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1.发明授权公开(公告)号：US08357751B2
公开(公告)日：2013-01-22
申请号：US12745682
申请日：2008-11-26
IPC分类号： C08L27/12 , C08L31/00 , C08F214/18 , C08F16/24 , B32B27/06
CPC分类号： C08F28/02 , C08F8/44 , C08F220/24 , C08F220/34 , C08F220/38 , C09D133/14 , C09D143/04 , Y10T428/249921 , Y10T428/3154
摘要： A polymer is provided comprising a first pendant group selected from at least one of a perfluorinated ether group or a perfluoroalkanesulfonamido group, a second pendant group comprising an ammonium group, wherein the second pendant group is free of silicon, and a third pendant group comprising an ammonium group and a reactive silicon containing group. A composition comprising the polymer is provided. The polymer and composition are useful for protecting a substrate, for example, to render the substrate oil repellent, water repellent, or both, or to provide stain repellency to the substrate.
摘要翻译： 提供一种聚合物，其包括选自全氟化醚基团或全氟烷基磺酰胺基中的至少一种的第一侧基，包含铵基的第二侧基，其中第二侧基不含硅，第三侧基包含 铵基和含活性硅的基团。 提供了包含聚合物的组合物。 聚合物和组合物可用于保护基材，例如使基材拒油，拒水或两者，或为基材提供防污性。
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2.发明申请公开(公告)号：US20110045271A1
公开(公告)日：2011-02-24
申请号：US12745682
申请日：2008-11-26
IPC分类号： C08L27/12 , C08F214/18 , C08F4/00 , B32B27/06
CPC分类号： C08F28/02 , C08F8/44 , C08F220/24 , C08F220/34 , C08F220/38 , C09D133/14 , C09D143/04 , Y10T428/249921 , Y10T428/3154
摘要： A polymer is provided comprising a first pendant group selected from at least one of a perfluorinated ether group or a perfluoroalkanesulfonamido group, a second pendant group comprising an ammonium group, wherein the second pendant group is free of silicon, and a third pendant group comprising an ammonium group and a reactive siliconcontaining group. A composition comprising the polymer is provided. The polymer and composition are useful for protecting a substrate, for example, to render the substrate oil repellent, water repellent, or both, or to provide stain repellency to the substrate.
摘要翻译： 提供一种聚合物，其包括选自全氟化醚基团或全氟烷基磺酰胺基中的至少一种的第一侧基，包含铵基的第二侧基，其中第二侧基不含硅，第三侧基包含 铵基和反应性含硅基团。 提供了包含聚合物的组合物。 聚合物和组合物可用于保护基材，例如使基材拒油，拒水或两者，或为基材提供防污性。
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3.发明申请Amide-linked Perfluoropolyether Thiol Compounds and Processes for their Preparation and Use 有权酰胺连接的全氟聚醚硫醇化合物及其制备和使用的方法公开(公告)号：US20110237765A1
公开(公告)日：2011-09-29
申请号：US13132673
申请日：2009-12-02
IPC分类号： C08F2/38 , C07C235/10 , C07C235/06 , C07C323/59 , C07C231/12
CPC分类号： C07D303/48 , B05D1/185 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C07C323/41 , C07C323/52 , C07C323/60 , C08F2/38 , C08G65/007 , C08G65/334 , C09D171/02 , G03F7/0002
摘要： A perfluoropolyether thiol compound comprises a perfluoropolyether segment, at least one mercapto group (—SH), and at least one intervening divalent carbonylimino moiety (—C(═O)—NR—, wherein R is hydrogen or alkyl). The compound can be produced, for example, by a ring-opening reaction of thiolactones with perfluoropolyether-substituted, primary or secondary amines. The compound can be used, for example, as a polymerization chain transfer agent, as an intermediate for the preparation of functional group-containing fluorochemical derivatives such as disulfides, and as a fluorinated surface treatment.
摘要翻译： 全氟聚醚硫醇化合物包括全氟聚醚链段，至少一个巯基（-SH）和至少一个插入的二价羰基亚氨基部分（-C（= O）-NR-，其中R是氢或烷基）。 该化合物可以例如通过硫代内酯与全氟聚醚取代的伯或仲胺的开环反应来制备。 该化合物可以用作例如作为制备含二氟化物的含官能团的含氟化合物衍生物的中间体的聚合链转移剂，作为氟化表面处理。
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4.发明授权Amide-linked perfluoropolyether thiol compounds and processes for their preparation and use 有权酰胺连接的全氟聚醚硫醇化合物及其制备和使用的方法公开(公告)号：US08901263B2
公开(公告)日：2014-12-02
申请号：US13132673
申请日：2009-12-02
IPC分类号： C07C323/60
CPC分类号： C07D303/48 , B05D1/185 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C07C323/41 , C07C323/52 , C07C323/60 , C08F2/38 , C08G65/007 , C08G65/334 , C09D171/02 , G03F7/0002
摘要： A perfluoropolyether thiol compound comprises a perfluoropolyether segment, at least one mercapto group (—SH), and at least one intervening divalent carbonylimino moiety (—C(═O)—NR—, wherein R is hydrogen or alkyl). The compound can be produced, for example, by a ring-opening reaction of thiolactones with perfluoropolyether-substituted, primary or secondary amines. The compound can be used, for example, as a polymerization chain transfer agent, as an intermediate for the preparation of functional group-containing fluorochemical derivatives such as disulfides, and as a fluorinated surface treatment.
