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公开(公告)号:US06451487B1
公开(公告)日:2002-09-17
申请号:US09545094
申请日:2000-04-07
申请人: Simon Besner , Michel Armand , Jean-François Magnan , André Bélanger , Michel Gauthier , Elisabeth Dupuis
发明人: Simon Besner , Michel Armand , Jean-François Magnan , André Bélanger , Michel Gauthier , Elisabeth Dupuis
IPC分类号: H01H402
CPC分类号: H01M10/05 , H01M2/1646 , H01M2/1653 , H01M4/02 , H01M4/13 , H01M4/5825 , H01M4/62 , H01M4/622 , H01M4/624 , H01M6/18 , H01M6/181 , H01M6/185
摘要: The present invention concerns a composite electrode for an electrochemical cell, an electrochemical cell comprising the composite electrode, a process for preparing the composite electrode, and a process for the preparation of a half-cell comprising a porous mineral composite-porous mineral separator sub-network.
摘要翻译: 本发明涉及一种用于电化学电池的复合电极,包含该复合电极的电化学电池,一种制备该复合电极的方法,以及一种制备半电池的方法,该半电池包括多孔矿物复合多孔矿物分离器 网络。
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公开(公告)号:US06844114B2
公开(公告)日:2005-01-18
申请号:US10252580
申请日:2002-09-24
申请人: Michel Gauthier , Simon Besner , Michel Armand , Jean-François Magnan , Hugues Hamelin , André Bélanger
发明人: Michel Gauthier , Simon Besner , Michel Armand , Jean-François Magnan , Hugues Hamelin , André Bélanger
CPC分类号: H01M4/667 , H01M4/485 , H01M4/66 , H01M4/661 , H01M4/663 , H01M10/05 , H01M10/052 , Y02E60/122 , Y10T29/10
摘要: The present invention is concerned with a protective coating with current applied on a metallic collector of an electrode. The protective coating comprises a mineral binder vitreous or partly vitreous and optionally an electronic conduction additive. This coating is applied in the form of a solution or dispersion on the collector of the electrode and dried, so that it coats and protects at least part of the surface of the metal of the collector to prevent the formation of passivation films generated by active species produced by other components of the generator.
摘要翻译: 本发明涉及具有施加在电极的金属集电体上的电流的保护涂层。 保护性涂层包括玻璃状或部分玻璃状的矿物粘合剂和任选的电子导电添加剂。 将该涂层以溶液或分散体的形式施加在电极的集电体上并干燥,使其涂覆并保护集电体金属的至少一部分表面,以防止由活性物质产生的钝化膜的形成 由发电机的其他部件生产。
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公开(公告)号:US06485866B1
公开(公告)日:2002-11-26
申请号:US09544133
申请日:2000-04-06
申请人: Michel Gauthier , Simon Besner , Michel Armand , Jean-François Magnan , Hugues Hamelin , André Bélanger
发明人: Michel Gauthier , Simon Besner , Michel Armand , Jean-François Magnan , Hugues Hamelin , André Bélanger
IPC分类号: H01M470
CPC分类号: H01M4/667 , H01M4/485 , H01M4/66 , H01M4/661 , H01M4/663 , H01M10/05 , H01M10/052 , Y02E60/122 , Y10T29/10
摘要: The present invention is concerned with a protective coating with current applied on a metallic collector of an electrode. The protective coating comprises a mineral binder vitreous or partly vitreous and optionally an electronic conduction additive. This coating is applied in the form of a solution or dispersion on the collector of the electrode and dried, so that it coats and protects at least part of the surface of the metal of the collector to prevent the formation of passivation films generated by active species produced by other components of the generator.
