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公开(公告)号:US4723026A
公开(公告)日:1988-02-02
申请号:US807512
申请日:1985-11-22
IPC分类号: C08G65/48 , C08F20060101 , C08F2/12 , C08F2/44 , C08F283/06 , C08G20060101 , C08G18/38 , C08G18/50 , C08G18/63 , C08G65/32 , C08G81/00 , C08L20060101 , C08L71/02 , C08L101/00 , C07F7/08 , C07F7/18
CPC分类号: C08G18/5096 , C08G18/636
摘要: A novel family of modified polyols suitable for use in the preparation of fluid polymer/polyols. The modified polyols are the reaction product obtained by reacting a silicon atom containing compound with an unmodified polyol, the silicon atom compound being one which has (a) at least olefinically unsatured hydrocarbyl group and (b) at least one functional group which is reactable with the hydroxy groups on the polyol. Examples of such silicon atom containing compounds include vinyltriethoxysilane and vinyltrimethoxysilane. Modified polyols of the type described are particularly useful in the preparation of polymer/polyols containing high levels of polymer since they reduce the viscosity of the final polymer/polyol and decrease the tendency of the polymer/polyol to produce polymer sediment.
摘要翻译: PCT No.PCT / GB85 / 00176 Sec。 371日期:1985年11月22日 102(e)1985年11月22日PCT PCT公布1985年4月24日PCT公布。 出版物WO85 / 04891 1985年11月7日。一种适用于制备流体聚合物/多元醇的新型改性多元醇系列。 改性多元醇是通过使含硅原子的化合物与未改性的多元醇反应得到的反应产物,硅原子化合物是具有(a)至少烯属不饱和烃基的化合物,和(b)至少一个可与 多元醇上的羟基。 这种含硅原子化合物的实例包括乙烯基三乙氧基硅烷和乙烯基三甲氧基硅烷。 所述类型的改性多元醇特别可用于制备含有高含量聚合物的聚合物/多元醇,因为它们降低了最终聚合物/多元醇的粘度,并降低了聚合物/多元醇产生聚合物沉淀物的倾向。
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公开(公告)号:US4871783A
公开(公告)日:1989-10-03
申请号:US243344
申请日:1988-09-12
IPC分类号: C08G65/44 , C08F20/00 , C08F20/14 , C08F20/44 , C08F283/06 , C08G18/62 , C08G18/63 , C08G65/38
CPC分类号: C08G18/632 , C08F283/06
摘要: Modified polyols having the formula R.sub.m SiXx.sub.4-m wherein m=1 to 3, X is an alkoxy group and at least one R group is either HS--R.sup.1 -- or HS--(SiR.sup.2.sub.2 O).sub.n -- are described. The modified polyols, when mixed with base polyol, are used in the manufacture of graft polymer polyols having low viscosity and good filtrability. The graft polymer polyol can be used in the manufacture of polyurethane foam.
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公开(公告)号:US4831076A
公开(公告)日:1989-05-16
申请号:US726626
申请日:1985-04-24
申请人: Werner A. Lidy , Huy P. Thanh
发明人: Werner A. Lidy , Huy P. Thanh
IPC分类号: C08G65/48 , C08F20060101 , C08F2/12 , C08F2/44 , C08F283/06 , C08G20060101 , C08G18/38 , C08G18/50 , C08G18/63 , C08G65/32 , C08G81/00 , C08L20060101 , C08L71/02 , C08L101/00
CPC分类号: C08G18/5096 , C08G18/636
摘要: A modified polyol, suitable for use as a non-aqueous dispersant in the preparation of polymer/polyols containing high levels of polymer, is provided. The modified polyol comprises the product obtained by reaction of a polyol with a coupling agent having at least two functional groups which are reactable with hydroxyl groups on the polyol. Suitable coupling agents include silicon compounds having two such functional groups, organic compounds having two or more alkoxy groups, saturated dicarboxylic acid derivatives, alkyl or aryl esters of carbonic acid, alkyl or aryl sulphonates, boric acid or its esters and titanates.
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公开(公告)号:US4883832A
公开(公告)日:1989-11-28
申请号:US65777
申请日:1987-06-24
IPC分类号: C08G65/48 , C08F20060101 , C08F2/12 , C08F2/44 , C08F283/06 , C08G20060101 , C08G18/38 , C08G18/50 , C08G18/63 , C08G65/32 , C08G81/00 , C08L20060101 , C08L71/02 , C08L101/00
CPC分类号: C08G18/5096 , C08G18/636
摘要: Fluid polymer/polyol dispersions are prepared from novel polyether polyols.
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公开(公告)号:US5118721A
公开(公告)日:1992-06-02
申请号:US397244
申请日:1989-08-23
申请人: Jose Godoy , Jitka Jenc , Werner A. Lidy
发明人: Jose Godoy , Jitka Jenc , Werner A. Lidy
IPC分类号: C08F283/02 , C08F283/06 , C08F291/08 , C08G18/40 , C08G18/63 , C08J3/20 , C08K5/21 , C08K5/315 , C08K5/3492 , C08K5/55
CPC分类号: C08K5/34922 , C08F291/08 , C08G18/40 , C08G18/409 , C08G18/63 , C08J3/20 , C08K5/21 , C08K5/3155 , C08K5/55
摘要: A process for preparing a dispersion of a filler e.g., melamine, urea or borax in a dispersion or graft polymer polyol is provided. The process comprises (1) dispersing the filler in a suitable basestock (e.g., a polyether polyol) and (2) thereafter using this as the basestock for preparing the dispersion or graft polymer polyol.The polymer which is prepared in dispersed form in the second step may be for example (1) the reaction product of a polyamine, hydrazine or hydrazide and an isocyanate (PHD polymer) or (2) the reaction product of an olamine and an isocyanate (PIPA polymer). Alternatively styrene and acrylonitrile can be graft polymerised in the basestock in step (2). The new dispersion or graft polymer polyols containing dispersed filler are useful in the manufacture of fire resistant polyurethane foam for e.g., furniture applications.