摘要翻译： 全氟聚醚硫醇化合物包括全氟聚醚链段，至少一个巯基（-SH）和至少一个插入的二价羰基亚氨基部分（-C（= O）-NR-，其中R是氢或烷基）。 该化合物可以例如通过硫代内酯与全氟聚醚取代的伯或仲胺的开环反应来制备。 该化合物可以用作例如作为制备含二氟化物的含官能团的含氟化合物衍生物的中间体的聚合链转移剂，作为氟化表面处理。
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5.发明申请公开(公告)号：US20130264276A1
公开(公告)日：2013-10-10
申请号：US13881895
申请日：2011-12-20
IPC分类号： B01D39/16
CPC分类号： B01D39/163 , B01D39/1623 , B01D39/18 , B01D39/2017 , B01D39/2082 , B01D2239/0428 , B01D2239/0464 , C07B2200/00 , C07F7/1804
摘要： Filter media is treated with a composition comprising cationic fluorinated ether silanes to provide durable water- and/or oil-repellency properties.
摘要翻译： 用包含阳离子氟化醚硅烷的组合物处理过滤介质以提供耐久的水和/或拒油性能。
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公开(公告)号：US20130216820A1
公开(公告)日：2013-08-22
申请号：US13883385
申请日：2011-11-07
申请人： Justin A. Riddle , Naiyong Jing , Erik D. Olson , Karl J. Manske , Richard M. Flynn , Suresh S. Iyer
发明人： Justin A. Riddle , Naiyong Jing , Erik D. Olson , Karl J. Manske , Richard M. Flynn , Suresh S. Iyer
IPC分类号： C09D7/12
CPC分类号： C09D5/00 , C08J7/06 , C09D4/00 , C09D5/002 , C09D7/61 , C09D7/63 , C09D183/08 , C23C16/44 , Y10T428/249974
摘要： Articles having hydrophobic fluorinated coatings are provided. More specifically, the articles include a substrate, a primer layer of acid-sintered silica nanoparticles, and a hydrophobic fluorinated layer. The hydrophobic fluorinated coatings can be used on a large variety of substrate and tend to be quite durable even when subjected to repeated rubbing and/or cleaning.
摘要翻译： 提供具有疏水氟化涂层的制品。 更具体地，制品包括基底，酸烧结二氧化硅纳米颗粒的底漆层和疏水性氟化层。 疏水性氟化涂料可用于各种基材上，并且即使经受反复摩擦和/或清洁也趋于相当耐用。
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公开(公告)号：US20130209814A1
公开(公告)日：2013-08-15
申请号：US13817237
申请日：2011-10-28
IPC分类号： G02B5/08
CPC分类号： G02B5/0808 , B32B7/12 , B32B15/082 , B32B15/20 , B32B27/08 , B32B27/308 , B32B2255/20 , B32B2255/205 , B32B2255/26 , B32B2255/28 , B32B2270/00 , B32B2274/00 , B32B2307/412 , B32B2307/416 , B32B2307/712 , B32B2307/714 , B32B2405/00 , B32B2551/08 , C08J7/04 , C08J2333/12 , G02B1/04 , Y10T428/31699
摘要： Reflective articles and related methods of manufacture are provided. These articles include a metallic layer extending across a non-tacky base layer. The base layer includes either a block copolymer or random copolymer with at least two polymeric components, one of which has a glass transition temperature of at least 50 degrees Celsius and the other of which has a glass transition temperature no greater than 20 degrees Celsius. These articles provide excellent optical clarity, non-corrosiveness, ultraviolet light stability, and resistance to outdoor weathering conditions compared to conventional reflective films.
摘要翻译： 提供了反光制品和相关的制造方法。 这些制品包括穿过非粘性基层延伸的金属层。 基层包括具有至少两种聚合物组分的嵌段共聚物或无规共聚物，其中一种聚合物组分的玻璃化转变温度至少为50摄氏度，另一种玻璃化转变温度不高于20摄氏度。 与常规反射膜相比，这些制品提供优异的光学透明度，非腐蚀性，紫外光稳定性和耐室外耐候性。
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公开(公告)号：US20120289736A1
公开(公告)日：2012-11-15
申请号：US13514322
申请日：2010-12-22
申请人： Yu Yang , Miguel A. Guerra , Richard G. Hansen , David S. Hays , Suresh S. Iyer , Ramesh C. Kumar , George G.I. Moore
发明人： Yu Yang , Miguel A. Guerra , Richard G. Hansen , David S. Hays , Suresh S. Iyer , Ramesh C. Kumar , George G.I. Moore
IPC分类号： C07C229/26 , C07C69/62
CPC分类号： C08G65/007 , C07C231/02 , C08G65/332 , C08G65/3322 , C08G69/40 , C08G69/42 , C07C233/56
摘要： Compounds containing at least one perfluoropolyether segment and at least two oxalylamino groups as well as methods of making these compounds are described. The compounds can be polymeric materials or can be used in the preparation of various copolymeric materials by reaction with compounds having at least two primary or secondary amino groups.
