摘要:
In an electrochemical cell using a conventional thermally resistant container, there is a problem in that, when it is used at a relatively high voltage, for example, around 3 V, a metal of a collector is dissolved and characteristics thereof are extremely deteriorated. In order to prevent a positive electrode current collector from being dissolved even at a high potential, a surface of the positive electrode current collector is covered by a valve metal or carbon such that the positive electrode current collector and a positive electrode do not come in contact with each other. Therefore, in the electrochemical cell according to the invention, the positive electrode current collector is prevented from being dissolved.
摘要:
An electrochemical cell has a container containing a positive electrode, a negative electrode, and an electrolyte. The container has a bottom face and a hole formed in the bottom face. A positive electrode current collector is embedded in the bottom face of the container so that the hole formed in the bottom face exposes a portion of the positive electrode current collector. A covering portion is adhered to the positive electrode and covers the exposed portion of the positive electrode current collector. The positive electrode current collector is electrically connected to the positive electrode via the covering portion. A lid seals the container.
摘要:
An electrochemical cell has an outer case formed of one of ceramics and glass. An electrochemical cell element is hermetically sealed in the outer case. The electrochemical cell element contains a positive pole, a negative pole, and a non-aqueous electrolyte containing an organic solvent. A metal layer is formed on an edge of the outer case. A sealing plate is resistance welded to the metal layer. The sealing plate is made of an alloy containing, in weight percentage, Co by 1 to 50%, Ni by 1 to 70%, Fe by 20% or higher, Cr by 10% or lower, Mn by 2.0% or lower, Si by 1.0% or lower and C by 1.0% or lower.
摘要:
An electrochemical cell has a container having a main surface and a cavity containing therein a positive electrode, a negative electrode, a separator separating the positive and negative electrodes from one another, and an electrolyte. A sealing plate that seals the cavity of the container is bonded to the main surface of the container with an unoxidized weld.
摘要:
In a conventional electrochemical cell, since a welding between a container and a sealing plate is performed in the atmospheric air, a weld zone is oxidized and a corrosion resistance decreases. For this reason, impurities are eluted from the weld zone into an electrolyte, and this causes an internal resistance increase and a capacity decrease of the electrochemical cell. Further, there is a possibility that an organic solvent in the electrolyte is oxidized by the welding. According to the invention, in order to solve the above problems, the seal welding between the container and the sealing plate of the electrochemical cell is performed under an inert atmosphere.
摘要:
A 1.5 V non-aqueous electrolyte secondary battery having high energy density, excellent charge and discharge characteristics and long cycle life is provided. The non-aqueous electrolyte secondary battery uses, as the negative electrode active material, lithium-containing silicon oxide represented by the compositional formula Li.sub.x SiO.sub.y and defined such that the lithium content x and oxygen amount y are satisfied with 1.5.ltoreq.x.ltoreq.4.5 and 0
摘要:
In an electrochemical cell in which a container is bonded to a cap, observation of liquid leakage has been needed in directions from four sides of the container, therefore much time and high cost have been required. The outer circumference of the cap is made to be smaller than that of the container, whereby surfaces for observing liquid leakage can be made to be only one surface in a direction from an upside of the cap, consequently an electrochemical cell can be provided at low cost.
摘要:
A non-aqueous electrolyte secondary battery has a negative electrode, a positive electrode and a non-aqueous electrolyte with lithium ion conductivity. A composite oxide produced from a metal or a metalloid and lithium represented by composition formula Li.sub.x MO (where M represents metals or metalloids other than alkali metals, and x satisifies 0.ltoreq.x) is used as an active material of one or both of the negative electrode and the positive electrode. The battery exhibits a large charging/discharging capacity and a high energy density together with smaller polarization (internal resistance) on charging and discharging which facilitates a large current charging and discharging with a long cycle life and reduces deterioration due to excess charging and excess discharging.
摘要:
A non-aqueous electrolyte secondary battery has a negative electrode, a positive electrode and a non-aqueous electrolyte with lithium ion conductivity. A composite oxide containing lithium represented by composition formula Li.sub.x Si.sub.1-y M.sub.y O.sub.z (where M is one or more kinds of elements selected from metals other than alkaline metals, and metalloids other than silicon, and x, y and z satisfy O.ltoreq.x, 0
摘要翻译:非水电解质二次电池具有负极,正极和具有锂离子传导性的非水电解质。 含有由组成式LixSi1-yMyOz表示的锂的复合氧化物(其中M是选自除碱金属以外的金属中的一种或多种元素,除硅以外的准金属,x,y和z满足O X = 0
摘要:
A nonaqueous electrolyte secondary battery uses lithium or a substance capable of absorbing and releasing lithium as a negative active material of a negative electrode, and uses a layer-like composite oxide of the formula Li.sub.x M.sub.y L.sub.z O.sub.2, where M is one or more transistion metal elements selected from Groups IIIB, IVB, VB, VIB, VIIB and VIII of the periodic table, L is one or more elements selected from nonmetal, metalloid and semimetal elements selected from Groups IIIA, IVA and VA of the periodic table, alkaline earth metal elements and metal elements of Zn and Cu as a positive active material constituting a positive electrode. The polarization (internal resistance) at the time of charging and discharging is reduced and an effective charging-discharging capacity is enhanced. Charging and discharging at a large current become easy, and a cycle deterioration is improved.