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1.发明授权Transparent blend compositions containing graft copolymers of (thioaromatic) alkylate rubber substrates 失效含有（硫代芳族）烷基化物橡胶底物的接枝共聚物的透明共混组合物
公开(公告)号：US5512631A
公开(公告)日：1996-04-30
申请号：US152801
申请日：1993-11-12
IPC分类号： C07C323/12 , C08F20/38 , C08F265/00 , C08F265/04 , C08F265/06 , C08F273/00 , C08L51/00 , C08L51/06 , C08L69/00 , C08L77/00
CPC分类号： C08F265/04 , C08F273/00
摘要： Compounds of Formula I ##STR1## wherein Z is an aromatic group, each R is individually selected from the group consisting of alkyl groups of from 1 to about 12 carbon atoms, thioalkyl groups of from 1 to about 12 carbon atoms, and halogen atoms, n is from 1 to about 6, and x is from 0 to 7, are suitable for use in preparing rubber latex particles. The rubbers are useful as substrates in graft copolymers and the resulting graft copolymers are suitable for use in thermoplastic blend compositions, particularly with transparent polymers. The rubber materials are advantageous in that they exhibit low glass transition temperatures and high refractive indices.
摘要翻译： 式I的化合物其中Z是芳族基团，其中R各自独立地选自1至约12个碳原子的烷基，1至约12个碳原子的硫代烷基和 卤素原子，n为1至约6，x为0至7，适用于制备橡胶胶乳颗粒。 橡胶可用作接枝共聚物中的底物，所得接枝共聚物适用于热塑性共混组合物，特别是与透明聚合物。 橡胶材料的优点在于它们具有低玻璃化转变温度和高折射率。
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2.发明授权Graft copolymers containing (thioaromatic) alkyl acrylate rubber substrates 失效含有（硫代芳族）烷基丙烯酸酯橡胶底物的接枝共聚物
公开(公告)号：US5274044A
公开(公告)日：1993-12-28
申请号：US920695
申请日：1992-07-28
IPC分类号： C07C323/12 , C08F20/38 , C08F265/00 , C08F265/04 , C08F265/06 , C08F273/00 , C08L51/00 , C08L51/06 , C08L69/00 , C08L77/00
CPC分类号： C08F265/04 , C08F273/00
摘要： Compounds of Formula I ##STR1## wherein Z is an aromatic group, each R is individually selected from the group consisting of alkyl groups of from 1 to about 12 carbon atoms, thioalkyl groups of from 1 to about 12 carbon atoms, and halogen atoms, n is from 1 to about 6, and x is from 0 to 7, are suitable for use in preparing rubber latex particles. The rubbers are useful as substrates in graft copolymers and the resulting graft copolymers are suitable for use in thermoplastic blend compositions, particularly with transparent polymers. The rubber materials are advantageous in that they exhibit low glass transition temperatures and high refractive indices.
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3.发明授权High rubber graft thermoplastic composition with improved mechanical properties prepared by melt blending 失效通过熔融共混制备的具有改进的机械性能的高橡胶接枝热塑性组合物
公开(公告)号：US5306771A
公开(公告)日：1994-04-26
申请号：US008042
申请日：1993-01-22
申请人： Michael P. Laughner , Marinus E. J. Dekkers , James J. Scobbo, Jr. , Robert J. Halley , Ronald L. Jalbert
发明人： Michael P. Laughner , Marinus E. J. Dekkers , James J. Scobbo, Jr. , Robert J. Halley , Ronald L. Jalbert
CPC分类号： C08L25/12 , C08L51/06 , C08L23/16 , Y10T428/1352
摘要： High rubber graft thermoplastic compositions are prepared by melt blending an EPDM or an EP rubber and a copolymer derived from a vinyl cyanide compound and a vinyl aromatic compound. Both the copolymer and the rubber are independently either epoxy or carboxy functionalized.
摘要翻译： 通过熔融共混EPDM或EP橡胶和衍生自乙烯基氰化合物和乙烯基芳族化合物的共聚物制备高橡胶接枝热塑性组合物。 共聚物和橡胶都独立地是环氧或羧基官能化的。
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公开(公告)号：US4732938A
公开(公告)日：1988-03-22
申请号：US805644
申请日：1985-12-06
申请人： Thomas S. Grant , Ronald L. Jalbert , David Whalen
发明人： Thomas S. Grant , Ronald L. Jalbert , David Whalen
CPC分类号： C08L71/126 , C08F283/08 , C08G65/485 , C08L77/00
摘要： Compositions comprising a carboxylated PPE resin and a polyamide having good compatibility and impact properties. The carboxylated PPE resin/polyamide alloys are produced by a process wherein a mixture consisting essentially of the PPE resin and a minor amount of an unsaturated carboxylic compound are first melt processed, then compounded with the polyamide.
摘要翻译： 包含羧化PPE树脂和具有良好相容性和冲击性能的聚酰胺的组合物。 羧化的PPE树脂/聚酰胺合金通过以下方法制造，其中基本上由PPE树脂和少量的不饱和羧酸化合物组成的混合物首先被熔融加工，然后与聚酰胺配混。
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公开(公告)号：US5026777A
公开(公告)日：1991-06-25
申请号：US437795
申请日：1989-11-17
摘要： Thermoplastic molding compositions having an inherent matte or low gloss surface finish comprise a polymer blend of a polycarbonate and an emulsion grafted ABS polymer, and a low gloss enhancing amount of a poly(epoxide).
