摘要:
Process for the preparation of a catalyst including an inert support, cobalt, ruthenium and a third element selected from scandium and yttrium, comprising at least the following steps:1) Preparation of a first catalytic precursor (A) containing cobalt and the inert support: subsequent calcination, reduction and passivation;2) Preparation of a second catalytic precursor (B) containing cobalt, ruthenium and the inert support, by means of the deposition of ruthenium on the first catalytic support (A): subsequent calcination, reduction and passivation3) Preparation of the final catalyst by means of the deposition of an element selected from scandium and yttrium on the catalytic precursor (B); subsequent calcination, reduction and passivation.
摘要:
A process for the alkylation of aliphatic hydrocarbons with olefins catalyzed by a silica-based material, characterised in that the surface Si--OH groups of said silica are esterified with a fluoroalkylsulphonic acid of formula CF.sub.3 (CF.sub.2).sub.n SO.sub.3 H, where n is a whole number between 0 and 11, said material having a Hammett acidity Ho.ltoreq.-11.4.
摘要翻译:一种用二氧化硅基材料催化的用烯烃烷基化脂族烃的方法,其特征在于所述二氧化硅的表面Si-OH基团用式CF 3(CF 2)n SO 3 H的氟代烷基磺酸酯化,其中n是整数 在0和11之间,所述材料具有哈米特酸度H H 11-14。
摘要:
Process for the epoxidation of olefins with oxygen and/or air and a redox system, in the presence of titanium silicalite, characterized in that the redox system is selected from: 1) quinone/hydroquinone derivatives having the general formula (Ia) and (Ib) ##STR1## 2) acetophenone/1-phenyl ethanol derivatives having the general formula (IIa) and (IIb) ##STR2##
摘要:
A synthetic, crystalline, porous material is disclosed, together with the related preparation process. Such material of zeolitic nature containing oxides of silicon, titanium and gallium corresponds, in the calcined and anhydrous state, to the following empyrical formula:pHGaO.sub.2.qTiO.sub.2.SiO.sub.2,wherein p has a value greater than zero and smaller than or equal to 0.050, and q has a value greater than zero and smaller than or equal to 0.025, and the H.sup.+ of HGaO.sub.2 can be at least partially replaceable or replaced by cations.
摘要:
A method is disclosed for preparing complexes of metals of the VIII Group of the Periodic Table, useful as hydrogenation catalysts. The method, as a single-step process, comprises reacting a polymeric complex containing V Group elements and VIII Group metal compounds directly with a metal atom which is directly bound to the V group element in the presence of a reducing substance. The reducing substance is selected among alkali metal and alkaline earth metal hydrides, mixed alkaline-III group element hydrides, organic metallic compounds of III Group metals, alkali metal and alkaline earth metal alkyls, Grignard compounds.