摘要翻译： 描述了含有至少一个全氟聚醚链段和至少两个草酰氨基的化合物以及制备这些化合物的方法。 这些化合物可以是聚合材料，或者可以通过与具有至少两个伯或仲氨基的化合物反应而用于制备各种共聚物。
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9.发明申请OPTICAL DEVICE SURFACE TREATMENT PROCESS AND SMUDGE-RESISTANT ARTICLE PRODUCED THEREBY 审中-公开光学设备表面处理工艺和抗菌品生产公开(公告)号：US20130229378A1
公开(公告)日：2013-09-05
申请号：US13883368
申请日：2011-11-07
申请人： Suresh S. Iyer , Richard M. Flynn , Rama V. Rajagopal , Erik D. Olson , Karl J. Manske , Moses M. David , Jean A. Kelly
发明人： Suresh S. Iyer , Richard M. Flynn , Rama V. Rajagopal , Erik D. Olson , Karl J. Manske , Moses M. David , Jean A. Kelly
IPC分类号： G06F3/041
摘要： A surface treatment process comprises (a) providing at least one optical device; (b) providing a curable surface treatment composition comprising (1) at least one fluorinated organosilane compound comprising (i) a monovalent segment selected from polyfluoroalkyl, polyfluoroether, polyfluoropolyether, and combinations thereof and (ii) a monovalent endgroup comprising at least one silyl moiety comprising at least one group selected from hydrolyzable groups, hydroxyl, and combinations thereof, and (2) at least one fluorinated organosilane compound comprising (i) a multivalent segment selected from polyfluoroalkane, polyfluoroether, polyfluoropolyether, and combinations thereof and (ii) at least two monovalent endgroups, each independently comprising at least one silyl moiety comprising at least one group selected from hydrolyzable groups, hydroxyl, and combinations thereof; (c) applying the curable surface treatment composition to the optical device; and (d) curing the applied, curable surface treatment composition.
摘要翻译： 表面处理方法包括（a）提供至少一个光学装置; （b）提供可固化的表面处理组合物，其包含（1）至少一种氟化有机硅烷化合物，其包含（i）选自多氟烷基，多氟醚，多氟聚醚及其组合的单价链段和（ii）包含至少一个甲硅烷基部分的单价末端基 包括选自可水解基团，羟基及其组合中的至少一个基团，和（2）至少一种氟化有机硅烷化合物，其包含（i）选自多氟烷烃，多氟醚，多氟聚醚及其组合的多价链段和（ii）至少 两个单价端基，各自独立地包含至少一个含有至少一个选自可水解基团，羟基及其组合的基团的甲硅烷基部分; （c）将可固化表面处理组合物施加到光学装置上; 和（d）固化所施加的可固化表面处理组合物。
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公开(公告)号：US08858813B2
公开(公告)日：2014-10-14
申请号：US13130320
申请日：2009-12-02
申请人： Lijun Zu , Matthew H. Frey , Suresh S. Iyer
发明人： Lijun Zu , Matthew H. Frey , Suresh S. Iyer
IPC分类号： C03C15/00 , C07C323/60 , B05D1/18 , B82Y30/00 , B82Y40/00 , C07C323/41 , C07C323/52 , C08G65/00 , C08G65/334 , C09D171/02 , G03F7/00
CPC分类号： C07D303/48 , B05D1/185 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C07C323/41 , C07C323/52 , C07C323/60 , C08F2/38 , C08G65/007 , C08G65/334 , C09D171/02 , G03F7/0002
摘要： A patterning process comprises (a) providing at least one substrate having at least one major surface; (b) providing at least one patterning composition comprising at least one functionalizing molecule that is a perfluoropolyether organosulfur compound; (c) applying the patterning composition to the major surface of the substrate in a manner so as to form at least one functionalized region and at least one unfunctionalized region of the major surface; and (d) etching at least a portion of the unfunctionalized region.
摘要翻译： 图案化工艺包括（a）提供至少一个具有至少一个主表面的衬底; （b）提供至少一种图案化组合物，其包含至少一种作为全氟聚醚有机硫化合物的官能化分子; （c）以使得形成至少一个官能化区域和主表面的至少一个未官能化区域的方式将图案形成组合物施加到基材的主表面; 和（d）蚀刻非官能化区域的至少一部分。
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