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公开(公告)号：US20130025757A1
公开(公告)日：2013-01-31
申请号：US13639337
申请日：2011-05-17
申请人： Shusaku Tomoi , Koichi Kawaguchi
发明人： Shusaku Tomoi , Koichi Kawaguchi
CPC分类号： C08L77/00 , B60C1/0008 , C08L23/283 , Y10T152/10495 , C08L29/04 , C08L29/06 , C08L23/0861
摘要： Provided is a thermoplastic elastomer composition that can be suitably used for the inner liners of pneumatic tires and exhibits high air barrier properties and high fatigue durability. The present invention is a thermoplastic elastomer composition comprising a thermoplastic resin composition and a rubber composition dispersed in the thermoplastic resin composition, wherein the thermoplastic resin composition comprises a polyamide and an ethylene-vinyl alcohol copolymer or a poly(vinyl alcohol), the rubber composition comprises a halogenated isoolefin-p-alkylstyrene copolymer and is cross inked. The thermoplastic resin composition preferably comprises 1 to 25% by weight of the ethylene-vinyl alcohol copolymer or the poly(vinyl alcohol). The thermoplastic elastomer composition preferably comprises 100 parts by weight of the thermoplastic resin composition and 80 to 200 parts by weight of the halogenated isoolefin-p-alkylstyrene copolymer.
摘要翻译： 提供一种热塑性弹性体组合物，其可以适用于充气轮胎的内衬，并且具有高空气阻隔性和高疲劳耐久性。 本发明是一种热塑性弹性体组合物，其包含热塑性树脂组合物和分散在热塑性树脂组合物中的橡胶组合物，其中热塑性树脂组合物包含聚酰胺和乙烯 - 乙烯醇共聚物或聚（乙烯醇），橡胶组合物 包括卤代异烯烃 - 对 - 烷基苯乙烯共聚物，并且是交联的。 热塑性树脂组合物优选包含1至25重量％的乙烯 - 乙烯醇共聚物或聚（乙烯醇）。 热塑性弹性体组合物优选包含100重量份的热塑性树脂组合物和80-200重量份的卤代异烯烃 - 对烷基苯乙烯共聚物。
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公开(公告)号：US08940835B2
公开(公告)日：2015-01-27
申请号：US13639337
申请日：2011-05-17
申请人： Shusaku Tomoi , Koichi Kawaguchi
发明人： Shusaku Tomoi , Koichi Kawaguchi
CPC分类号： C08L77/00 , B60C1/0008 , C08L23/283 , Y10T152/10495 , C08L29/04 , C08L29/06 , C08L23/0861
摘要： Provided is a thermoplastic elastomer composition that can be suitably used for the inner liners of pneumatic tires and exhibits high air barrier properties and high fatigue durability. The present invention is a thermoplastic elastomer composition comprising a thermoplastic resin composition and a rubber composition dispersed in the thermoplastic resin composition, wherein the thermoplastic resin composition comprises a polyamide and an ethylene-vinyl alcohol copolymer or a poly(vinyl alcohol), the rubber composition comprises a halogenated isoolefin-p-alkylstyrene copolymer and is cross inked. The thermoplastic resin composition preferably comprises 1 to 25% by weight of the ethylene-vinyl alcohol copolymer or the poly(vinyl alcohol). The thermoplastic elastomer composition preferably comprises 100 parts by weight of the thermoplastic resin composition and 80 to 200 parts by weight of the halogenated isoolefin-p-alkylstyrene copolymer.
摘要翻译： 提供一种热塑性弹性体组合物，其可以适用于充气轮胎的内衬，并且具有高空气阻隔性和高疲劳耐久性。 本发明是一种热塑性弹性体组合物，其包含热塑性树脂组合物和分散在热塑性树脂组合物中的橡胶组合物，其中热塑性树脂组合物包含聚酰胺和乙烯 - 乙烯醇共聚物或聚（乙烯醇），橡胶组合物 包括卤代异烯烃 - 对 - 烷基苯乙烯共聚物，并且是交联的。 热塑性树脂组合物优选包含1至25重量％的乙烯 - 乙烯醇共聚物或聚（乙烯醇）。 热塑性弹性体组合物优选包含100重量份的热塑性树脂组合物和80-200重量份的卤代异烯烃 - 对烷基苯乙烯共聚物。
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公开(公告)号：US08202604B2
公开(公告)日：2012-06-19
申请号：US12297240
申请日：2007-04-26
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
CPC分类号： B29D30/3028 , B29D30/0681 , B29D2030/0682 , B60C5/14 , B60C2005/145 , Y10T428/24479 , Y10T428/24777
摘要： A pneumatic tire having an air permeation preventive layer formed by adhering a resin film containing thermoplastic resin as a main component thereof to a tire inner wall surface, wherein the resin film is laminated, as a narrow width slit film shape, with an elastomer and the resultant ribbon-shaped laminate is continuously and spirally wound in a tire circumferential direction so that the edges thereof partially overlap to thereby form the air permeation preventive layer, whereby a pneumatic tire having a light weight and superior air permeation preventive property, no splice openings of the air permeation preventive layer at the time of tire processing, and capable of shortening the processing time can be obtained as well as the production method thereof.
