gas comprising greater than 0.1 volume % oxygen up to and including 2 volume % oxygen is introduced into the reaction vessel to displace at least a portion of the combustible gas mixture from the reaction vessel. Subsequently, additional regeneration gases may be introduced into the reaction vessel. Numerous means for providing various regeneration gases are presented.
摘要翻译： 在制造含氢气体的方法中，将烃进料气体和蒸汽引入含有复合金属氧化物和蒸汽 - 烃重整催化剂的反应容器中，从而形成包含氢气的可燃气体混合物。 将包括大于0.1体积％氧气的再生气体引入反应容器中以将至少一部分可燃气体混合物从反应容器中置换。 随后，可以向反应容器中引入另外的再生气体。 提出了许多用于提供各种再生气体的方法。
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公开(公告)号：US20100196259A1
公开(公告)日：2010-08-05
申请号：US12630388
申请日：2009-12-03
CPC分类号： B01D53/02 , B01D53/62 , B01D2251/404 , B01D2253/112 , B01D2253/304 , B01D2253/308 , B01D2253/311 , B01D2257/504 , B01J20/041 , B01J20/28004 , B01J20/28011 , B01J20/2803 , B01J20/28054 , B01J20/28069 , B01J20/28085 , C01B3/38 , C01B3/56 , C01B2203/0233 , C01B2203/0425 , C01B2203/043 , C01B2203/0475 , C01B2203/1005 , C01B2203/1041 , C01B2203/1058 , C01B2203/1082 , C01B2203/1088 , C01B2203/1241 , C01B2203/1614 , Y02C10/04 , Y02C10/08 , Y02C20/20 , Y02P20/152
摘要： CO2 sorptive pellets and/or granules and their use for removing CO2 from CO2-containing gases and for producing hydrogen. CO2 sorptive pellets are suitable for use in fixed bed reactors and the like due to sufficient crush strength. CO2 sorptive granules are suitable for moving, ebullated, expanded and fluidized beds. The CO2 sorptive pellets and/or granules comprise calcium oxide and/or magnesium oxide and at least one binding agent such as calcium titanate, calcium aluminate, calcium zirconate, magnesium titanate, magnesium aluminate, and magnesium zirconate. A method for making the CO2-sorptive pellets is described. The CO2 sorptive pellets optionally comprise at Ni, Pd, Pt, and/or Rh.
摘要翻译： CO2吸附颗粒和/或颗粒，以及它们用于从含CO 2气体中除去CO 2和用于产生氢的用途。 CO 2吸附颗粒由于足够的压碎强度而适合用于固定床反应器等。 CO2吸附颗粒适用于移动，沸腾，膨胀和流化床。 CO 2吸附性颗粒和/或颗粒包含氧化钙和/或氧化镁和至少一种结合剂，例如钛酸钙，铝酸钙，锆酸锆，钛酸镁，铝酸镁和锆酸镁。 描述了制备二氧化碳吸附颗粒的方法。 CO 2吸附颗粒任选地包含Ni，Pd，Pt和/或Rh。
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7.发明申请Process for the Production of Hydrogen Gas Employing a Thermally Stable Catalyst 审中-公开使用热稳定催化剂生产氢气的方法公开(公告)号：US20100068130A1
公开(公告)日：2010-03-18
申请号：US12211981
申请日：2008-09-17
申请人： Frederick Carl Wilhelm , Robert R. Broekhuis , Diwakar Garg , Sudipta Chattopadhyay , William B. Retallick
发明人： Frederick Carl Wilhelm , Robert R. Broekhuis , Diwakar Garg , Sudipta Chattopadhyay , William B. Retallick
CPC分类号： C01B3/384 , B01J21/04 , B01J23/63 , B01J23/83 , B01J37/0207 , B01J37/0225 , B01J37/0242 , C01B3/40 , C01B2203/0233 , C01B2203/1017 , C01B2203/1023 , C01B2203/1058 , C01B2203/1064 , C01B2203/1082 , C01B2203/1241 , C01B2203/1247 , Y02P20/52
摘要： The present invention provides a process for producing a gaseous product comprising hydrogen, said process comprising: contacting a feed gas mixture comprising steam and a gas comprising from 1 to 5 carbon atoms with a catalyst structure under reaction conditions sufficient to produce the product gas comprising hydrogen, wherein the catalyst structure comprises: a metal substrate comprising a metal; at least one layer of a catalyst support material coated onto the metal substrate, wherein the catalyst support material comprises: θ-alumina, zirconia, and at least one rare earth metal oxide; and at least one catalytically active component, wherein the at least one catalytically active component is incorporated either into or onto the catalyst support material.