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公开(公告)号:US4912260A
公开(公告)日:1990-03-27
申请号:US170827
申请日:1988-03-21
申请人: Ian D. Dobson , Werner A. Lidy , Peter S. Williams
发明人: Ian D. Dobson , Werner A. Lidy , Peter S. Williams
IPC分类号: B01J23/89 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/16 , C07C209/24 , C07C209/26 , C07C209/48 , C07C211/06
CPC分类号: C07C209/16 , C07C209/26
摘要: Amines are produced by reacting at elevated temperature a first reactant which is either an alcohol, an aldehyde or a ketone with a second reactant which is either ammonia, a primary or secondary amine or a nitrile in the presence as catalyst of a composition comprising (i) nickel, (ii) ruthenium, and (iii) at least one other transition metal selected from either the second or third row transition metals, for example palladium, rhenium or iridium.
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公开(公告)号:US4596653A
公开(公告)日:1986-06-24
申请号:US661711
申请日:1984-10-17
CPC分类号: C08G77/46 , B01D17/047 , C10G33/04
摘要: Emulsions of oil and water are broken by treating them with a demulsifier which is a polysiloxane polyalkylene oxide copolymer in which the polyalkylene oxide segment is composed of random ethylene oxide and propylene oxide units.The demulsifier is particularly useful in breaking emulsions of water in crude oil which are normally difficult to separate and in breaking emulsions at relatively low temperatures, e.g. 30.degree. to 45.degree. C.
摘要翻译: 油和水的乳液通过用聚硅氧烷聚环氧烷共聚物的破乳剂处理而破坏,其中聚环氧烷链段由无规环氧乙烷和环氧丙烷单元组成。 破乳剂特别可用于破碎原油中的水的乳液,其通常难于分离,并在相对低的温度下破乳。 30〜45℃
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公开(公告)号:US5155142A
公开(公告)日:1992-10-13
申请号:US413322
申请日:1989-09-27
申请人: Werner A. Lidy
发明人: Werner A. Lidy
CPC分类号: C08G18/3225 , C08G18/089 , C08G18/1875 , C08G18/5024 , C08G18/6204 , C08G2101/0083
摘要: A process for preparing polyurea or polyurethane/urea foams from a polyamine or aminated polyether polyol is provided. The process comprises reacting the above component with a polyisocyanate (e.g. TDI, MDI etc.), a blowing agent (e.g. water) and a carboxylic acid or carboxylate acid salt. The function of the carboxylic acid or carboxylic acid salt is to slow down the reaction between the amine and the isocyanate so that effective foaming can take place before the reaction is completed.
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公开(公告)号:US4843106A
公开(公告)日:1989-06-27
申请号:US193283
申请日:1988-05-09
IPC分类号: C08J9/04 , C08F283/06 , C08G18/63 , C08K3/00 , C08K5/00 , C08K5/49 , C08L51/06 , C08L51/08 , C08L75/00 , C08L75/04
CPC分类号: C08K5/0066 , C08G18/63 , C08K5/49 , Y10S521/906
摘要: Fluid polymer polyol dispersions which impart improved fire resistance to polyurethane foam. The fluid polymer polyol dispersions are prepared by grafting one or more monomers onto a polyol backbone with the difference that the grafting takes place in the presence of a flame retardant. During the grafting process the flame retardant is incorporated into the fluid polymer polyol dispersion. When such fluid polymer polyol dispersions are used, the fire resistance of the final polyurethane foam is improved relative to cases where a conventional fluid polymer polyol dispersion and a flame retardant are added separately to the polyurethane foam formulation.
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公开(公告)号:US4571413A
公开(公告)日:1986-02-18
申请号:US701097
申请日:1985-02-12
申请人: John G. Dolden , Sidney G. Fogg , Werner A. Lidy
发明人: John G. Dolden , Sidney G. Fogg , Werner A. Lidy
CPC分类号: C08L61/06
摘要: A curable phenolic resin composition comprising (A) a major proportion of an aqueous phenolic resole resin and (B) a minor proportion of a poly(1,2-alkylene oxide) having terminating groups selected from the group comprising --NH.sub.2, --CONH.sub.2, --CH.CO.NH.sub.2 and --OCONH.sub.2 groups. The compositions are preferably cured with an acid catalyst and post cured at an elevated temperature.
摘要翻译: 一种可固化的酚醛树脂组合物,其包含(A)主要比例的酚醛树脂水溶液树脂和(B)少量的具有选自-NH 2,-CONH 2, -CH.CO.NH 2和-OCONH 2基团。 组合物优选用酸催化剂固化并在升高的温度下固化。
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