Ultrafine porous graphitic carbon fiber and preparation method thereof
    1.
    发明申请
    Ultrafine porous graphitic carbon fiber and preparation method thereof 有权
    超细多孔石墨碳纤维及其制备方法

    公开(公告)号:US20070134151A1

    公开(公告)日:2007-06-14

    申请号:US11607520

    申请日:2006-12-01

    IPC分类号: C01B31/04 D01F9/12

    摘要: The present invention discloses an ultrafine graphitic carbon fiber and a preparation method thereof. An ultrafine fiber having a diameter of 1 to 3000 nm is prepared by electrospinning a halogenated polymer solution containing a metal compound inducing graphitization. In carbonization, an ultrafine porous graphitic carbon fiber having a large specific surface area, micropores and macropores is prepared by the graphitization by a metal catalyst generated from the metal compound. The ultrafine carbon fiber can be used as a carbon material for storing hydrogen, an adsorbing material of biochemically noxious substances, an electrode material of a supercapacitor, a secondary cell and a fuel cell, and a catalyst carrier material.

    摘要翻译: 本发明公开了一种超细石墨碳纤维及其制备方法。 通过静电纺丝含有引起石墨化的金属化合物的卤化聚合物溶液制备直径为1至3000nm的超细纤维。 在碳化中,通过由金属化合物生成的金属催化剂的石墨化制备具有大比表面积的超细多孔石墨碳纤维,微孔和大孔。 超细碳纤维可以用作储存氢的碳材料,生化有害物质的吸附材料,超级电容器的电极材料,二次电池和燃料电池以及催化剂载体材料。

    Ultrafine porous graphitic carbon fiber and preparation method thereof
    2.
    发明授权
    Ultrafine porous graphitic carbon fiber and preparation method thereof 有权
    超细多孔石墨碳纤维及其制备方法

    公开(公告)号:US07887772B2

    公开(公告)日:2011-02-15

    申请号:US11607520

    申请日:2006-12-01

    IPC分类号: D01F9/12

    摘要: The present invention discloses an ultrafine graphitic carbon fiber and a preparation method thereof. An ultrafine fiber having a diameter of 1 to 3000 nm is prepared by electrospinning a halogenated polymer solution containing a metal compound inducing graphitization. In carbonization, an ultrafine porous graphitic carbon fiber having a large specific surface area, micropores and macropores is prepared by the graphitization by a metal catalyst generated from the metal compound. The ultrafine carbon fiber can be used as a carbon material for storing hydrogen, an adsorbing material of biochemically noxious substances, an electrode material of a supercapacitor, a secondary cell and a fuel cell, and a catalyst carrier material.

    摘要翻译: 本发明公开了一种超细石墨碳纤维及其制备方法。 通过静电纺丝含有引起石墨化的金属化合物的卤化聚合物溶液制备直径为1至3000nm的超细纤维。 在碳化中,通过由金属化合物生成的金属催化剂的石墨化制备具有大比表面积的超细多孔石墨碳纤维,微孔和大孔。 超细碳纤维可以用作储存氢的碳材料,生化有害物质的吸附材料,超级电容器的电极材料,二次电池和燃料电池以及催化剂载体材料。

    Metal oxide supercapacitor having metal oxide electrode coated onto titanium dioxide ultrafine fiber and method for preparing the same
    4.
    发明授权
    Metal oxide supercapacitor having metal oxide electrode coated onto titanium dioxide ultrafine fiber and method for preparing the same 失效
    具有涂覆在二氧化钛超细纤维上的金属氧化物电极的金属氧化物超级电容及其制备方法

    公开(公告)号:US07670467B2

    公开(公告)日:2010-03-02

    申请号:US11556007

    申请日:2006-11-02

    摘要: A supercapacitor having a metal oxide electrode and a method for preparing the same. The method comprises preparing a substrate composed of a current collector and a titanium dioxide ultrafine fiber matrix layer formed on the current collector, and electrochemically depositing a metal oxide thin film layer onto the substrate by a constant current potentiometry or a cyclic voltammetric method. Since the metal oxide is uniformly deposited on the substrate having a wide specific surface area with the titanium dioxide ultrafine fiber, a bonding material or a conductive particle need not to be added to the capacitor electrode. Therefore, a resistance of the capacitor electrode is prevented from being increased, and thus a capacitance of the capacitor electrode is prevented from being decreased.

