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    Composite treatment with LiPO3
    1.
    发明授权
    Composite treatment with LiPO3 有权
    用LiPO3复合处理

    公开(公告)号：US06492061B1

    公开(公告)日：2002-12-10

    申请号：US09544134

    申请日：2000-04-06

    申请人： Michel Gauthier ,  Simon Besner ,  Michel Armand ,  Jean-François Magnan ,  Pierre Hovington

    发明人： Michel Gauthier ,  Simon Besner ,  Michel Armand ,  Jean-François Magnan ,  Pierre Hovington

    IPC分类号： H01M462

    CPC分类号： H01M10/0565 ,  H01M4/364 ,  H01M4/485 ,  H01M4/62 ,  H01M4/622 ,  H01M10/052

    摘要： The present invention concerns a lithium electrochemical generator including at least one composite electrode comprising an active material and a first and second solid electrolytes non-homogeneously distributed into the composite. The first solid electrolyte is of mineral nature, vitreous or partly vitreous, and is a specific conductor of lithium ions, and is preferably localized on the surface of the particles of active materials of the electrode. The second solid electrolyte is organic, comprises a dry or gelified polymer electrolyte conducting ions surrounding the dispersed solid phases and acts as a deformable binder, preferably elastomeritically, of the composite in contact also with the collector and the separator electrolyte of the generator. A thin layer of the first electrolyte wets and coats at least a part of the surface of the active material particles to protect the coated surface of passivation or degradation reactions induced by the second electrolyte, and to maintain a good quality of ionic and electronic exchanges between the active material of the electrode and the other components of the composite, the first electrolyte being impermeable to the components of the second electrolyte.

    摘要翻译： 本发明涉及一种锂电化学发生器，其包括至少一个复合电极，该复合电极包括活性材料和非均匀分布于复合材料中的第一和第二固体电解质。 第一固体电解质具有矿物性质，玻璃状或部分玻璃质，并且是锂离子的特定导体，并且优选位于电极的活性材料颗粒的表面上。 第二固体电解质是有机的，包括干燥或凝胶化的聚合物电解质，其传导围绕分散的固相的离子，并且作为复合材料的可变形粘合剂，优选地弹性体地与发生器的收集器和分离器电解质接触。 第一电解质的薄层润湿并涂覆活性材料颗粒表面的至少一部分，以保护涂覆的表面由第二电解质引起的钝化或降解反应，并保持良好的离子和电子交换质量 电极的活性材料和复合材料的其它组分，第一电解质不能渗透到第二电解质的组分。

    Electrolytic composition with polymer base for electrochemical generator
    5.
    发明授权
    Electrolytic composition with polymer base for electrochemical generator 有权
    电化学发生器用电解质组合物

    公开(公告)号：US06280882B1

    公开(公告)日：2001-08-28

    申请号：US09142055

    申请日：1998-12-14

    申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    IPC分类号： H01M614

    CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

    摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

    摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂电解组合物包括由聚醚 和至少第二聚合物基质，宏观上分离的，以及至少一种碱性盐以及极性非质子传递溶剂。聚合物基质能够被至少一种极性非质子传递溶剂溶胀。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。

    Electrolytic composition with polymer base for electrochemical generator
    6.
    发明授权
    Electrolytic composition with polymer base for electrochemical generator 失效
    电化学发生器用电解质组合物

    公开(公告)号：US06806002B2

    公开(公告)日：2004-10-19

    申请号：US09878356

    申请日：2001-06-12

    申请人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    发明人： Alain Vallee ,  Michel Armand ,  Yves Choquette ,  Andre Belanger ,  Michel Gauthier ,  Michel Perrier ,  Karim Zaghib ,  Estelle Potvin ,  Simon Besner

    IPC分类号： H01M462

    CPC分类号： H01M2/1686 ,  H01M2/1673 ,  H01M6/181 ,  Y10T29/49108 ,  Y10T29/49115

    摘要： The invention concerns an aprotic electrolytic composition located in the separator and in at least one composite electrode containing a powder of an active electrode material, and if necessary an electronic conduction additive of an electrochemical generator. The electrolytic composition comprises a first polymer matrix consisting of a polyether and at least a second polymer matrix, macroscopically separated, and also at least an alkaline salt as well as a polar aprotic solvent: The polymer matrices are capable of being swollen by at least one of the polar aprotic solvents. The solvent or mixture of solvents is unevenly distributed between the polymer matrices. The invention also concerns an electrochemical generator comprising a negative electrode and positive electrode reversible to alkaline ions and a separator with polymer electrolyte, the electrolytic component of which is the composition described above. The invention further concerns the manufacture in two or three steps of a sub-assembly of an electrochemical generator by coating an electrode support with a composite electrode containing the second matrix, followed by a surface coating on the electrode resulting from the preceding step with a solution containing the first polymer matrix so as to form the separator wholly or partly.

    摘要翻译： 本发明涉及位于分离器中的非质子电解组合物和至少一个含有活性电极材料的粉末的复合电极，如果需要的话，电化学发生器的电子导电添加剂。 电解质组合物包括由聚醚和至少第二聚合物基质组成的宏观分离的第一聚合物基质，以及至少一种碱性盐以及极性非质子溶剂。聚合物基质能够被至少一种 的极性非质子溶剂。 溶剂或溶剂混合物不均匀地分布在聚合物基质之间。 本发明还涉及一种电化学发生器，其包括负极和碱性离子可逆的正极和具有聚合物电解质的隔膜，其电解组分是上述组成。 本发明还涉及通过用包含第二基质的复合电极涂覆电极载体，然后在前述步骤中由溶液形成的电极上的表面涂层的方法，在电化学发生器的子组件的两个或三个步骤中制造两个或三个步骤 含有第一聚合物基质以全部或部分形成隔膜。