摘要:
A process for the production of olefins which comprises passing an oxygenate-containing feedstock over a zeo type catalyst at a temperature greater than 200.degree. C. characterized in that the oxygenate-containing feedstock comprises C.sub.3 and/or C.sub.4 olefins and as oxygenate methanol formaldehyde and/or dimethylether, the molar ratio of olefin to oxygenate being greater than 1:20 and the zeo type catalyst being of TON-type structure.
摘要:
A catalyst which comprises zinc, together with an effective amount of a platinum group metal on a support which is a material having the silicalite structure, the framework of said material consisting essentially of silicon and oxygen atoms or of silicon, zinc and oxygen atoms. There is also provided a process for the dehydrogenation of a C.sub.2 to C.sub.10 paraffin to yield an alkene product which process comprises contacting the paraffin under dehydrogenation conditions with a catalyst according to the invention.
摘要:
A catalyst which is substantially free of alkali and alkaline earth metals and comprises an effective amount of a platinum group metal on a silicalite support; characterised in that the catalyst also comprises tin. There is also provided a process for the dehydrogenation of a C.sub.2 to C.sub.10 paraffin to yield an alkene product, which comprises contacting the paraffin under dehydrogenation conditions with a catalyst according to the invention.
摘要:
Novel membranes comprise crystals of a zeo-type material carried by a porous support. The crystal growth of the zeo-type material is essentially continuous over the pores of the support and the zeo-type material is crystallized directly from and bonds directly to the support. Membranes may be prepared by immersing the support in a synthesis gel, crystallizing the gel, removing the support, and repeating these steps at least once.
摘要:
A crystalline material having, in the dehydrated form, the empirical formula:m(M.sub.2/a O):X.sub.z O.sub.xz/2 :.sub.y YO.sub.2 (I)in which m is 0.5 to 1.5; M is a cation of valency a; X is a metal of valency x, selected from aluminium, boron, gallium, zinc, iron and titanium; z is 2 when x is an odd number, and z is 1 when x is an even number; y is at least 5; and Y is silicon or germanium; and having, in the calcined hydrogen form, an X-ray diffraction pattern including significant peaks substantially as shown in Table I herein. The material has been designated SUZ-2, and is used in the conversion of hydrocarbons or oxygenates.
摘要:
Novel membranes comprise crystals of a zeo-type material carried by a porous support. The crystal growth of the zeo-type material is essentially continuous over the pores of the support and the zeo-type material is crystallized directly from and bonds directly to the support. Membranes may be prepared by immersing the support in a synthesis gel, crystallizing the gel, removing the support, and repeating these steps at least once.
摘要:
This invention relates to a process for restructuring an olefinic feedstock rich in linear olefins into a product olefin of narrower composition which is richer in branched olefins than the starting feedstock. Such restructuring is achieved by contacting the feedstock with an unmodified or partially modified tectometallosilicate of the Theta-1 type at relatively low temperatures. The product olefins are valuable as petrochemical feedstock for producing polyolefins, alcohols, ethers and other oxygenates, surfactants, alkyl aromatics and oligomers useful as gasoline blending components.
摘要:
This invention relates to a process for selective dealumination, particularly surface dealumination of zeolites by sequential ion-exchange and calcination. The process is selective in the sense that the aluminium atoms within the pore structure of the zeolite remain virtually intact.The surface dealuminated zeolites can be used, after loading with a gallium compound, as catalysts in hydrocarbon conversion reactions.
摘要:
A process for the dimerization of at least one olefin with a carbon number between 2 and 10 by contacting the feed with a catalyst system comprising at least: (a) tectometallosilicate zeolite with having TON-type structure, (b) tectometallosilicate zeolite with having MTT-type structure, (c) tectometallosilicate zeolite with the same structure as that of the ZSM-48 zeolite, or (d) silicoaluminophosphate (SAPO) zeo-type with AEL-type structure; under dimerization condition to produce highly branched olefins.
摘要:
Novel membranes comprise crystals of a zeo-type material carried by a porous support. The crystal growth of the zeo-type material is essentially continuous over the pores of the support and the zeo-type material is crystallized directly from and bonds directly to the support. Membranes may be prepared by immersing the support in a synthesis gel, crystallizing the gel, removing the support, and repeating these steps at least once.