摘要翻译: 本发明涉及具有施加在电极的金属集电体上的电流的保护涂层。 保护性涂层包括玻璃状或部分玻璃状的矿物粘合剂和任选的电子导电添加剂。 将该涂层以溶液或分散体的形式施加在电极的集电体上并干燥,使其涂覆并保护集电体金属的至少一部分表面,以防止由活性物质产生的钝化膜的形成 由发电机的其他部件生产。
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公开(公告)号:US06492061B1
公开(公告)日:2002-12-10
申请号:US09544134
申请日:2000-04-06
IPC分类号: H01M462
CPC分类号: H01M10/0565 , H01M4/364 , H01M4/485 , H01M4/62 , H01M4/622 , H01M10/052
摘要: The present invention concerns a lithium electrochemical generator including at least one composite electrode comprising an active material and a first and second solid electrolytes non-homogeneously distributed into the composite. The first solid electrolyte is of mineral nature, vitreous or partly vitreous, and is a specific conductor of lithium ions, and is preferably localized on the surface of the particles of active materials of the electrode. The second solid electrolyte is organic, comprises a dry or gelified polymer electrolyte conducting ions surrounding the dispersed solid phases and acts as a deformable binder, preferably elastomeritically, of the composite in contact also with the collector and the separator electrolyte of the generator. A thin layer of the first electrolyte wets and coats at least a part of the surface of the active material particles to protect the coated surface of passivation or degradation reactions induced by the second electrolyte, and to maintain a good quality of ionic and electronic exchanges between the active material of the electrode and the other components of the composite, the first electrolyte being impermeable to the components of the second electrolyte.
摘要翻译: 本发明涉及一种锂电化学发生器,其包括至少一个复合电极,该复合电极包括活性材料和非均匀分布于复合材料中的第一和第二固体电解质。 第一固体电解质具有矿物性质,玻璃状或部分玻璃质,并且是锂离子的特定导体,并且优选位于电极的活性材料颗粒的表面上。 第二固体电解质是有机的,包括干燥或凝胶化的聚合物电解质,其传导围绕分散的固相的离子,并且作为复合材料的可变形粘合剂,优选地弹性体地与发生器的收集器和分离器电解质接触。 第一电解质的薄层润湿并涂覆活性材料颗粒表面的至少一部分,以保护涂覆的表面由第二电解质引起的钝化或降解反应,并保持良好的离子和电子交换质量 电极的活性材料和复合材料的其它组分,第一电解质不能渗透到第二电解质的组分。
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公开(公告)号:US06962666B2
公开(公告)日:2005-11-08
申请号:US10740449
申请日:2003-12-22
申请人: Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallée , Michel Armand , Jean-François Magnan
发明人: Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallée , Michel Armand , Jean-François Magnan
IPC分类号: H01M4/131 , B05D5/12 , C01B31/02 , H01B1/00 , H01B1/08 , H01G9/00 , H01G11/46 , H01M4/04 , H01M4/06 , H01M4/08 , H01M4/136 , H01M4/1391 , H01M4/36 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/62 , H01M6/16 , H01M6/18 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M10/0566 , H01M10/36
CPC分类号: H01M4/136 , H01B1/24 , H01G9/042 , H01G9/155 , H01M4/364 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要: The present invention concerns electrode materials capable of redox reactions by electrons and alkaline ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要翻译: 本发明涉及能够通过与电解质进行电子和碱离子交换的氧化还原反应的电极材料。 这些应用领域是主要(电池)或二次电化学发生器,超级电容器和电致变色型光调制系统。
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公开(公告)号:US06855273B2
公开(公告)日:2005-02-15
申请号:US10175794
申请日:2002-06-21
申请人: Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallée , Michel Armand , Jean-François Magnan
发明人: Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallée , Michel Armand , Jean-François Magnan
IPC分类号: H01M4/131 , B05D5/12 , C01B31/02 , H01B1/00 , H01B1/08 , H01G9/00 , H01G11/46 , H01M4/04 , H01M4/06 , H01M4/08 , H01M4/136 , H01M4/1391 , H01M4/36 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/62 , H01M6/16 , H01M6/18 , H01M10/05 , H01M10/052 , H01M10/0565 , H01M10/0566 , H01M10/36
CPC分类号: H01M4/136 , H01B1/24 , H01G9/042 , H01G9/155 , H01M4/364 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要: The present invention concerns electrode materials capable of redox reactions by electrons and alkaline ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要翻译: 本发明涉及能够通过电子和碱离子与电解质交换的氧化还原反应的电极材料。 应用领域是超级电容器类型的初级(电池)或二级电化学发生器,超级电容器和光调制系统。
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公开(公告)号:US06280882B1
公开(公告)日:2001-08-28
申请号:US09142055
申请日:1998-12-14
申请人: Alain Vallee , Michel Armand , Yves Choquette , Andre Belanger , Michel Gauthier , Michel Perrier , Karim Zaghib , Estelle Potvin , Simon Besner
发明人: Alain Vallee , Michel Armand , Yves Choquette , Andre Belanger , Michel Gauthier , Michel Perrier , Karim Zaghib , Estelle Potvin , Simon Besner
IPC分类号: H01M614
CPC分类号: H01M2/1686 , H01M2/1673 , H01M6/181 , Y10T29/49108 , Y10T29/49115
摘要: The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.