摘要翻译： 一种充气轮胎，其特征在于，具有通过将含有热塑性树脂作为主要成分的树脂膜以轮胎内壁面的方式粘合而形成的透气防止层，所述轮胎内壁面通过弹性体将所述树脂膜层压成窄宽度狭缝膜， 所得到的带状层压体在轮胎周向上连续并螺旋地卷绕，使得其边缘部分重叠，从而形成防透气层，由此具有重量轻且优异的防透气性的充气轮胎，没有接合开口 可以获得轮胎加工时的防透气层，能够缩短加工时间的方法及其制造方法。
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4.发明申请STABILIZED DYNAMICALLY VULCANIZED THERMOPLASTIC ELASTOMER COMPOSITIONS USEFUL IN FLUID BARRIER APPLICATIONS 有权稳定的动态弹性体弹性体弹性体组合物在流体阻隔器中的应用公开(公告)号：US20120041108A1
公开(公告)日：2012-02-16
申请号：US13140080
申请日：2008-12-17
IPC分类号： C08K5/3475 , C08K5/13 , C08K5/134 , C08K5/3492 , C08K5/07
CPC分类号： C08L77/00 , C08K5/005 , C08L9/02 , C08L15/00 , C08L23/283 , C08L51/00 , C08L51/04 , C08L51/06 , C08L51/08 , C08L53/02 , C08L55/02 , C08L2666/02 , C08L2666/24 , C08L2666/14 , C08L2666/04 , C08L2666/06
摘要： A stabilized, dynamically vulcanized thermoplastic elastomer composition comprising dispersed dynamically vulcanized particles of at least one first elastomer or rubber comprising halogenated isobutylene-containing elastomer and dispersed particles of at least one second elastomer or rubber comprising at least one functional group capable of reacting with and grafting to a polyamide, the particles of the at least one first and at least one second elastomers dispersed in a continuous thermoplastic polyamide or nylon resin matrix comprising at least one nylon homopolymer, nylon copolymer or mixture thereof, the composition or the at least one first elastomer further comprising at least one stabilizer against degradation induced by exposure to actinic, particularly ultraviolet, radiation. The compositions are preferably produced in a mixing extruder and are suitable for producing durable, flexible, thermoplastic elastomer fluid barrier films or layers useful in industrial articles such as vehicle tire innerliners and hoses.
摘要翻译： 一种稳定的，动态硫化的热塑性弹性体组合物，其包含至少一种包含含卤代异丁烯的弹性体的至少一种第一弹性体或橡胶的分散的动态硫化颗粒和至少一种第二弹性体或橡胶的分散颗粒，所述第二弹性体或橡胶包含至少一个能与载体 至少一种第一和至少一种第二弹性体的颗粒分散在包含至少一种尼龙均聚物，尼龙共聚物或其混合物的连续热塑性聚酰胺或尼龙树脂基质中，所述组合物或至少一种第一弹性体 进一步包含至少一种稳定剂，其防止通过暴露于光化特别是紫外线辐射而引起的降解。 组合物优选在混合挤出机中制备，并且适用于生产用于工业制品例如车辆轮胎内衬和软管的耐用的，柔性的，热塑性的弹性体流体屏障膜或层。
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5.发明申请METHOD FOR PRODUCING PNEUMATIC TIRE HAVING LIGHT BLOCKING PROTECTIVE LAYER ON SURFACE OF AIR PERMEATION PREVENTIVE LAYER 审中-公开在空气渗透防止层表面生产具有遮光保护层的气泡轮胎的方法公开(公告)号：US20100071823A1
公开(公告)日：2010-03-25
申请号：US12525740
申请日：2008-02-06
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
CPC分类号： B29D30/0681 , B29D2030/0682 , B60C1/0008 , B60C5/14 , B60C13/002 , B60C2005/145
摘要： A method of production of a pneumatic tire having a layer of a thermoplastic resin or a thermoplastic elastomer composition comprised of a thermoplastic resin in which an elastomer component is dispersed arranged as an air permeation preventive layer on the inner surface of the tire and having a light blocking protective layer for preventing degradation caused by sunlight, placed on the surface of the air permeation preventive layer after vulcanization.