摘要翻译： 具有固有的无光泽或低光泽表面光洁度的热塑性成型组合物包括聚碳酸酯和乳液接枝的ABS聚合物的聚合物共混物和低光泽增加量的聚（环氧化物）。
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公开(公告)号：US5001178A
公开(公告)日：1991-03-19
申请号：US318888
申请日：1989-03-06
申请人： Ronald L. Jalbert , Keith E. Cox
发明人： Ronald L. Jalbert , Keith E. Cox
IPC分类号： C08G59/00 , C08K5/1515 , C08K5/524 , C08L51/04 , C08L55/00 , C08L55/02 , C08L63/00 , C08L67/00 , C08L67/02
CPC分类号： C08L51/04 , C08K5/1515 , C08L67/02
摘要： Thermoplastic blend compositions comprise a crystalline polyalkylene terephthalate, a styrenic polymer component, and a diepoxide. The styrenic polymer component comprises a rigid portion formed from at least one monomer selected from the group consisting of styrene, halogen-substituted styrene, alpha-methyl styrene and para-methyl styrene, and at least one additional ethylenically unsaturated monomer, and a rubber portion including polybutadiene.
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7.发明授权
公开(公告)号：US4491649A
公开(公告)日：1985-01-01
申请号：US556888
申请日：1983-12-01
IPC分类号： C08L21/00 , C08L7/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L69/00 , C08L71/00 , C08L71/12 , C08L77/00 , C08L101/00 , C08L53/00
CPC分类号： C08L71/123 , C08L69/00 , Y10S525/905
摘要： Polyphenylene ether resins impact modified with a rubbery impact modifier such as an ABA block copolymer or a polyolefin is made more processable by further compounding with a moderate amount of an aromatic polycarbonate. The compositions exhibit markedly high impact strength and high heat distortion temperature characteristics.
摘要翻译： 通过与中等量的芳族聚碳酸酯进一步配混，用橡胶状抗冲改性剂如ABA嵌段共聚物或聚烯烃进行冲击改性的聚苯醚树脂更加可加工。 该组合物显示出显着的高冲击强度和高的热变形温度特性。
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公开(公告)号：US4963620A
公开(公告)日：1990-10-16
申请号：US308090
申请日：1989-02-09
申请人： Thomas S. Grant , Ronald L. Jalbert
发明人： Thomas S. Grant , Ronald L. Jalbert
CPC分类号： C08L71/126 , C08L77/00 , Y10S525/905
摘要： Thermoplastic blend compositions comprise a polyphenylene ether resin, a polyamide resin and a compatibilizing agent present in an amount sufficient to effect compatibilization of the polyphenylene ether resin and the polyamide resin. The compatibilizing agent comprises a compound selected from the group consisting of tetracarboxylic acids of aromatic and alicyclic compounds and dianhydride derivatives thereof, and halogen substituted phthalic anhydrides.
摘要翻译： 热塑性共混物组合物包含聚苯醚树脂，聚酰胺树脂和相当剂量，其量足以使聚苯醚树脂和聚酰胺树脂相容化。 相容剂包括选自芳族和脂环族化合物的四羧酸及其二酐衍生物的化合物和卤素取代的邻苯二甲酸酐。
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9.发明授权
公开(公告)号：US4923924A
公开(公告)日：1990-05-08
申请号：US171801
申请日：1988-03-22
IPC分类号： C08F283/08 , C08G65/48 , C08L71/12 , C08L77/00
CPC分类号： C08L71/126 , C08F283/08 , C08G65/485 , C08L77/00
摘要： Thermoplastic blend compositions comprise a polyamide, a carboxylated polyphenylene ether resin and an impact modifier. The carboxylated polyphenylene ether resin is the product of melt mixing a mixture consisting essentially of polyphenylene ether resin and a minor amount of an ethylenically unsaturated carboxylic acid compound. The impact modifier may comprise a graft of a vinyl aromatic polymer on a rubbery substrate; a vinyl aromatic-conjugated diene-vinyl aromatic triblock polymer; a carboxylated vinyl aromatic-conjugated diene-vinyl aromatic triblock polymer; a carboxylated alpha-olefin polymer; a copolymer of an alpha-olefin compound and an unsaturated carboxylic compound; a graft of a rigid acrylic polymer on a rubber substrate; a linear low density polyethylene; or mixtures thereof.
摘要翻译： 热塑性共混组合物包含聚酰胺，羧化聚苯醚树脂和抗冲改性剂。 羧基化聚苯醚树脂是熔融混合基本上由聚苯醚树脂和少量烯属不饱和羧酸化合物组成的混合物的产物。 冲击改性剂可以包括乙烯基芳族聚合物在橡胶基质上的接枝; 乙烯基芳族 - 共轭二烯 - 乙烯基芳族三嵌段聚合物; 羧基乙烯基芳族 - 共轭二烯 - 乙烯基芳族三嵌段聚合物; 羧化α-烯烃聚合物; α-烯烃化合物和不饱和羧酸化合物的共聚物; 刚性丙烯酸聚合物在橡胶基材上的接枝; 线性低密度聚乙烯; 或其混合物。
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公开(公告)号：US4654405A
公开(公告)日：1987-03-31
申请号：US804947
申请日：1985-12-05
申请人： Ronald L. Jalbert , Thomas S. Grant
发明人： Ronald L. Jalbert , Thomas S. Grant
CPC分类号： C08G65/485 , C08L71/126
摘要： Melt-processing a mixture of a polyphenylene ether (PPE) and an ethylenically unsaturated carboxylic compound, in the absence of an added free radical initiator such as a peroxide, serves to introduce carboxyl functionality into the PPE resin. The resulting carboxylated PPE resins are useful in forming alloys with more polar resins such as polyamides.
摘要翻译： 在没有添加的自由基引发剂如过氧化物的情况下，熔融加工聚苯醚（PPE）和烯属不饱和羧酸化合物的混合物用于将羧基官能团引入PPE树脂中。 得到的羧化PPE树脂可用于与更极性树脂如聚酰胺形成合金。
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