摘要翻译: 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料粉末的复合电极,如果需要的话,电化学发生器的电子导电添加剂电解组合物包括由聚醚 和至少第二聚合物基质,宏观上分离的,以及至少一种碱性盐以及极性非质子传递溶剂。聚合物基质能够被至少一种极性非质子传递溶剂溶胀。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器,其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜,其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体,然后在前述步骤中由溶液形成的电极上的表面涂层的方法,在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。
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8.
公开(公告)号:US06806002B2
公开(公告)日:2004-10-19
申请号:US09878356
申请日:2001-06-12
申请人: Alain Vallee , Michel Armand , Yves Choquette , Andre Belanger , Michel Gauthier , Michel Perrier , Karim Zaghib , Estelle Potvin , Simon Besner
发明人: Alain Vallee , Michel Armand , Yves Choquette , Andre Belanger , Michel Gauthier , Michel Perrier , Karim Zaghib , Estelle Potvin , Simon Besner
IPC分类号: H01M462
CPC分类号: H01M2/1686 , H01M2/1673 , H01M6/181 , Y10T29/49108 , Y10T29/49115
摘要: The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.
摘要翻译: 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料的粉末的复合电极,如果需要的话,电化学发生器的电子导电添加剂。 电解质组合物包括由聚醚和至少第二聚合物基质组成的宏观分离的第一聚合物基质,以及至少一种碱性盐以及极性非质子溶剂。聚合物基质能够被至少一种 的极性非质子溶剂。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器,其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜,其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体,然后在前述步骤中由溶液形成的电极上的表面涂层的方法,在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。
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公开(公告)号:US20080257721A1
公开(公告)日:2008-10-23
申请号:US12033636
申请日:2008-02-19
申请人: Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
发明人: Nathalie Ravet , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
CPC分类号: H01M4/136 , H01B1/24 , H01G9/042 , H01G9/155 , H01M4/364 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要: The present invention concerns electrode materials capable of redox reactions by electrons and alkaline ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要翻译: 本发明涉及能够通过电子和碱离子与电解质交换的氧化还原反应的电极材料。 应用领域是超级电容器类型的初级(电池)或二级电化学发生器,超级电容器和光调制系统。
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公开(公告)号:US20110086273A1
公开(公告)日:2011-04-14
申请号:US12899067
申请日:2010-10-06
申请人: NATHALIE RAVET , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
发明人: NATHALIE RAVET , Simon Besner , Martin Simoneau , Alain Vallee , Michel Armand , Jean-Francois Magnan
CPC分类号: H01M4/136 , H01B1/24 , H01G9/042 , H01G9/155 , H01M4/364 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/52 , H01M4/58 , H01M4/5825 , H01M4/583 , H01M4/622 , H01M4/625 , H01M10/052 , H01M10/0565 , H01M2300/0082 , Y02E60/13
摘要: The present invention concerns electrode materials capable of redox reactions by electrons and alkali ions exchange with an electrolyte. The applications are in the field of primary (batteries) or secondary electrochemical generators, super capacitors and light modulating system of the super capacitor type.
摘要翻译: 本发明涉及能够通过电子和碱离子与电解质交换的氧化还原反应的电极材料。 应用领域是超级电容器类型的初级(电池)或二级电化学发生器,超级电容器和光调制系统。
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