摘要翻译： 一种具有热塑性树脂层或热塑性弹性体组合物的热塑性树脂层的充气轮胎的制造方法，所述热塑性树脂或热塑性弹性体组合物由其中分散有弹性体组分的热塑性树脂构成，作为防透气层布置在轮胎的内表面上并具有光 用于防止阳光引起的劣化的阻挡保护层，放置在硫化后的防透气层的表面上。
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公开(公告)号：US08933172B2
公开(公告)日：2015-01-13
申请号：US13639445
申请日：2011-02-10
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
CPC分类号： C08L77/02 , B60C1/0008 , C08G69/48 , C08J2363/00 , C08J2377/02 , C08J2377/06 , C08J2415/02 , C08L63/00 , C08L77/06 , C08L2205/05 , Y10T152/10495 , C08L15/02 , C08L25/08 , C08L77/00
摘要： A thermoplastic elastomer composition having a continuous phase and a dispersed phase, wherein the continuous phase comprising (A) an epoxy-modified polyamide resin, and the dispersed phase comprising (B) a halogenated isoolefin-paraalkylstyrene copolymer rubber, wherein the thermoplastic elastomer composition is obtained by melt-kneading (B) halogenated isoolefin-paraalkylstyrene copolymer rubber, (C) a polyamide resin, and (D) a polyfunctional epoxy compound having two or more epoxy groups per molecule in an amount of 0.05 parts by weight or more and less than 3 parts by weight with respect to 100 parts by weight of polyamide resin (C), at a temperature which is equal to or more than the melting point of polyamide resin (C), and epoxy-modified polyamide resin (A) is produced by the reaction of polyamide resin (C) with polyfunctional epoxy compound (D) during the melt-kneading.
摘要翻译： 一种具有连续相和分散相的热塑性弹性体组合物，其中所述连续相包含（A）环氧改性聚酰胺树脂，和包含（B）卤化异烯烃 - 对烷基苯乙烯共聚物橡胶的分散相，其中所述热塑性弹性体组合物为 通过熔融捏合（B）卤代异烯烃 - 对烷基苯乙烯共聚物橡胶，（C）聚酰胺树脂和（D）每分子具有两个或更多个环氧基的多官能环氧化合物，其量为0.05重量份以上 相对于聚酰胺树脂（C）100重量份，聚酰胺树脂（C）的熔点以上的温度和环氧改性聚酰胺树脂（A）的重量比3重量份 通过在熔融捏合过程中聚酰胺树脂（C）与多官能环氧化合物（D）的反应。
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公开(公告)号：US20120111469A1
公开(公告)日：2012-05-10
申请号：US13259062
申请日：2011-03-07
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
IPC分类号： B60C19/00 , B32B7/12 , B32B3/00 , C09J153/02
CPC分类号： B60C5/14 , B60C1/0008 , B60C2005/145 , C08L15/02 , C08L61/06 , C08L61/14 , C09J111/00 , C09J153/02 , C09J161/06 , Y10T428/265 , Y10T428/2874
摘要： Provided is an adhesive composition that provides excellent adhesion between a thermoplastic resin or a thermoplastic elastomer in which an elastomer component is dispersed in the thermoplastic resin and a tire by a combination of general-purpose materials, without using any special polymer. The adhesive composition comprises 100 parts by weight of a base polymer and 20 to 50 parts by weight of a resol-type phenolic resin-based resin crosslinking agent, wherein 100 parts by weight of the base polymer comprises 80 to 99 parts by weight of a thermoplastic elastomer and 1 to 20 parts by weight of a halogenated rubber. The resol-type phenolic resin-based resin crosslinking agent is preferably an alkylphenol-formaldehyde resin. Examples of the thermoplastic elastomer can include styrene-butadiene-styrene block copolymers, and examples of the halogenated rubber can include chloroprene rubber and chlorosulfonated polyethylene.