    摘要翻译: 具有金属氧化物电极的超级电容器及其制备方法。 该方法包括制备由集电体构成的基板和形成在集电体上的二氧化钛超细纤维矩阵层,并通过恒定电流电位法或循环伏安法将金属氧化物薄膜层电化学沉积到基板上。 由于金属氧化物通过二氧化钛超细纤维均匀地沉积在具有宽比表面积的基板上,所以不需要在电容器电极上添加接合材料或导电颗粒。 因此,防止电容器电极的电阻增加,从而防止电容器电极的电容减小。

    Heat resisting ultrafine fibrous separator and secondary battery using the same
    5.
    发明授权
    Heat resisting ultrafine fibrous separator and secondary battery using the same 有权
    耐热超细纤维分离器和使用其的二次电池

    公开(公告)号:US08815432B2

    公开(公告)日:2014-08-26

    申请号:US12376511

    申请日:2006-12-08

    IPC分类号: H01M2/16

    摘要: A heat-resisting ultrafine fibrous separator of the present invention is prepared by an electrospinning process, formed of ultrafine fibers of heat-resisting polymer resin having a melting point more than 1800 C or not having the melting point, or ultrafine fibers of polymer resin capable of swelling in an electrolyte, together with the ultrafine fibers of heat-resisting polymer resin. Also, polyolefine fine particles providing a shutdown function are dispersed in the heat-resisting resin or the polymer resin capable of swelling in the electrolyte. The heat-resisting ultrafine fibrous separator of the present invention has the shutdown function, low thermal contraction, thermal endurance, excellent ionic conductivity and excellent adhesive property with an electrode, so a battery having excellent cycling characteristics, and having high-energy density and high capacity can be prepared.

    摘要翻译: 本发明的耐热超细纤维隔膜是通过静电纺丝法制备的,该方法由熔点高于1800℃或不具有熔点的耐热聚合物树脂的超细纤维或聚合物树脂的超细纤维制成 在电解质中膨胀,以及耐热聚合物树脂的超细纤维。 此外,提供关闭功能的聚烯烃微粒分散在耐热树脂或能够在电解质中膨胀的聚合物树脂中。 本发明的耐热超细纤维隔膜具有关闭功能,低热收缩,耐热性,优异的离子导电性和优异的电极粘合性,因此具有优异的循环特性,并且具有高能量密度和高 能力可以准备。

    HEAT RESISTING ULTRAFINE FIBROUS SEPARATOR AND SECONDARY BATTERY USING THE SAME
    6.
    发明申请
    HEAT RESISTING ULTRAFINE FIBROUS SEPARATOR AND SECONDARY BATTERY USING THE SAME 有权
    热电偶极纤维分离器和使用相同的二次电池

    公开(公告)号:US20100233523A1

    公开(公告)日:2010-09-16

    申请号:US12376511

    申请日:2006-12-08

    摘要: A heat-resisting ultrafine fibrous separator of the present invention is prepared by an electrospinning process, formed of ultrafine fibers of heat-resisting polymer resin having a melting point more than 1800 C or not having the melting point, or ultrafine fibers of polymer resin capable of swelling in an electrolyte, together with the ultrafine fibers of heat-resisting polymer resin. Also, polyolefine fine particles providing a shutdown function are dispersed in the heat-resisting resin or the polymer resin capable of swelling in the electrolyte. The heat-resisting ultrafine fibrous separator of the present invention has the shutdown function, low thermal contraction, thermal endurance, excellent ionic conductivity and excellent adhesive property with an electrode, so a battery having excellent cycling characteristics, and having high-energy density and high capacity can be prepared.