摘要翻译： 本发明提供了一种生产包含氢的气态产物的方法，所述方法包括：在足以产生包含氢气的产物气体的反应条件下，将包含蒸汽和包含1至5个碳原子的气体的进料气体混合物与催化剂结构接触 其中所述催化剂结构包括：包含金属的金属基材; 涂覆在金属基材上的至少一层催化剂载体材料，其中催化剂载体材料包括： - 氧化铝，氧化锆和至少一种稀土金属氧化物; 和至少一种催化活性组分，其中所述至少一种催化活性组分引入到催化剂载体材料中或载体上。
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8.发明授权Supported catalyst and use thereof for reforming of steam and hydrocarbons 有权负载催化剂及其用于蒸汽和碳氢化合物重整的用途公开(公告)号：US08877673B2
公开(公告)日：2014-11-04
申请号：US13882543
申请日：2011-11-08
IPC分类号： B01J23/02 , B01J37/00 , B01J35/10 , C01B3/40 , B01J23/00 , B01J23/78 , B01J37/02 , B01J23/83 , B01J37/08
CPC分类号： B01J23/83 , B01J23/002 , B01J23/78 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/08 , C01B3/40 , C01B2203/0233 , C01B2203/0811 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , C01B2203/1247 , Y02P20/52
摘要： A method of making a supported catalyst for reforming of steam and hydrocarbons and a steam-hydrocarbon reforming process using the supported catalyst. The supported catalyst is made from a mixture comprising 20 to 99.5 mass % of lanthanum-stabilized γ-alumina and/or lanthanum-stabilized θ-alumina, 0 to 60 mass % oalumina, 0 to 25 mass % of calcium carbonate and/or magnesium carbonate, and 0.5 to 5 mass % of graphite, a cellulose ether, and/or magnesium stearate. The supported catalyst has a porosity between 55% and 75% and a pore volume between 0.3 cc/g and 0.65 cc/g.
摘要翻译： 制备用于蒸汽和烃的重整的负载催化剂的方法和使用负载型催化剂的蒸汽 - 烃重整方法。 负载型催化剂由含有镧稳定的γ-氧化铝和/或镧稳定的氧化铝20〜99.5质量％，氧化钇0〜60质量％，碳酸钙0〜25质量％和/或 碳酸镁，0.5〜5质量％的石墨，纤维素醚，和/或硬脂酸镁。 载体催化剂的孔隙率为55％至75％，孔体积为0.3cc / g至0.65cc / g。
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9.发明申请公开(公告)号：US20130225399A1
公开(公告)日：2013-08-29
申请号：US13882543
申请日：2011-11-08
IPC分类号： B01J23/83
CPC分类号： B01J23/83 , B01J23/002 , B01J23/78 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0018 , B01J37/0201 , B01J37/08 , C01B3/40 , C01B2203/0233 , C01B2203/0811 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , C01B2203/1247 , Y02P20/52
摘要： A method of making a supported catalyst for reforming of steam and hydrocarbons and a steam-hydrocarbon reforming process using the supported catalyst. The supported catalyst is made from a mixture comprising 20 to 99.5 mass % of lanthanum-stabilized γ-alumina and/or lanthanum-stabilized θ-alumina, 0 to 60 mass % oalumina, 0 to 25 mass % of calcium carbonate and/or magnesium carbonate, and 0.5 to 5 mass % of graphite, a cellulose ether, and/or magnesium stearate. The supported catalyst has a porosity between 55% and 75% and a pore volume between 0.3 cc/g and 0.65 cc/g.
摘要翻译： 制备用于蒸汽和烃的重整的负载催化剂的方法和使用负载型催化剂的蒸汽 - 烃重整方法。 载体催化剂由包含20-99.5质量％的镧稳定的γ-氧化铝和/或镧稳定的θ-氧化铝，0至60质量％的氧化铝，0至25质量％的碳酸钙和/或镁的混合物制成 碳酸盐，0.5〜5质量％的石墨，纤维素醚，和/或硬脂酸镁。 载体催化剂的孔隙率为55％至75％，孔体积为0.3cc / g至0.65cc / g。
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公开(公告)号：US07563308B2
公开(公告)日：2009-07-21
申请号：US11208723
申请日：2005-08-23
申请人： Daniel Joseph Tempel , Philip Bruce Henderson , Jeffrey Richard Brzozowski , Ronald Martin Pearlstein , Diwakar Garg
发明人： Daniel Joseph Tempel , Philip Bruce Henderson , Jeffrey Richard Brzozowski , Ronald Martin Pearlstein , Diwakar Garg
CPC分类号： C01B3/001 , C01B9/08 , C01B13/0285 , C01B25/06 , C01B32/80 , F17C11/00 , F17C11/005 , F17C11/007 , Y02E60/321 , Y02E60/324
摘要： A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.
摘要翻译： 本文公开了用于储存和输送气体的混合物和方法。 在一个方面，提供了一种混合物，其包含：包含阴离子和阳离子的离子液体，所述气体的至少一部分设置在离子液体内并可逆地与离子液体化学反应，以及任选的未反应气体。 在另一方面，提供了一种从包含离子液体和一种或多种气体的混合物输送气体的方法，包括：使至少一部分气体与离子液体反应，以提供包含化学反应气体和 离子液体并且从混合物中分离化学反应的气体，其中分离步骤之后的化学反应气体在反应步骤之前具有与化学反应气体基本上相同的化学同一性。
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