摘要翻译： 提供一种粘合剂组合物，其不使用任何特殊的聚合物，在热塑性树脂或热塑性树脂中的弹性体组分分散在热塑性树脂中的热塑性弹性体和通过组合的通用材料的轮胎之间提供优异的粘附性。 粘合剂组合物包含100重量份的基础聚合物和20至50重量份的甲阶酚醛树脂型酚醛树脂基树脂交联剂，其中100重量份的基础聚合物包含80至99重量份的 热塑性弹性体和1〜20重量份的卤化橡胶。 甲阶酚醛树脂型树脂交联剂优选为烷基酚 - 甲醛树脂。 热塑性弹性体的实例可包括苯乙烯 - 丁二烯 - 苯乙烯嵌段共聚物，卤代橡胶的实例可包括氯丁二烯橡胶和氯磺化聚乙烯。
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公开(公告)号：US20090288749A1
公开(公告)日：2009-11-26
申请号：US12296008
申请日：2007-04-02
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
IPC分类号： B60C5/14
CPC分类号： B60C1/0008 , B32B25/14 , C08K3/014 , C08K3/04 , C08K5/005 , C08L21/00 , C08L53/02 , C08L53/025 , C08L2666/24 , C08L2666/02
摘要： A pneumatic tire having, as an air permeation preventive layer on the surface thereof, a layer of a thermoplastic resin or a layer of a thermoplastic elastomer composition comprising a thermoplastic resin, in which an elastomer component is dispersed, arranged and further having, on the surface of the layer of the thermoplastic resin or the layer of the thermoplastic elastomer composition, a light-blocking layer having a light transmittance of less than 10% in the range of a wavelength of 280 to 400 nm, wherein degradation of the air permeation preventive layer by sunlight is prevented using the thermoplastic resin or thermoplastic elastomer composition.
摘要翻译： 一种充气轮胎，其具有作为其表面的透气防止层的热塑性树脂层或热塑性弹性体组合物层，所述热塑性弹性体组合物包含其中分散有弹性体成分的热塑性树脂，并且还具有 热塑性树脂层或热塑性弹性体组合物层的表面，在波长280-400纳米范围内具有小于10％的透光率的遮光层，其中防透气性降低 使用热塑性树脂或热塑性弹性体组合物防止了阳光层。
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公开(公告)号：US20090165914A1
公开(公告)日：2009-07-02
申请号：US12297240
申请日：2007-04-26
申请人： Shusaku Tomoi
发明人： Shusaku Tomoi
CPC分类号： B29D30/3028 , B29D30/0681 , B29D2030/0682 , B60C5/14 , B60C2005/145 , Y10T428/24479 , Y10T428/24777
摘要： A pneumatic tire having an air permeation preventive layer formed by adhering a resin film containing thermoplastic resin as a main component thereof to a tire inner wall surface, wherein the resin film is laminated, as a narrow width slit film shape, with an elastomer and the resultant ribbon-shaped laminate is continuously and spirally wound in a tire circumferential direction so that the edges thereof partially overlap to thereby form the air permeation preventive layer, whereby a pneumatic tire having a light weight and superior air permeation preventive property, no splice openings of the air permeation preventive layer at the time of tire processing, and capable of shortening the processing time can be obtained as well as the production method thereof.
摘要翻译： 一种充气轮胎，其特征在于，具有通过将含有热塑性树脂作为主要成分的树脂膜以轮胎内壁面的方式粘合而形成的透气防止层，所述轮胎内壁面通过弹性体将所述树脂膜层压成窄宽度的狭缝膜， 所得到的带状层压体在轮胎周向上连续并螺旋地卷绕，使得其边缘部分重叠，从而形成防透气层，由此具有重量轻且优异的防透气性的充气轮胎，没有接合开口 可以获得轮胎加工时的防透气层，能够缩短加工时间的方法及其制造方法。
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公开(公告)号：US20130056123A1
公开(公告)日：2013-03-07
申请号：US13392724
申请日：2011-03-18
申请人： Shusaku Tomoi , Kouichi Kawaguchi
发明人： Shusaku Tomoi , Kouichi Kawaguchi
CPC分类号： C08K3/04 , B60C1/0008 , C08J3/28 , C08J2323/22 , C08L23/22 , C08L23/283 , C08L25/18 , C08L77/02 , C08L77/06
摘要： Disclosed is a method for producing a thermoplastic elastomer composition having a phase structure comprising a continuous phase comprising at least one thermoplastic resin and a disperse phase comprising dynamically crosslinked elastomer particles finely dispersed in the continuous phase, the method being characterized by dispersing in at least one crosslinkable elastomer component furnace carbon black having a BET nitrogen adsorption specific surface area of from 100 to 260 m2/g and a primary particle average particle diameter of from 10 to 25 nm in an amount of 1 to 15 parts by weight with respect to 100 parts by weight of the at least one crosslinkable elastomer component, prior to or during dynamic crosslinking.
摘要翻译： 公开了一种具有相结构的热塑性弹性体组合物的方法，所述相组织包括连续相，该连续相包含至少一种热塑性树脂和包含在连续相中细分散的动态交联的弹性体颗粒的分散相，该方法的特征在于将至少一种 交联性弹性体成分炉炭黑，其BET氮吸附比表面积为100〜260m2 / g，一次粒子平均粒径为10〜25nm，相对于100份为1〜15份 的至少一种可交联弹性体组分，在动态交联之前或期间。
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