    摘要翻译: 本发明的耐热超细纤维隔膜是通过静电纺丝法制备的,该方法由熔点大于1800℃或不具有熔点的耐热聚合物树脂的超细纤维或聚合物树脂的超细纤维形成 在电解质中膨胀,以及耐热聚合物树脂的超细纤维。 此外,提供关闭功能的聚烯烃微粒分散在耐热树脂或能够在电解质中膨胀的聚合物树脂中。 本发明的耐热超细纤维隔膜具有关闭功能,低热收缩,耐热性,优异的离子导电性和优异的电极粘合性,因此具有优异的循环特性,并且具有高能量密度和高 能力可以准备。

    HEAT RESISTING SEPARATOR HAVING ULTRAFINE FIBROUS LAYER AND SECONDARY BATTERY HAVING THE SAME
    7.
    发明申请
    HEAT RESISTING SEPARATOR HAVING ULTRAFINE FIBROUS LAYER AND SECONDARY BATTERY HAVING THE SAME 审中-公开
    具有超滤层的隔热隔离层及具有该层的二次电池

    公开(公告)号:US20100304205A1

    公开(公告)日:2010-12-02

    申请号:US12376516

    申请日:2006-12-08

    IPC分类号: H01M2/18

    摘要: A polyolefin separator having an heat-resistant ultrafine fibrous layer and a secondary battery using the same, in which the separator has a shutdown function, low thermal contraction characteristics, thermal endurance, excellent ionic conductivity, excellent cycling characteristics at the time of battery construction, and excellent adhesion with an electrode. The present N invention adopts a very simple and easy process to form an ultrafine fibrous layer through an electrospinning process, and at the same time, to remove solvent and to form pores. Accordingly, the separator of the present invention is useful particularly for electrochemical devices used in a hybrid electric automobile, an electric automobile, and a fuel cell automobile, requiring high thermal endurance and thermal stability.

    摘要翻译: 具有耐热超细纤维层的聚烯烃隔膜和使用其的二次电池,其中隔膜具有关闭功能,低热收缩特性,耐热性,优异的离子导电性,电池构造时的优异的循环特性, 和与电极的优异粘合性。 本发明采用非常简单和简单的方法,通过静电纺丝方法形成超细纤维层,同时除去溶剂并形成孔。 因此,本发明的隔膜特别适用于需要高耐热性和热稳定性的混合电动汽车,电动汽车和燃料电池汽车中使用的电化学装置。

    GAS SENSOR USING METAL OXIDE NANOPARTICLES, AND METHOD FOR MANUFACTURING SAME
    8.
    发明申请
    GAS SENSOR USING METAL OXIDE NANOPARTICLES, AND METHOD FOR MANUFACTURING SAME 有权
    使用金属氧化物纳米颗粒的气体传感器及其制造方法

    公开(公告)号:US20120042713A1

    公开(公告)日:2012-02-23

    申请号:US13266815

    申请日:2010-04-30

    IPC分类号: G01N27/12 B05D1/04 B05D5/12

    摘要: The present invention provides a gas sensor, including: a sensor substrate provided with an electrode; and a thin layer of sensor material formed by spraying a solution in which metal oxide nanoparticles are dispersed onto the sensor substrate. The gas sensor is advantageous in that a sensor material is formed into a porous thin layer containing metal oxide nanoparticles having a large specific surface area, thus realizing high sensitivity on the ppb scale and a high reaction rate. Further, the gas sensor is advantageous in that it can be manufactured at room temperature, and the thickness of a sensor material can be easily adjusted by adjusting the spray time, so that a thin gas sensor or a thick gas sensor can be easily manufactured.

    摘要翻译: 本发明提供一种气体传感器,包括:具有电极的传感器基板; 以及通过将金属氧化物纳米粒子分散在传感器基板上的溶液喷雾形成的薄层传感器材料。 气体传感器的优点在于,传感器材料形成为具有大比表面积的金属氧化物纳米粒子的多孔薄层,因此在ppb量程上实现高灵敏度和高反应速率。 此外,气体传感器的优点在于其可以在室温下制造,并且通过调节喷射时间可以容易地调节传感器材料的厚度,从而可以容易地制造薄气体传感器或厚气体传感器。