Process for copolymerizing ethylene with vinylsilanes
    1.
    发明授权
    Process for copolymerizing ethylene with vinylsilanes 有权
    乙烯与乙烯基硅烷共聚的方法

    公开(公告)号:US06936671B2

    公开(公告)日:2005-08-30

    申请号:US10681657

    申请日:2003-10-08

    CPC classification number: C08F210/02 C08F230/08 C08F4/6367 C08F2500/20

    Abstract: A process for copolymerizing ethylene with vinylsilanes is disclosed. The process uses a Ziegler-Natta catalyst and cocatalyst wherein the Ziegler-Natta catalyst is prepared from a Group 4-6 halogen-containing transition metal and a mixture of an organomagnesium compound and a silicon-containing compound. Silane-functionalized polyolefins produced using the process can be crosslinkable and can be used to bond polyolefins to polysiloxanes or other functionalized polymers.

    Abstract translation: 公开了一种使乙烯与乙烯基硅烷共聚的方法。 该方法使用齐格勒 - 纳塔催化剂和助催化剂,其中齐格勒 - 纳塔催化剂由含4-6族含卤素的过渡金属和有机镁化合物与含硅化合物的混合物制备。 使用该方法制备的硅烷官能化聚烯烃可以是可交联的,并且可以用于将聚烯烃与聚硅氧烷或其它官能化聚合物结合。

    Preparing multimodal polyethylene having controlled long chain branching distribution
    5.
    发明申请
    Preparing multimodal polyethylene having controlled long chain branching distribution 审中-公开
    制备具有受控长支链分布的多峰聚乙烯

    公开(公告)号:US20090048402A1

    公开(公告)日:2009-02-19

    申请号:US11894016

    申请日:2007-08-17

    Abstract: A process to prepare a multimodal polyethylene with controlled LCB distribution is disclosed. In the first stage, ethylene is polymerized in the presence of a Ziegler catalyst that results in a homopolyethylene component having a higher LCB concentration. In the second stage, ethylene is copolymerized with a 1-olefin in the presence of the Ziegler catalyst and a lower concentration of hydrogen resulting in a copolymer component with a lower LCB concentration. The homopolyethylene component and the copolymer component are combined to form a novel multimodal polyethylene.

    Abstract translation: 公开了制备具有受控LCB分布的多峰聚乙烯的方法。 在第一阶段中,乙烯在齐格勒催化剂存在下聚合,导致具有较高LCB浓度的均聚乙烯组分。 在第二阶段中,乙烯在齐格勒催化剂存在下与1-烯烃共聚,较低浓度的氢气导致具有较低LCB浓度的共聚物组分。 将均聚乙烯组分和共聚物组分合并形成新的多峰聚乙烯。

    Propylene polymerization process with enhanced catalyst activity
    6.
    发明授权
    Propylene polymerization process with enhanced catalyst activity 失效
    丙烯聚合方法具有增强的催化剂活性

    公开(公告)号:US06630544B1

    公开(公告)日:2003-10-07

    申请号:US10125757

    申请日:2002-04-18

    CPC classification number: C08F10/06 C08F110/06 C08F2/00

    Abstract: A process for polymerizing propylene is disclosed. The process involves charging propylene and about 90 to 99% of an organoaluminum cocatalyst to a reactor and heating this mixture to at least about 50° C. This is followed by addition of a premix of 1 to 10% of the organoaluminum cocatalyst with a magnesium halide-supported Ziegler-Natta catalyst. The temperature of the reaction mixture is maintained to produce a propylene polymer. The process gives improved catalyst activity.

    Abstract translation: 公开了一种聚合丙烯的方法。 该方法包括将丙烯和约90至99%的有机铝助催化剂装入反应器中,并将该混合物加热至至少约50℃。随后加入1至10%的有机铝助催化剂与镁 卤化物载体的齐格勒 - 纳塔催化剂。 保持反应混合物的温度以产生丙烯聚合物。 该方法提供了改进的催化剂活性。

    Process for making ethylene homopolymers
    8.
    发明授权
    Process for making ethylene homopolymers 有权
    制备乙烯均聚物的方法

    公开(公告)号:US08202952B2

    公开(公告)日:2012-06-19

    申请号:US12313576

    申请日:2008-11-21

    Abstract: A process for making an ethylene homopolymer in the presence of an oxide-supported chromium catalyst is disclosed. A small amount of an α-olefin contacted with the catalyst before polymerizing ethylene or introduced into an ethylene homopolymerization unexpectedly boosts process productivity. When used at part per million levels, the α-olefin improves productivity while maintaining desirable polymer properties. The invention is particularly valuable for making HDPE resins useful for blow molding applications.

    Abstract translation: 公开了一种在氧化物负载的铬催化剂存在下制备乙烯均聚物的方法。 在聚合乙烯或引入乙烯均聚物之前,与催化剂接触的少量α-烯烃意外地提高了工艺生产率。 当以百万分之一的水平使用时,α-烯烃可以提高生产率,同时保持所需的聚合物性能。 本发明对于制备用于吹塑应用的HDPE树脂是特别有价值的。

    Shear modification of polyolefin-clay nanocomposites
    10.
    发明授权
    Shear modification of polyolefin-clay nanocomposites 有权
    聚烯烃 - 粘土纳米复合材料的剪切改性

    公开(公告)号:US07183348B2

    公开(公告)日:2007-02-27

    申请号:US11034493

    申请日:2005-01-13

    CPC classification number: C08K3/346 C08L23/02

    Abstract: A method for modifying polyolefin-clay nanocomposites is disclosed. The method comprises shearing a melt of solution-prepared nanocomposites at an effective shear rate. The modified nanocomposite shows significantly decreased complex melt viscosity, storage modulus, and loss modulus.

    Abstract translation: 公开了一种改性聚烯烃 - 粘土纳米复合材料的方法。 该方法包括以有效剪切速率剪切溶液制备的纳米复合材料的熔体。 改性纳米复合材料显示出显着降低的复合熔体粘度,储能模量和损耗模量。

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